Startseite Naturwissenschaften 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
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9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update

  • Jenna K. Buchanan und Paul G. Plieger EMAIL logo
Veröffentlicht/Copyright: 18. April 2020
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 75 Heft 5

Abstract

9Be solution NMR spectroscopy is a useful tool for the characterisation of beryllium complexes. An updated comprehensive table of the 9Be NMR chemical shifts of beryllium complexes in solution is presented. The recent additions span a greater range of chemical shifts than those previously reported, and more overlap is observed between the chemical shift regions of four-coordinate complexes and those with lower coordination numbers. Four-coordinate beryllium species have smaller ω1/2 values than the two- and three-coordinate species due to their higher order symmetry. In contrast to previous studies, no clear relationship is observed between chemical shift and the size and number of chelate rings.

Keywords: 9Be NMR; beryllium complexes; chemical shift

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Received: 2020-01-17
Accepted: 2020-03-02
Published Online: 2020-04-18
Published in Print: 2020-05-26

©2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Progress in the chemistry and biochemistry of beryllium
  5. Research Articles
  6. Beryllium-associated diseases from a chemist’s point of view
  7. A consistent model for the key complex in chronic beryllium disease
  8. Reviews
  9. The role of beryllium in alloys, Zintl phases and intermetallic compounds
  10. Solid-state Be-9 NMR of beryllium compounds
  11. 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
  12. Research Articles
  13. Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
  14. Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
  15. A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
  16. Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
  17. Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
  18. Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
https://doi.org/10.1515/znb-2020-0007
Schlagwörter für diesen Artikel
9Be NMR; beryllium complexes; chemical shift

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Progress in the chemistry and biochemistry of beryllium
  5. Research Articles
  6. Beryllium-associated diseases from a chemist’s point of view
  7. A consistent model for the key complex in chronic beryllium disease
  8. Reviews
  9. The role of beryllium in alloys, Zintl phases and intermetallic compounds
  10. Solid-state Be-9 NMR of beryllium compounds
  11. 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
  12. Research Articles
  13. Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
  14. Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
  15. A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
  16. Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
  17. Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
  18. Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
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Heruntergeladen am 1.1.2026 von https://www.degruyterbrill.com/document/doi/10.1515/znb-2020-0007/html
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