Startseite New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)
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New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)

  • Valentin Weippert , Arthur Haffner und Dirk Johrendt EMAIL logo
Veröffentlicht/Copyright: 15. Oktober 2020
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 75 Heft 11

Abstract

The new supertetrahedral compounds MSiAs2, MGaSiAs3 and mC/tI-M4Ga5SiAs9 (M = Sr, Eu) have been synthesized by solid-state reactions at high temperatures. The structures were determined by single crystal or powder X-ray diffraction. MSiAs2 and MGaSiAs3 crystallize in the monoclinic TlGaSe2- and RbCuSnS3-type structures, respectively (space group C2/c). These are topologically hierarchical variants of the tetragonal HgI2-type structure with stacked layers of T2 or T3 supertetrahedra. The T4 compounds M4Ga5SiAs9 are dimorphic and form new structure types in the space groups C2/c and I41/amd, respectively. The latter exhibits coinciding layer stacking as known from tetragonal HgI2. The T4 compounds close the gap between the longer known T2 types and the recently reported compounds with T5 and T6 supertetrahedra. Measurements of the optical band gap, electrical resistivity and Hall Effect support the semiconducting nature of M4Ga5SiAs9. Magnetization measurements confirm Eu2+ in Eu4Ga5SiAs9 and indicate ferromagnetism below T = 2 K.

Keywords: arsenide; crystal structure; gallium; semiconductor; supertetrahedra

Dedicated to: Professor Robert Glaum on the occasion of his 60th birthday.

Corresponding author: Dirk Johrendt, Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstraße 5–13 (D), 81377 Munich, Germany, E-mail:

Funding source: Deutsche Forschungsgemeinschaft

Acknowledgements

Financial support by the Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This study was funded by Deutsche Forschungsgemeinschaft.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary material

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2020-0152).

Received: 2020-09-21
Accepted: 2020-09-25
Published Online: 2020-10-15
Published in Print: 2020-11-26

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Editorial
  4. Robert Glaum zum 60. Geburtstag gewidmet
  5. Research Articles
  6. Structural transition and antiferromagnetic ordering in the solid solution CePd1−xAuxAl (x = 0.1–0.9)
  7. Ternary plumbides ATPb2 (A = Ca, Sr, Ba, Eu; T = Rh, Pd, Pt) with distorted, lonsdaleite-related substructures of tetrahedrally connected lead atoms
  8. Intergrowth of niobium tungsten oxides of the tetragonal tungsten bronze type
  9. FeBiS2Cl – A new iron-containing member of the MPnQ2X family
  10. Thallium diphosphates
  11. Behavior of beryllium halides and triflate in acetonitrile solutions
  12. Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2 (RE = Sc, Y, Ho–Lu)
  13. Three of a kind? The non-isotypic triple CsCe[P2Se6], CsSm[P2Se6] and CsEr[P2Se6]
  14. The crystal structure of ZrCr2D≈4 at 50 K ≤ T ≤ 200 K
  15. High-pressure synthesis and crystal structure of HP-Al2B3O7(OH)
  16. New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)
  17. Comparative photophysical study of Pt(II) complex-nanoclay hybrid materials as dry powders and hydrogels
  18. Carbon subsulfide C3S2 – synthesis by flash vacuum pyrolysis and crystal structure determination
https://doi.org/10.1515/znb-2020-0152
Schlagwörter für diesen Artikel
arsenide; crystal structure; gallium; semiconductor; supertetrahedra

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Editorial
  4. Robert Glaum zum 60. Geburtstag gewidmet
  5. Research Articles
  6. Structural transition and antiferromagnetic ordering in the solid solution CePd1−xAuxAl (x = 0.1–0.9)
  7. Ternary plumbides ATPb2 (A = Ca, Sr, Ba, Eu; T = Rh, Pd, Pt) with distorted, lonsdaleite-related substructures of tetrahedrally connected lead atoms
  8. Intergrowth of niobium tungsten oxides of the tetragonal tungsten bronze type
  9. FeBiS2Cl – A new iron-containing member of the MPnQ2X family
  10. Thallium diphosphates
  11. Behavior of beryllium halides and triflate in acetonitrile solutions
  12. Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2 (RE = Sc, Y, Ho–Lu)
  13. Three of a kind? The non-isotypic triple CsCe[P2Se6], CsSm[P2Se6] and CsEr[P2Se6]
  14. The crystal structure of ZrCr2D≈4 at 50 K ≤ T ≤ 200 K
  15. High-pressure synthesis and crystal structure of HP-Al2B3O7(OH)
  16. New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)
  17. Comparative photophysical study of Pt(II) complex-nanoclay hybrid materials as dry powders and hydrogels
  18. Carbon subsulfide C3S2 – synthesis by flash vacuum pyrolysis and crystal structure determination
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