Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
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Yuheng Li
Yuheng Li postgraduate School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P.R. China.
Yue Lei postgraduate, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P.R. China.
Haiyan Gao associate professor, she received a doctorate in science from the Institute of Coal Chemistry, Chinese Academy of Sciences in 2003. Research direction is physical chemistry, synthesis and application of chemicals, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China
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Liangliang Lin
Liangliang Lin associated professor, he received his Ph.D. degree from Eindhoven University of Technology in 2018, major in chemical engineering. His research interests include process intensification, surfactants, and microreactors. School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China.
Hujun Xu professor, he received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 70 papers in the field of surfactants and detergents, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China.
Abstract
In this study, the interaction between a diester amide Gemini surfactant (C12–E2Ph–C12) and the non-ionic polymer polyethylene glycol (PEG) with average molecular weights of 6000 g mol−1 and 10,000 g mol−1 was investigated using the surface tension method. The study showed no discernible interaction between them. Further examinations, using surface tension, micropolarity and turbidity methods were conducted to investigate the interaction between C12–E2Ph–C12 and the anionic polymer sodium alginate (NaAlg). C12–E2Ph–C12 and NaAlg molecules bind together to form aggregates with a pearl necklace-like structure, driven by electrostatic attraction. This interaction is evident in both the surface tension and micropolarity curves, where double plateaus appear. The inorganic salt NaCl exhibited a dual influence on the interaction between C12–E2Ph–C12 and NaAlg, manifesting as either salt enhancement or reduction, depending on their competitive effects. Additionally, the dyeing performance of the different surfactants on two types of dyes was investigated using a colorimeter. C12–E2Ph–C12 showed favorable effects on dyeing uniformity, color fastness, and improvement of hair tensile strength. Hair dyeing results were satisfactory when C12–E2Ph–C12 was included as a uniform coloring agent and NaAlg was used as a thickening agent in the hair dye formulation.
About the authors
Yuheng Li postgraduate School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P.R. China.
Yue Lei postgraduate, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P.R. China.
Haiyan Gao associate professor, she received a doctorate in science from the Institute of Coal Chemistry, Chinese Academy of Sciences in 2003. Research direction is physical chemistry, synthesis and application of chemicals, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China.
Liangliang Lin associated professor, he received his Ph.D. degree from Eindhoven University of Technology in 2018, major in chemical engineering. His research interests include process intensification, surfactants, and microreactors. School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China.
Hujun Xu professor, he received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 70 papers in the field of surfactants and detergents, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, P. R. China.
Acknowledgments
Thank you to my mentor Gao Haiyan for her careful guidance. I would like to express my gratitude to Senior Sister Lei Yue, Senior Brother Zhou Yue, and fellow laboratory mates for their assistance during the experimental process. Special thanks to the instructors of various testing instruments for their patient guidance during my experiments.
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Research ethics: Not applicable.
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Author contributions: Yuheng Li: experimental design, experiment execution, data collection and analysis, figure creation, manuscript writing. Yue Lei: experimental design. Haiyan Gao: experimental design, review and editing. Liangliang Lin: technical support, review and editing. Hujun Xu: technical support, review and editing.
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Competing interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: Not applicable.
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© 2024 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Review Articles
- A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
- A critical review on scale-up strategies of biosurfactant production and its applications
- Physical Chemistry
- Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
- Application
- Study on modified graphene oxide-based emulsion cleaner for oily sludge
- Gemini Surfactants
- Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
- Surface Active Ionic Liquids
- Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
- Drug Delivery System
- Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
- Detergent Ingredients
- Thermodynamic and surface active investigations of aqueous solution of sodium dodecylbenzene sulfonate in presence of builders: sequestration of Ca2+ ions and interaction with H2O2
Artikel in diesem Heft
- Frontmatter
- Review Articles
- A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
- A critical review on scale-up strategies of biosurfactant production and its applications
- Physical Chemistry
- Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
- Application
- Study on modified graphene oxide-based emulsion cleaner for oily sludge
- Gemini Surfactants
- Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
- Surface Active Ionic Liquids
- Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
- Drug Delivery System
- Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
- Detergent Ingredients
- Thermodynamic and surface active investigations of aqueous solution of sodium dodecylbenzene sulfonate in presence of builders: sequestration of Ca2+ ions and interaction with H2O2
