Home Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
Article
Licensed
Unlicensed Requires Authentication

Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)

  • Pooja Sharma

    Pooja Sharma was born in 1994 in India. She received her bachelor’s degree in 2015 from Punjabi university Patiala and master’s degree in Chemistry in 2017 from Thapar University, Patiala, India. She completed her PhD in 2023 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behavior of surface-active ionic liquids. She is currently working as an assistant professor at lovely professional university Phagwara.

     EMAIL logo     , Shubham Sharma

    Dr Shubham Sharma was born in Uttarakhand, India. He completed his Bachelor and Master’s degree from MJP Rohilkhand University Bareilly, UP (India). After that, he did PhD from Dr B R Ambedkar NIT Jalandhar, Punjab, India. Currently, he is working at GLA University, Mathura, UP, India as an Assistant Professor. His research interests include synthesis of nitrogen containing heterocycles.

         , Bharti Budhalakoti

    Bharti Budhalakoti was born in Uttarakhand, India. She completed her graduation from Indira Priyadarshini Govt. Girls Degree College, Haldwani. She then completed her M.Sc. from Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab) in the year 2019. She is now a research scholar at Department of Chemistry Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab)

         and Harsh Kumar

    Harsh Kumar was born in 1977 in India. He received his bachelor’s, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. He was working as an Associate Professor in the same department. He had 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He had supervised more than 50 candidates for masters and doctoral thesis. He had published more than 200 papers in national and international journals. His research interests were Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behavior of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.
Published/Copyright: July 3, 2024
Become an author with De Gruyter Brill
Author Information
Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 61 Issue 4

Abstract

This study investigated the influence of vitamin B7 (biotin) at different concentrations (0.1, 0.3 and 0.5) mM on the micellisation behaviour of three different ionic liquids with different cationic headgroups, namely N-methylmorpholinium bromide [Mor1,12][Br], N-dodecyl-N-methylpyrrolidinium bromide [Pyrr1,12][Br], and 1-dodecyl-3-methylimidazolium bromide [C12mim][Br], at four different temperatures (298.15, 303.15, 308.15, and 313.15) K using electrical conductivity and surface tension measurements. The evaluated CMC values for the studied system were used to obtain information about the colloidal behavior of the ionic liquids in the presence of biotin. The different thermodynamic parameters were studied. Tensiometry was used to determine the interfacial properties. The parameters obtained were used to study the different types of interactions for micelle formation. The main objective of studying these interactions is to further utilize this type of mixture in pharmaceutical industry, medicinal chemistry, and bio industry.

Keywords: surface active ionic liquid (SAIL); biotin; electrical conductivity; micellization; surface tension; interfacial behavior
Corresponding author: Pooja Sharma, Department of Chemistry, Lovely Professional University, Phagwara 144401, Punjab, India; and Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India, E-mail:

About the authors

Pooja Sharma

Pooja Sharma was born in 1994 in India. She received her bachelor’s degree in 2015 from Punjabi university Patiala and master’s degree in Chemistry in 2017 from Thapar University, Patiala, India. She completed her PhD in 2023 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behavior of surface-active ionic liquids. She is currently working as an assistant professor at lovely professional university Phagwara.

Shubham Sharma

Dr Shubham Sharma was born in Uttarakhand, India. He completed his Bachelor and Master’s degree from MJP Rohilkhand University Bareilly, UP (India). After that, he did PhD from Dr B R Ambedkar NIT Jalandhar, Punjab, India. Currently, he is working at GLA University, Mathura, UP, India as an Assistant Professor. His research interests include synthesis of nitrogen containing heterocycles.

Bharti Budhalakoti

Bharti Budhalakoti was born in Uttarakhand, India. She completed her graduation from Indira Priyadarshini Govt. Girls Degree College, Haldwani. She then completed her M.Sc. from Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab) in the year 2019. She is now a research scholar at Department of Chemistry Dr BR Ambedkar National Institute of Technology, Jalandhar (Punjab)

Harsh Kumar

Harsh Kumar was born in 1977 in India. He received his bachelor’s, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. He was working as an Associate Professor in the same department. He had 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He had supervised more than 50 candidates for masters and doctoral thesis. He had published more than 200 papers in national and international journals. His research interests were Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behavior of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

  4. Research funding: None declared.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

References

1. Sarkar, A.; Sinha, B. Effect of Tetrabutylammonium Hydrogen Sulphate on the Solution Thermodynamics of Thiamine Hydrochloride in Aqueous Solutions. J. Mol. Liq. 2016, 223, 321–328. https://doi.org/10.1016/j.molliq.2016.08.072.Search in Google Scholar

2. Rodriguez-Melendez, R.; Zempleni, J. Regulation of Gene Expression by Biotin. J. Nutr. Biochem. 2003, 14 (12), 680–690. https://doi.org/10.1016/j.jnutbio.2003.07.001.Search in Google Scholar PubMed

