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Study on the adsorption performance of zeolite imidazole frameworks materials for Co(II) and Mn(II) in solution

  • Ping Bao , Yipeng Zhou , Xiaowei Wang , Jinfeng Men , Chengqiang Liang EMAIL logo and Hao Ding EMAIL logo
Published/Copyright: July 24, 2024
Radiochimica Acta
From the journal Radiochimica Acta Volume 112 Issue 11

Abstract

The radionuclides 60Co and 54Mn are the main activation products produced in the operation of nuclear power facilities. Wastewater with these radionuclides must be treated to meet standards before being discharged. A variety of zeolite imidazole frameworks (ZIFs) materials were synthesized at room temperature, and the adsorption effect of ZIF-67 was found to be the best through adsorption experiments on Co(II) and Mn(II). The thermal stability test and structural characterization of ZIF-67 were carried out. At the same time, the influence of the initial pH value, adsorption time, and initial concentration of the solution on the adsorption of Co(II) and Mn(II) by ZIF-67 was investigated. The results show that: ZIF-67 has a microporous structure with a BET surface area of 1,035.72 m2/g. In addition, ZIF-67 has good thermal stability, under the condition of pH = 6, a temperature of 303 K and the initial concentration of 500 mg/L. The saturated adsorption capacity for Co(II) and Mn(II) reached 230.25 mg/g and 338.75 mg/g, respectively. ZIF-67 exhibits good selective adsorption performance for Co(II) and Mn (II) in high concentration interfering ion solutions and multi-ion solutions. The adsorption process of ZIF-67 was analyzed by kinetics, thermodynamics, isotherms, and adsorption diffusion models. The analysis of thermodynamic parameters shows that the adsorption process of ZIF-67 to Co(II) and Mn(II) is spontaneous and endothermic. The pseudo-second-order kinetic model, Langmuir isotherm model, and Boyd model are more in line with the adsorption process of Co(II) and Mn(II) by ZIF-67. It shows that the active sites on the surface of ZIF-67 are evenly distributed, and the adsorption process is single-molecule chemical layer adsorption. In addition, the liquid film diffusion dominates the adsorption rate during the adsorption process of Co(II) and Mn(II) by ZIF-67.

Keywords: cobalt; manganese; activation products; ZIF-67; adsorption
Corresponding authors: Chengqiang Liang and Hao Ding, Department of Nuclear Science and Engineering, Naval University of Engineering, Wuhan, 430033, China, E-mail: (C. Liang), (H. Ding).

  1. Research ethics: Not applicable.

  2. Author contributions: Ping Bao: conceptualization, methodology, experiment and original draft preparation. Yipeng Zhou: data analysis and writing. Xiaowei Wang: data analysis and writing. Jinfeng Men: data analysis, writing. Chengqiang Liang: data analysis, writing and supervision. Hao Ding: writing, reviewing and editing.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Received: 2024-01-14
Accepted: 2024-07-07
Published Online: 2024-07-24
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Independent isomeric yield ratios of fission products in the epi-cadmium neutron-induced fission of 245Cm
  4. Preparation of MnO2 modified winter melon-derived biochar for enhanced adsorption of U(VI) from aqueous solution
  5. Separation studies of 60Co (II) and 134Cs (I) radionuclides from aqueous solution using starch-grafted citric acid-acrylamide/magnesia hydrogel
  6. Study on the adsorption performance of zeolite imidazole frameworks materials for Co(II) and Mn(II) in solution
  7. Synthesis, in silico and biodistribution studies of a novel 47Sc-radiolabeled α-amino acid ester derivative attached to pyrazine and tetrazole rings for tumor targeted radiotherapy
  8. [113mIn]In-PSMA: high potential agent for SPECT imaging of prostate cancer
  9. Physicochemical model of uranium hexafluoride (UF6) radiolysis under action of alpha particles
  10. Identification and time evolution of thionyl chloride (SOCl2) radiolysis products
  11. Measurement of gross alpha radioactivity levels and estimation of annual effective dose in hazelnut kernels
  12. Characterization of ferrous-xylenol orange-polyvinyl alcohol gel for gamma dosimetry using spectroscopy
https://doi.org/10.1515/ract-2024-0274
Keywords for this article
cobalt; manganese; activation products; ZIF-67; adsorption

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Independent isomeric yield ratios of fission products in the epi-cadmium neutron-induced fission of 245Cm
  4. Preparation of MnO2 modified winter melon-derived biochar for enhanced adsorption of U(VI) from aqueous solution
  5. Separation studies of 60Co (II) and 134Cs (I) radionuclides from aqueous solution using starch-grafted citric acid-acrylamide/magnesia hydrogel
  6. Study on the adsorption performance of zeolite imidazole frameworks materials for Co(II) and Mn(II) in solution
  7. Synthesis, in silico and biodistribution studies of a novel 47Sc-radiolabeled α-amino acid ester derivative attached to pyrazine and tetrazole rings for tumor targeted radiotherapy
  8. [113mIn]In-PSMA: high potential agent for SPECT imaging of prostate cancer
  9. Physicochemical model of uranium hexafluoride (UF6) radiolysis under action of alpha particles
  10. Identification and time evolution of thionyl chloride (SOCl2) radiolysis products
  11. Measurement of gross alpha radioactivity levels and estimation of annual effective dose in hazelnut kernels
  12. Characterization of ferrous-xylenol orange-polyvinyl alcohol gel for gamma dosimetry using spectroscopy
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