Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
-
Jacob E. Walley
,
Diane A. Dickie
und
Robert J. Gilliard
Abstract
Interest in beryllium, the lightest member of group 2 elements, has grown substantially within the synthetic community. Herein, we report the synthesis and crystal structure of a heteroleptic haloberyllium borohydride bis(1-isopropyl-3-methyl-benzimidazol-2-ylidene)methane ‘carbodicarbene’ (CDC) complex [(CDC)BeCl(BH4)]. Crystallographic data: Triclinic space group P1̅, a = 8.8695(14), b = 12.394(2), c = 16.844(3) Å, α = 102.395(4), β = 96.456(4), γ = 99.164(4)°, wR2 (all data) = 0.2706 for 6720 unique data and 357 refined parameters.
Acknowledgements
The authors acknowledge the University of Virginia for support of this work.
Notes: The authors declare no competing financial interest.
References
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©2020 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Progress in the chemistry and biochemistry of beryllium
- Research Articles
- Beryllium-associated diseases from a chemist’s point of view
- A consistent model for the key complex in chronic beryllium disease
- Reviews
- The role of beryllium in alloys, Zintl phases and intermetallic compounds
- Solid-state Be-9 NMR of beryllium compounds
- 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
- Research Articles
- Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
- Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
- A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
- Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
- Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
- Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Progress in the chemistry and biochemistry of beryllium
- Research Articles
- Beryllium-associated diseases from a chemist’s point of view
- A consistent model for the key complex in chronic beryllium disease
- Reviews
- The role of beryllium in alloys, Zintl phases and intermetallic compounds
- Solid-state Be-9 NMR of beryllium compounds
- 9Be nuclear magnetic resonance spectroscopy trends in discrete complexes: an update
- Research Articles
- Coordination chemistry of Be2+ ions with chelating oxygen donor ligands: further insights using electrospray mass spectrometry
- Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia
- A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
- Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex
- Hungry for charge – how a beryllium scorpionate complex “eats” a weakly coordinating anion
- Synthesis and crystal structures of β-[Be(DMF)4]I2, [Be(Pyr)4]I2, [Be(NMP)4]I2 and [BeI2(Lut)2]