3. Mittal, H.; Al Alili, A.; Morajkar, P. P.; Alhassan, S. M. Graphene Oxide Crosslinked Hydrogel Nanocomposites of Xanthan Gum for the Adsorption of Crystal Violet Dye. J. Mol. Liq. 2021, 323, 115034. https://doi.org/10.1016/j.molliq.2020.115034.Search in Google Scholar

4. Singh, A.; Sharma, S.; Kaur, N.; Singh, N. Self-Assembly of Imidazolium/Benzimidazolium Cationic Receptors: Their Environmental and Biological Applications. New J. Chem. 2020, 44 (44), 19360–19375. https://doi.org/10.1039/D0NJ03836A.Search in Google Scholar

5. Li, Q.; Tong, K.; Sun, M.; Yao, M.; Zhuang, W.; Pan, Y.; Chen, X. The Self-Assembly of an Imidazolium Surfactant in an Aprotic Ionic Liquid. 1. Comparison in Aprotic and Protic Ionic Liquids. Soft Matter 2020, 16 (31), 7246–7249. https://doi.org/10.1039/D0SM01246G.Search in Google Scholar

6. Losetty, V.; Chennuri, B. K.; Gardas, R. L. Synthesis, Spectroscopic Characterization and Acoustic, Volumetric, Transport and Thermal Properties of Hydroxyl Ammonium Based Ionic Liquids. J. Chem. Thermodyn. 2016, 92, 175–181. https://doi.org/10.1016/j.jct.2015.09.016.Search in Google Scholar

7. Abbott, A. P.; Frisch, G.; Hartley, J.; Ryder, K. S. Processing of Metals and Metal Oxides Using Ionic Liquids. Green Chem. 2011, 13 (3), 471–481. https://doi.org/10.1039/C0GC00716A.Search in Google Scholar

8. Mittal, H.; Al Alili, A.; Morajkar, P. P.; Alhassan, S. M. GO Crosslinked Hydrogel Nanocomposites of Chitosan/carboxymethyl Cellulose–A Versatile Adsorbent for the Treatment of Dyes Contaminated Wastewater. Int. J. Biol. Macromol. 2021, 167, 1248–1261. https://doi.org/10.1016/j.ijbiomac.2020.11.079.Search in Google Scholar PubMed

9. Mittal, H.; Al Alili, A.; Alhassan, S. M. High Efficiency Removal of Methylene Blue Dye Using κ-carrageenan-poly (Acrylamide-co-methacrylic acid)/AQSOA-Z05 Zeolite Hydrogel Composites. Cellulose 2020, 27, 8269–8285. https://doi.org/10.1007/s10570-020-03365-6.Search in Google Scholar

10. Mittal, H.; Al Alili, A.; Alhassan, S. M. Solid Polymer Desiccants Based on Poly (Acrylic Acid-Co-Acrylamide) and Laponite RD: Adsorption Isotherm and Kinetics Studies. Colloids Surf., A 2020, 599, 124813. https://doi.org/10.1016/j.colsurfa.2020.124813.Search in Google Scholar

11. Buettner, C. S.; Cognigni, A.; Schröder, C.; Bica-Schröder, K. Surface-active Ionic Liquids: A Review. J. Mol. Liq. 2022, 347, 118160. https://doi.org/10.1016/j.molliq.2021.118160.Search in Google Scholar

12. Vanyúr, R.; Biczók, L.; Miskolczy, Z. Micelle Formation of 1-Alkyl-3-Methylimidazolium Bromide Ionic Liquids in Aqueous Solution. Colloids Surf., A 2007, 299 (1-3), 256–261. https://doi.org/10.1016/j.colsurfa.2006.11.049.Search in Google Scholar

13. Ao, M.; Kim, D. Aggregation Behavior of Aqueous Solutions of 1-Dodecyl-3-Methylimidazolium Salts with Different Halide Anions. J. Chem. Eng. Data 2013, 58 (6), 1529–1534. https://doi.org/10.1021/je301147k.Search in Google Scholar

14. Cornellas, A.; Perez, L.; Comelles, F.; Ribosa, I.; Manresa, A.; Garcia, M. T. Self-aggregation and Antimicrobial Activity of Imidazolium and Pyridinium Based Ionic Liquids in Aqueous Solution. J. Colloid Interface Sci. 2011, 355 (1), 164–171. https://doi.org/10.1016/j.jcis.2010.11.063.Search in Google Scholar PubMed

15. Naushad, M. J. C. E. J. Surfactant Assisted Nano-Composite Cation Exchanger: Development, Characterization and Applications for the Removal of Toxic Pb2+ from Aqueous Medium. Chem. Eng. J. 2014, 235, 100–108. https://doi.org/10.1016/j.cej.2013.09.013.Search in Google Scholar

