Startseite Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich
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Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich

  • Kevin U. Bareiß , Fabian M. Kleeberg , David Enseling , Thomas Jüstel und Thomas Schleid EMAIL logo
Veröffentlicht/Copyright: 21. Februar 2022
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 77 Heft 2-3

Abstract

Thallium(I) decahydro-closo-decaborate Tl2[B10H10] and thallium(I) dodecahydro-closo-dodecaborate Tl2[B12H12] are readily available as microcrystalline powders from reactions of thallium(I) carbonate Tl2[CO3] with aqueous solutions of the respective free acid (H3O)2[B10H10] or (H3O)2[B12H12]. Tl2[B12H12] crystallizes with an anti-fluorite related structure (cubic, Fm3‾, a = 1074.23(8) pm, Z = 4). Each Tl+ cation is coordinated by four icosahedral [B12H12]2– anions (d(B–B) = 180–181 pm) providing a twelvefold coordination sphere of hydrogen atoms (d(Tl–H) = 296 pm). Tl2[B10H10] crystallizes monoclinically in the space group P21/n with a = 704.03(5), b = 1111.45(8), c = 1281.16(9) pm and β = 94.912(3)° for Z = 4. The bicapped square antiprismatic [B10H10]2– anions (d(B–B) = 147–176 pm to the two apical boron atoms, d(B–B) = 161–199 pm within the corpus) again form distorted tetrahedra around the (Tl1)+, but square pyramids around the (Tl2)+ cations. Thus (Tl1)+ is coordinated by 12 hydrogen atoms (d(Tl1–H) = 275–315 pm), but (Tl2)+ only by 11 of them (d(Tl2–H) = 267–357 pm). Both compounds show a greenish-yellow photoluminescence caused by an interconfigurational 6sp–6s2 emission (3Pn→1S0, n = 0–2) at the Tl+ cation.

Keywords: decahydro-closo-decaborates; dodecahydro-closo-dodecaborates; lone-pair cations; Raman and photoluminescence spectroscopy; thallium

Professor Holger Braunschweig zum 60. Geburtstag gewidmet.

Corresponding author: Thomas Schleid, Universität Stuttgart, Stuttgart, Germany, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Erhalten: 2022-01-13
Angenommen: 2022-01-23
Online erschienen: 2022-02-21
Erschienen im Druck: 2022-03-28

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

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  2. In this issue
  3. Research Articles
  4. Structural and electrochemical properties of the binary silicides Eu5Si3 and EuSi
  5. The solid solution TbNiIn1−xGa x
  6. Structural characterization of benzketozone monohydrate
  7. Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands
  8. Pressure-induced phase transitions and mechanical properties of insensitive high explosive 1,1-diamino-2,2-dinitroethylene
  9. Synthesis of a bifunctional boron-Lewis acid and studies on host-guest chemistry using pyridine and TMPD
  10. Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks
  11. Two new bis(pyridine)-bis(amide)-based copper(II) coordination compounds for the electrochemical detection of trace Cr(VI) and efficient electrocatalytic oxygen evolution
  12. Synthesis, characterization and crystal structure of 4-methoxybenzylidene-based zinc(II) complexes
  13. A Ni(II) coordination polymer with dual electrochemical functions: synthesis, crystal structure, hydrogen evolution reaction and l-ascorbic acid sensing
  14. Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich
https://doi.org/10.1515/znb-2022-0007
Schlagwörter für diesen Artikel
decahydro-closo-decaborates; dodecahydro-closo-dodecaborates; lone-pair cations; Raman and photoluminescence spectroscopy; thallium

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Structural and electrochemical properties of the binary silicides Eu5Si3 and EuSi
  5. The solid solution TbNiIn1−xGa x
  6. Structural characterization of benzketozone monohydrate
  7. Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands
  8. Pressure-induced phase transitions and mechanical properties of insensitive high explosive 1,1-diamino-2,2-dinitroethylene
  9. Synthesis of a bifunctional boron-Lewis acid and studies on host-guest chemistry using pyridine and TMPD
  10. Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks
  11. Two new bis(pyridine)-bis(amide)-based copper(II) coordination compounds for the electrochemical detection of trace Cr(VI) and efficient electrocatalytic oxygen evolution
  12. Synthesis, characterization and crystal structure of 4-methoxybenzylidene-based zinc(II) complexes
  13. A Ni(II) coordination polymer with dual electrochemical functions: synthesis, crystal structure, hydrogen evolution reaction and l-ascorbic acid sensing
  14. Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich
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