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Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)

  • Pooja Sharma

    Pooja Sharma was born in 1994 in India. She received her bachelor’s degree in 2015 from Punjabi university Patiala and master’s degree in Chemistry in 2017 from Thapar University, Patiala, India. She completed her PhD in 2023 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behavior of surface-active ionic liquids. She is currently working as an assistant professor at lovely professional university Phagwara.

     EMAIL logo     , Shubham Sharma

    Dr Shubham Sharma was born in Uttarakhand, India. He completed his Bachelor and Master’s degree from MJP Rohilkhand University Bareilly, UP (India). After that, he did PhD from Dr B R Ambedkar NIT Jalandhar, Punjab, India. Currently, he is working at GLA University, Mathura, UP, India as an Assistant Professor. His research interests include synthesis of nitrogen containing heterocycles.

         , Bharti Budhalakoti

    Bharti Budhalakoti was born in Uttarakhand, India. She completed her graduation from Indira Priyadarshini Govt. Girls Degree College, Haldwani. She then completed her M.Sc. from Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab) in the year 2019. She is now a research scholar at Department of Chemistry Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab)

         and Harsh Kumar

    Harsh Kumar was born in 1977 in India. He received his bachelor’s, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. He was working as an Associate Professor in the same department. He had 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He had supervised more than 50 candidates for masters and doctoral thesis. He had published more than 200 papers in national and international journals. His research interests were Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behavior of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.
Published/Copyright: July 3, 2024
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 61 Issue 4

Abstract

This study investigated the influence of vitamin B7 (biotin) at different concentrations (0.1, 0.3 and 0.5) mM on the micellisation behaviour of three different ionic liquids with different cationic headgroups, namely N-methylmorpholinium bromide [Mor1,12][Br], N-dodecyl-N-methylpyrrolidinium bromide [Pyrr1,12][Br], and 1-dodecyl-3-methylimidazolium bromide [C12mim][Br], at four different temperatures (298.15, 303.15, 308.15, and 313.15) K using electrical conductivity and surface tension measurements. The evaluated CMC values for the studied system were used to obtain information about the colloidal behavior of the ionic liquids in the presence of biotin. The different thermodynamic parameters were studied. Tensiometry was used to determine the interfacial properties. The parameters obtained were used to study the different types of interactions for micelle formation. The main objective of studying these interactions is to further utilize this type of mixture in pharmaceutical industry, medicinal chemistry, and bio industry.

Keywords: surface active ionic liquid (SAIL); biotin; electrical conductivity; micellization; surface tension; interfacial behavior
Corresponding author: Pooja Sharma, Department of Chemistry, Lovely Professional University, Phagwara 144401, Punjab, India; and Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India, E-mail:

About the authors

Pooja Sharma

Pooja Sharma was born in 1994 in India. She received her bachelor’s degree in 2015 from Punjabi university Patiala and master’s degree in Chemistry in 2017 from Thapar University, Patiala, India. She completed her PhD in 2023 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behavior of surface-active ionic liquids. She is currently working as an assistant professor at lovely professional university Phagwara.

Shubham Sharma

Dr Shubham Sharma was born in Uttarakhand, India. He completed his Bachelor and Master’s degree from MJP Rohilkhand University Bareilly, UP (India). After that, he did PhD from Dr B R Ambedkar NIT Jalandhar, Punjab, India. Currently, he is working at GLA University, Mathura, UP, India as an Assistant Professor. His research interests include synthesis of nitrogen containing heterocycles.

Bharti Budhalakoti

Bharti Budhalakoti was born in Uttarakhand, India. She completed her graduation from Indira Priyadarshini Govt. Girls Degree College, Haldwani. She then completed her M.Sc. from Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab) in the year 2019. She is now a research scholar at Department of Chemistry Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab)

Harsh Kumar

Harsh Kumar was born in 1977 in India. He received his bachelor’s, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. He was working as an Associate Professor in the same department. He had 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He had supervised more than 50 candidates for masters and doctoral thesis. He had published more than 200 papers in national and international journals. His research interests were Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behavior of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

  4. Research funding: None declared.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/tsd-2024-2597).

Received: 2024-03-29
Accepted: 2024-06-04
Published Online: 2024-07-03
Published in Print: 2024-07-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Review Articles
  3. A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
  4. A critical review on scale-up strategies of biosurfactant production and its applications
  5. Physical Chemistry
  6. Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
  7. Application
  8. Study on modified graphene oxide-based emulsion cleaner for oily sludge
  9. Gemini Surfactants
  10. Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
  11. Surface Active Ionic Liquids
  12. Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
  13. Drug Delivery System
  14. Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
  15. Detergent Ingredients
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https://doi.org/10.1515/tsd-2024-2597
Keywords for this article
surface active ionic liquid (SAIL); biotin; electrical conductivity; micellization; surface tension; interfacial behavior

Articles in the same Issue

  1. Frontmatter
  2. Review Articles
  3. A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
  4. A critical review on scale-up strategies of biosurfactant production and its applications
  5. Physical Chemistry
  6. Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
  7. Application
  8. Study on modified graphene oxide-based emulsion cleaner for oily sludge
  9. Gemini Surfactants
  10. Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
  11. Surface Active Ionic Liquids
  12. Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
  13. Drug Delivery System
  14. Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
  15. Detergent Ingredients
  16. Thermodynamic and surface active investigations of aqueous solution of sodium dodecylbenzene sulfonate in presence of builders: sequestration of Ca2+ ions and interaction with H2O2
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