16. Naushad, M.; ALOthman, Z. A. Separation of Toxic Pb2+ Metal from Aqueous Solution Using Strongly Acidic Cation-Exchange Resin: Analytical Applications for the Removal of Metal Ions from Pharmaceutical Formulation. Desalin. Water Treat. 2015, 53 (8), 2158–2166. https://doi.org/10.1080/19443994.2013.862744.Search in Google Scholar

17. Lee, B. H. Effects of Various Alcohols and Salts on the Mixed Micellization of Cationic Surfactant (CPC) with Nonionic Surfactant (TX-100). Colloid Interface Sci. Commun. 2017, 19, 1–4. https://doi.org/10.1016/j.colcom.2017.05.001.Search in Google Scholar

18. Wang, H.; Feng, Q.; Wang, J.; Zhang, H. Salt Effect on the Aggregation Behavior of 1-Decyl-3-Methylimidazolium Bromide in Aqueous Solutions. J. Phys. Chem. B 2010, 114 (3), 1380–1387. https://doi.org/10.1021/jp910903s.Search in Google Scholar PubMed

19. Pyne, A.; Kuchlyan, J.; Maiti, C.; Dhara, D.; Sarkar, N. Cholesterol Based Surface Active Ionic Liquid that Can Form Microemulsions and Spontaneous Vesicles. Langmuir 2017, 33 (23), 5891–5899. https://doi.org/10.1021/acs.langmuir.7b01158.Search in Google Scholar PubMed

20. Wojcieszak, M.; Syguda, A.; Karolak, M.; Pałkowski, Ł.; Materna, K. Quaternary Ammonium Salts Based on Caprylic Acid as Antimicrobial and Surface-Active Agents. RSC Adv. 2023, 13 (49), 34782–34797. https://doi.org/10.1039/D3RA07127H.Search in Google Scholar

21. Pałkowski, Ł.; Karolak, M.; Skrzypczak, A.; Wojcieszak, M.; Walkiewicz, F.; Podemski, J.; Krysiński, J.; Bojko, B.; Materna, K.; Krysiński, J. Antimicrobial and Cytotoxic Activity of Novel Imidazolium-Based Ionic Liquids. Molecules 2022, 27 (6), 1974. https://doi.org/10.3390/molecules27061974.Search in Google Scholar PubMed PubMed Central

22. Singh, G.; Kamboj, R.; Mithu, V. S.; Chauhan, V.; Kaur, T.; Kaur, G.; Kang, T. S.; Singh Kang, T. Nicotine-based Surface Active Ionic Liquids: Synthesis, Self-Assembly and Cytotoxicity Studies. J. Colloid Interface Sci. 2017, 496, 278–289. https://doi.org/10.1016/j.jcis.2017.02.021.Search in Google Scholar PubMed

23. Egorova, K. S.; Gordeev, E. G.; Ananikov, V. P. Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine. Chem. Rev. 2017, 117 (10), 7132–7189. https://doi.org/10.1021/acs.chemrev.6b00562.Search in Google Scholar PubMed

24. Singh, G.; Kaur, M.; Kaur, H.; Kang, T. S. Synthesis and Complexation of a New Caffeine Based Surface Active Ionic Liquid with Lysozyme in Aqueous Medium: Physicochemical, Computational and Antimicrobial Studies. J. Mol. Liq. 2021, 325, 115156. https://doi.org/10.1016/j.molliq.2020.115156.Search in Google Scholar

25. Garcia, M. T.; Gathergood, N.; Scammells, P. J. Biodegradable Ionic Liquids Part II. Effect of the Anion and Toxicology. Green Chem. 2005, 7 (1), 9–14. https://doi.org/10.1039/b411922c.Search in Google Scholar

26. Yang, Y.; McClements, D. J. Encapsulation of Vitamin E in Edible Emulsions Fabricated Using a Natural Surfactant. Food Hydrocolloids 2013, 30 (2), 712–720. https://doi.org/10.1016/j.foodhyd.2012.09.003.Search in Google Scholar

27. Kumar, H.; Sharma, P. Unraveling the Micellization Behavior and Thermodynamic Characteristics of Imidazolium-Based Ionic Liquid in Presence of Vitamins Thiamine Hydrochloride and Ascorbic Acid. Colloids Surf., A 2021, 630, 127563. https://doi.org/10.1016/j.colsurfa.2021.127563.Search in Google Scholar

28. Sharma, P.; Kumar, H.; Singla, M.; Ghfar, A. A.; Pandey, S. Micellization, Surface Activities, and Thermodynamic Studies on the Ionic Liquid in the Presence of Vitamins. J. Mol. Liq. 2022, 359, 119152. https://doi.org/10.1016/j.molliq.2022.119152.Search in Google Scholar

