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Solid-state Be-9 NMR of beryllium compounds

  • Hellmut Eckert EMAIL logo
Published/Copyright: April 10, 2020
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 75 Issue 5

Abstract

Despite the favorable NMR-spectroscopic features of the 9Be isotope, the exploration of solid Beryllium compounds by this method has been very limited, owing to safety concerns regarding their preparation and handling. The present review aims to be the first comprehensive one on this topic, summarizing the classical and modern methodologies available for determining the relevant 9Be NMR observables in the solid state. Results on molecular crystals, oxidic materials, and intermetallic systems will be discussed in terms of their informational content in relation to atomic and electronic structure and dynamics, leading to suggestions for future paths of investigation.

Keywords: beryllium-containing oxidic materials; beryllium coordination states; intermetallic compounds; solid-state NMR

Acknowledgements

This work was supported by FAPESP, process number 07793-6 and the Deutsche Forschungsgemeinschaft.

  1. Conflict of interest statement: I declare the absence of any conflict of interest.

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Received: 2020-02-09
Accepted: 2020-02-28
Published Online: 2020-04-10
Published in Print: 2020-05-26

©2020 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Progress in the chemistry and biochemistry of beryllium
  5. Research Articles
  6. Beryllium-associated diseases from a chemist’s point of view
  7. A consistent model for the key complex in chronic beryllium disease
  8. Reviews
  9. The role of beryllium in alloys, Zintl phases and intermetallic compounds
  10. Solid-state Be-9 NMR of beryllium compounds
  11. 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
  12. Research Articles
  13. Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
  14. Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
  15. A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
  16. Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
  17. Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
  18. Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
https://doi.org/10.1515/znb-2020-0026
Keywords for this article
beryllium-containing oxidic materials; beryllium coordination states; intermetallic compounds; solid-state NMR

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Progress in the chemistry and biochemistry of beryllium
  5. Research Articles
  6. Beryllium-associated diseases from a chemist’s point of view
  7. A consistent model for the key complex in chronic beryllium disease
  8. Reviews
  9. The role of beryllium in alloys, Zintl phases and intermetallic compounds
  10. Solid-state Be-9 NMR of beryllium compounds
  11. 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
  12. Research Articles
  13. Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
  14. Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
  15. A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
  16. Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
  17. Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
  18. Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
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