Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks
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Hua-Rui Wang
Abstract
Reactions of lanthanide nitrate, 1,3,5-benzenetrisbnzoic acid (H3BTB) and [RMI]Br ionic liquids (RMI = 1-alkyl-3-methylimidazolium; R = ethyl, propyl or butyl), gave rise to six novel lanthanide–organic frameworks (LOFs) [Ln(BTB)H2O], where Ln = Nd 1, Sm 2, Gd 3, Dy 4, Ho 5 and Er 6. These compounds have been characterized by elemental analysis, IR spectra, thermogravimetric analysis, single-crystal and powder X-ray diffraction. Compounds 1–6 are isostructural and consist of infinite rod-shaped lanthanide-carboxylate building units, which are further bridged by trigonal-planar BTB ligands to give non-interpenetrated open 3D frameworks. The results of variable-temperature magnetic studies have shown that the magnetic interaction between the Ln(III) ions in 3, 5 and 6 is mainly due to antiferromagnetic coupling as well as the depopulation of the Stark levels.
Funding source: key scientific research projects of higher education of Henan Province
Award Identifier / Grant number: 16A150016
Funding source: Henan Province Natural Science Foundation
Award Identifier / Grant number: 182300410237
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Author contributions: The author has accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was supported by key scientific research projects of higher education of Henan Province (16A150016) and Henan Province Natural Science Foundation (182300410237).
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Conflict of interest statement: The author declares no conflicts of interest regarding this article.
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© 2022 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this issue
- Research Articles
- Structural and electrochemical properties of the binary silicides Eu5Si3 and EuSi
- The solid solution TbNiIn1−xGa x
- Structural characterization of benzketozone monohydrate
- Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands
- Pressure-induced phase transitions and mechanical properties of insensitive high explosive 1,1-diamino-2,2-dinitroethylene
- Synthesis of a bifunctional boron-Lewis acid and studies on host-guest chemistry using pyridine and TMPD
- Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks
- Two new bis(pyridine)-bis(amide)-based copper(II) coordination compounds for the electrochemical detection of trace Cr(VI) and efficient electrocatalytic oxygen evolution
- Synthesis, characterization and crystal structure of 4-methoxybenzylidene-based zinc(II) complexes
- A Ni(II) coordination polymer with dual electrochemical functions: synthesis, crystal structure, hydrogen evolution reaction and l-ascorbic acid sensing
- Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich
Artikel in diesem Heft
- Frontmatter
- In this issue
- Research Articles
- Structural and electrochemical properties of the binary silicides Eu5Si3 and EuSi
- The solid solution TbNiIn1−xGa x
- Structural characterization of benzketozone monohydrate
- Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands
- Pressure-induced phase transitions and mechanical properties of insensitive high explosive 1,1-diamino-2,2-dinitroethylene
- Synthesis of a bifunctional boron-Lewis acid and studies on host-guest chemistry using pyridine and TMPD
- Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks
- Two new bis(pyridine)-bis(amide)-based copper(II) coordination compounds for the electrochemical detection of trace Cr(VI) and efficient electrocatalytic oxygen evolution
- Synthesis, characterization and crystal structure of 4-methoxybenzylidene-based zinc(II) complexes
- A Ni(II) coordination polymer with dual electrochemical functions: synthesis, crystal structure, hydrogen evolution reaction and l-ascorbic acid sensing
- Tl2[B10H10] und Tl2[B12H12]: Kristallstrukturen, Raman-Spektren und Tl+-Lone-Pair-Lumineszenz im Vergleich