29. Pal, A.; Deenadayalu, N.; Chaudhary, S. Effect of Hydrophilic Ionic Liquid on the Micellar Properties of Aqueous Tween-20. Fluid Phase Equilib. 2015, 391, 67–71. https://doi.org/10.1016/j.fluid.2015.02.005.Search in Google Scholar

30. Ruso, J. M.; Taboada, P.; Mosquera, V.; Sarmiento, F. Thermodynamics of Micellization of N-Alkyl Sulfates in an Alkaline Medium at Different Temperatures. J. Colloid Interface Sci. 1999, 214 (2), 292–296. https://doi.org/10.1006/jcis.1999.6198.Search in Google Scholar PubMed

31. Nusselder, J. J. H.; Engberts, J. B. Toward a Better Understanding of the Driving Force for Micelle Formation and Micellar Growth. J. Colloid Interface Sci. 1992, 148 (2), 353–361. https://doi.org/10.1016/0021-9797(92)90174-K.Search in Google Scholar

32. Aggarwal, R.; Khullar, P.; Mandial, D.; Mahal, A.; Ahluwalia, G. K.; Bakshi, M. S. Bipyridinium and Imidazolium Ionic Liquids for Nanomaterials Synthesis: PH Effect, Phase Transfer Behavior, and Protein Extraction. ACS Sustain. Chem. Eng. 2017, 5 (9), 7859–7870. https://doi.org/10.1021/acssuschemeng.7b01368.Search in Google Scholar

33. Bakshi, M. S.; Singh, J.; Kaur, J. Estimation of Degree of Counterion Binding and Thermodynamic Parameters of Ionic Surfactants from Cloud Point Measurements by Using Triblock Polymer as Probe. J. Colloid Interface Sci. 2005, 287 (2), 704–711. https://doi.org/10.1016/j.jcis.2005.02.040.Search in Google Scholar PubMed

34. Huang, J. B.; Mao, M.; Zhu, B. Y. The Surface Physico-Chemical Properties of Surfactants in Ethanol–Water Mixtures. Colloids Surf., A 1999, 155 (2-3), 339–348. https://doi.org/10.1016/S0927-7757(99)00003-5.Search in Google Scholar

35. Oida, T.; Nakashima, N.; Nagadome, S.; Ko, J. S.; Oh, S. W.; Sugihara, G. Adsorption and Micelle Formation of Mixed Surfactant Systems in Water. III. A Comparison between Cationic Gemini/cationic and Cationic Gemini/nonionic Combinations. J. Oleo Sci. 2003, 52 (10), 509–522. https://doi.org/10.5650/jos.52.509.Search in Google Scholar

Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/tsd-2024-2597).

Received: 2024-03-29
Accepted: 2024-06-04
Published Online: 2024-07-03
Published in Print: 2024-07-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Review Articles
  3. A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
  4. A critical review on scale-up strategies of biosurfactant production and its applications
  5. Physical Chemistry
  6. Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
  7. Application
  8. Study on modified graphene oxide-based emulsion cleaner for oily sludge
  9. Gemini Surfactants
  10. Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
  11. Surface Active Ionic Liquids
  12. Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
  13. Drug Delivery System
  14. Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
  15. Detergent Ingredients
  16. Thermodynamic and surface active investigations of aqueous solution of sodium dodecylbenzene sulfonate in presence of builders: sequestration of Ca2+ ions and interaction with H2O2
https://doi.org/10.1515/tsd-2024-2597
Keywords for this article
surface active ionic liquid (SAIL); biotin; electrical conductivity; micellization; surface tension; interfacial behavior

Articles in the same Issue

  1. Frontmatter
  2. Review Articles
  3. A mini review on the applications of artificial intelligence (AI) in surface chemistry and catalysis
  4. A critical review on scale-up strategies of biosurfactant production and its applications
  5. Physical Chemistry
  6. Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface
  7. Application
  8. Study on modified graphene oxide-based emulsion cleaner for oily sludge
  9. Gemini Surfactants
  10. Interactions between diester amide Gemini surfactants and polymers, and their application in hair dyes
  11. Surface Active Ionic Liquids
  12. Thermodynamic characteristics and aggregation behavior of surface active ionic liquids in presence of vitamin B7 (biotin)
  13. Drug Delivery System
  14. Determination of resveratrol in nanoformulations using UV-spectroscopy: forced degradation and drug entrapment
  15. Detergent Ingredients
  16. Thermodynamic and surface active investigations of aqueous solution of sodium dodecylbenzene sulfonate in presence of builders: sequestration of Ca2+ ions and interaction with H2O2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 13.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/tsd-2024-2597/html
Scroll to top button