Layered structures based on antimony tartrate dimers
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Xiqu Wang
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Allan J. Jacobson
Abstract
Four complex metal antimony tartrates have been synthesized in single crystal form by slowly evaporating aqueous solutions of potassium antimony tartrate (tartar emetic) and metal nitrates or chlorides. Crystal structures of these compounds all contain infinite layers formed by linking antimony tartrate dimers with M–O bonds, with M = Li, La, Ce or Nd. Dehydration of the La and Ce compounds at elevated temperatures led to new layered structures via single-crystal to single-crystal transformations.
Funding source: Robert. A. Welch Foundation
Award Identifier / Grant number: E-0024
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was funded by Robert A. Welch Foundation (Grant No. E-0024).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
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Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Crystal structure and magnetic properties of some compounds with GdNi2Ga3In type structure
- Partially disordered pyrochlore: time-temperature dependence of recrystallization and dehydration
- Lu37Ru16.4In4 – coloring and vacancy formation in a new structure type closely related to a 8 × 8 × 8 bcc superstructure
- BaFe0.875Re0.125O3−δ and BaFe0.75Ta0.25O3−δ as potential cathodes for solid-oxide fuel-cells: a structural study from neutron diffraction data
- Unbalanced racemates: solid state solutions containing enantiomeric pairs crystallizing in Sohncke space groups with (L:D) ratios other than (1:1) – illustrated with crystals of a Co(III) coordination compound
- Crystal structure and specific heat of calcium lanthanide oxyborates Ca4LnO(BO3)3
- Order-disorder (OD) structures of Rb2Zn(TeO3)(CO3)·H2O and Na2Zn2Te4O11
- Na2Cu+[Cu2+3O](AsO4)2Cl and Cu3[Cu3O]2(PO4)4Cl2: two new structure types based upon chains of oxocentered tetrahedra
- Organic and Metalorganic Crystal Structures (Original Paper)
- Two isomers Ba5Mg4C54O48H114 and Pb5Mg4C54O48H114
- Layered structures based on antimony tartrate dimers
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Crystal structure and magnetic properties of some compounds with GdNi2Ga3In type structure
- Partially disordered pyrochlore: time-temperature dependence of recrystallization and dehydration
- Lu37Ru16.4In4 – coloring and vacancy formation in a new structure type closely related to a 8 × 8 × 8 bcc superstructure
- BaFe0.875Re0.125O3−δ and BaFe0.75Ta0.25O3−δ as potential cathodes for solid-oxide fuel-cells: a structural study from neutron diffraction data
- Unbalanced racemates: solid state solutions containing enantiomeric pairs crystallizing in Sohncke space groups with (L:D) ratios other than (1:1) – illustrated with crystals of a Co(III) coordination compound
- Crystal structure and specific heat of calcium lanthanide oxyborates Ca4LnO(BO3)3
- Order-disorder (OD) structures of Rb2Zn(TeO3)(CO3)·H2O and Na2Zn2Te4O11
- Na2Cu+[Cu2+3O](AsO4)2Cl and Cu3[Cu3O]2(PO4)4Cl2: two new structure types based upon chains of oxocentered tetrahedra
- Organic and Metalorganic Crystal Structures (Original Paper)
- Two isomers Ba5Mg4C54O48H114 and Pb5Mg4C54O48H114
- Layered structures based on antimony tartrate dimers
