Startseite Maximum on the Electrical Conductivity Polytherm of Molten TeCl4
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Maximum on the Electrical Conductivity Polytherm of Molten TeCl4

  • Alexander B. Salyulev und Alexei M. Potapov EMAIL logo
Veröffentlicht/Copyright: 16. Mai 2017
Zeitschrift für Naturforschung A
Aus der Zeitschrift Zeitschrift für Naturforschung A Band 72 Heft 6

Abstract

The electrical conductivity of molten TeCl4 was measured up to 761K, i.e. 106 degrees above the normal boiling point of the salt. For the first time it was found that TeCl4 electrical conductivity polytherm has a maximum. It was recorded at 705K (κmax=0.245 Sm/cm), whereupon the conductivity decreases as the temperature rises. The activation energy of electrical conductivity was calculated.

Keywords: Activation Energy; Electrical Conductivity; Molten Salts; Tellurium Tetrachloride

References

[1] G. J. Janz, R. P. T. Tomkins, C. B. Allen, J. R. Downey, G. L. Gardner, et al., J. Phys. Chem. Ref. Data 4, 871 (1975).10.1063/1.555527Suche in Google Scholar

[2] L. F. Grantham and S. J. Yosim, J. Chem. Phys. 45, 1192 (1966).10.1063/1.1727737Suche in Google Scholar

[3] P. L. Spedding, Electrochim. Acta 18, 111 (1973).10.1016/0013-4686(73)87019-7Suche in Google Scholar

[4] A. B. Salyulev and А. А. Red’kin, Rasplavy (Melts) 3, 20 (1996) (in Russian).Suche in Google Scholar

[5] A. B. Salyulev and A. M. Potapov, Z. Naturforsch. 70a, 683 (2015).10.1515/zna-2015-0198Suche in Google Scholar

[6] A. B. Salyulev and A. M. Potapov, J. Chem. Eng. Data 60, 484 (2015).10.1021/je500433dSuche in Google Scholar

[7] Gmelins Handbuch der Anorganischen Chemie, System-Nummer 11, Tellur, Bd. B2, Springer Verlag, Berlin 1977.Suche in Google Scholar

[8] H. Bloom and I. A. Weeks, J. Chem. Soc. A 2028 (1969).10.1039/j19690002028Suche in Google Scholar

[9] A. Klemm, in: Molten Salt Chemistry (Ed. M. Blander), Interscience Publ., New York, London, Sydney 1964, p. 535.Suche in Google Scholar

[10] F. W. Poulsen and N. J. Bjerrum, J. Phys. Chem. 79, 1610 (1975).10.1021/j100582a028Suche in Google Scholar

[11] F. W. Poulsen and R. W. Berg, J. Inorg. Nucl. Chem. 40, 471 (1978).10.1016/0022-1902(78)80426-6Suche in Google Scholar

[12] A. L. Kuzmenko and V. V. Zvezdina, Khim. i Khim. Tekhn. (Chem. and Chem. Techn.) 11, 3 (1978) (in Rusian).Suche in Google Scholar

[13] D. Le Coq, B. Beuneu, and E. Bychkov, AIP Conf. Proc. 982, 712 (2008).10.1063/1.2897884Suche in Google Scholar

[14] D. Le Coq, A. Bytchkov, V. Honkimäki, B. Beuneu, and E. Bychkov, J. Non-Cryst. Solids 354, 259 (2008).10.1016/j.jnoncrysol.2007.07.099Suche in Google Scholar

[15] F. W. Poulsen, N. J. Bjerrum, and O. F. Nielsen, Inorg. Chem. 13, 2693 (1974).10.1021/ic50141a029Suche in Google Scholar

[16] N. P. Aravindakshan, C. M. Kuntz, K. E. Gemmell, and K. E. Johnson, J. Chem. Phys. 145, 094504 (2016).10.1063/1.4961687Suche in Google Scholar PubMed

Supplemental Material:

The online version of this article offers supplementary material (DOI: https://doi.org/10.1515/zna-2017-0072)

Received: 2017-3-1
Accepted: 2017-4-3
Published Online: 2017-5-16
Published in Print: 2017-5-24

©2017 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. Gravity beyond Einstein? Part I: Physics and the Trouble with Experiments
  4. Research Articles
  5. Mechanical, Dynamical and Thermodynamic Properties of Al-3wt%Mg from First Principles
  6. Gas Bubbles and Slugs Crossover in Air–Water Two-phase Flow by Multifractals
  7. Feinberg-Horodecki Equation with Pöschl-Teller Potential: Space-like Coherent States
  8. Approximate Solutions for the Nonlinear Third-Order Ordinary Differential Equations
  9. On Topological Indices of Certain Dendrimer Structures
  10. Increased Malleability in Tetragonal Zrx Ti1−x O2 Ternary Alloys: First-Principles Approach
  11. Generalised Multiplicative Indices of Polycyclic Aromatic Hydrocarbons and Benzenoid Systems
  12. Effect of Gravomagnetism on the Trajectory of Light Ray
  13. Rapid Communication
  14. Maximum on the Electrical Conductivity Polytherm of Molten TeCl4
https://doi.org/10.1515/zna-2017-0072
Schlagwörter für diesen Artikel
Activation Energy; Electrical Conductivity; Molten Salts; Tellurium Tetrachloride

Artikel in diesem Heft

  1. Frontmatter
  2. Review Article
  3. Gravity beyond Einstein? Part I: Physics and the Trouble with Experiments
  4. Research Articles
  5. Mechanical, Dynamical and Thermodynamic Properties of Al-3wt%Mg from First Principles
  6. Gas Bubbles and Slugs Crossover in Air–Water Two-phase Flow by Multifractals
  7. Feinberg-Horodecki Equation with Pöschl-Teller Potential: Space-like Coherent States
  8. Approximate Solutions for the Nonlinear Third-Order Ordinary Differential Equations
  9. On Topological Indices of Certain Dendrimer Structures
  10. Increased Malleability in Tetragonal Zrx Ti1−x O2 Ternary Alloys: First-Principles Approach
  11. Generalised Multiplicative Indices of Polycyclic Aromatic Hydrocarbons and Benzenoid Systems
  12. Effect of Gravomagnetism on the Trajectory of Light Ray
  13. Rapid Communication
  14. Maximum on the Electrical Conductivity Polytherm of Molten TeCl4
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 3.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zna-2017-0072/html?lang=de
Button zum nach oben scrollen