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Behavior of beryllium halides and triflate in acetonitrile solutions

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Veröffentlicht/Copyright: 20. Oktober 2020
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 75 Heft 11

Abstract

The solution behavior of beryllium halides and triflate in acetonitrile was studied by NMR, IR and Raman spectroscopy. Thereby mononuclear units [(MeCN)2BeX2] (X = Cl, Br, I, OTf) were identified as dominant species in these solutions. The solid state structure of [(MeCN)2Be(OTf)2] has been determined by X-ray diffraction. If only one equivalent of MeCN is used the dinuclear compounds [(MeCN)BeX2]2 (X = Cl, Br, I) are formed. Partial halide and triflate dissociation into the monomeric complexes as well as the formation of hetero-halide complexes [(MeCN)2BeClBr], [(MeCN)2BeClI] and [(MeCN)2BeBrI] was observed.

Keywords: acetonitrile; beryllium; coordination chemistry; N-donor adducts

Dedicated to: Professor Robert Glaum on the occasion of his 60th birthday.

Corresponding author: Magnus R. Buchner, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032Marburg, Germany, E-mail:

Funding source: DFG

Award Identifier / Grant number: BU2725/8-1

Acknowledgment

H. Lars Deubner is thanked for measurement of the Raman spectra. The DFG is gratefully acknowledged for financial support (BU2725/8-1).

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This study was funded by DFG under grant BU2725/8-1.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary material

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2020-0141).

Received: 2020-08-18
Accepted: 2020-09-09
Published Online: 2020-10-20
Published in Print: 2020-11-26

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Editorial
  4. Robert Glaum zum 60. Geburtstag gewidmet
  5. Research Articles
  6. Structural transition and antiferromagnetic ordering in the solid solution CePd1−xAuxAl (x = 0.1–0.9)
  7. Ternary plumbides ATPb2 (A = Ca, Sr, Ba, Eu; T = Rh, Pd, Pt) with distorted, lonsdaleite-related substructures of tetrahedrally connected lead atoms
  8. Intergrowth of niobium tungsten oxides of the tetragonal tungsten bronze type
  9. FeBiS2Cl – A new iron-containing member of the MPnQ2X family
  10. Thallium diphosphates
  11. Behavior of beryllium halides and triflate in acetonitrile solutions
  12. Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2 (RE = Sc, Y, Ho–Lu)
  13. Three of a kind? The non-isotypic triple CsCe[P2Se6], CsSm[P2Se6] and CsEr[P2Se6]
  14. The crystal structure of ZrCr2D≈4 at 50 K ≤ T ≤ 200 K
  15. High-pressure synthesis and crystal structure of HP-Al2B3O7(OH)
  16. New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)
  17. Comparative photophysical study of Pt(II) complex-nanoclay hybrid materials as dry powders and hydrogels
  18. Carbon subsulfide C3S2 – synthesis by flash vacuum pyrolysis and crystal structure determination
https://doi.org/10.1515/znb-2020-0141
Schlagwörter für diesen Artikel
acetonitrile; beryllium; coordination chemistry; N-donor adducts

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Editorial
  4. Robert Glaum zum 60. Geburtstag gewidmet
  5. Research Articles
  6. Structural transition and antiferromagnetic ordering in the solid solution CePd1−xAuxAl (x = 0.1–0.9)
  7. Ternary plumbides ATPb2 (A = Ca, Sr, Ba, Eu; T = Rh, Pd, Pt) with distorted, lonsdaleite-related substructures of tetrahedrally connected lead atoms
  8. Intergrowth of niobium tungsten oxides of the tetragonal tungsten bronze type
  9. FeBiS2Cl – A new iron-containing member of the MPnQ2X family
  10. Thallium diphosphates
  11. Behavior of beryllium halides and triflate in acetonitrile solutions
  12. Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2 (RE = Sc, Y, Ho–Lu)
  13. Three of a kind? The non-isotypic triple CsCe[P2Se6], CsSm[P2Se6] and CsEr[P2Se6]
  14. The crystal structure of ZrCr2D≈4 at 50 K ≤ T ≤ 200 K
  15. High-pressure synthesis and crystal structure of HP-Al2B3O7(OH)
  16. New layered supertetrahedral compounds T2-MSiAs2, T3-MGaSiAs3 and polytypic T4-M4Ga5SiAs9 (M = Sr, Eu)
  17. Comparative photophysical study of Pt(II) complex-nanoclay hybrid materials as dry powders and hydrogels
  18. Carbon subsulfide C3S2 – synthesis by flash vacuum pyrolysis and crystal structure determination
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