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Gamma and neutron attenuation of SiO2–B2O3–BaO–Li2O glasses doped with CeO2

  • Khalid Alsafi , Dalal Abdullah Aloraini , M. A. Saif and Kh. S. Shaaban ORCID logo EMAIL logo
Published/Copyright: April 5, 2024

Abstract

The demonstrations impact of CeO2 on the radiation shielding properties of SiO2–B2O3–BaO–Li2O glasses has been investigated. The observed trend in density ρ ranged from 3.127 to 4.022 g/cm³, whereas the molar volume V m of these glasses decreased. The half-value layers (HVL), and mean free paths (MFP) of CL glasses reinforce the notion that the presence of Ce ions, particularly in CL2, enhances the ability of glasses’ to attenuate gamma rays. The effective electron density (Neff) increases with the addition of CeO2, suggesting a correlation between the enhancement of radiation shielding properties and the amount of CeO2 incorporated into the glasses.


Corresponding author: Kh. S. Shaaban, Department of Chemistry, Faculty of Science, Al-Azhar University, P.O. 71542, Assiut, Egypt, E-mail:

Acknowledgments

The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R57), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

  1. Research ethics: The authors declare that there are no ethical questions involved in this work.

  2. Author contributions: Kh. S. Shaaban, Conceptualization, methodology, writing- original draft preparation, writing- reviewing and editing, Dalal Abdullah Aloraini, Conceptualization, methodology, writing- original draft preparation, writing- reviewing and editing, Khalid Alsafi, Methodology, Writing- Original draft preparation, writing-reviewing and editing and M. A. Saif, Data curation, methodology, software, writing-reviewing and editing.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

  4. Research funding: None declared.

  5. Data availability: No data was used for the research described in the article.

References

1. Shaaban, K. S.; Saddeek, Y. B. Effect of MoO3 Content on Structural, Thermal, Mechanical and Optical Properties of (B2O3-SiO2-Bi2O3-Na2O-Fe2O3) Glass System. Silicon 2017, 9, 785–793. https://doi.org/10.1007/s12633-017-9558-5.Search in Google Scholar

2. Shaaban, K. S.; Al-Baradi, A. M.; Wahab, E. A. A. The Impact of Y2O3 on Physical and Optical Characteristics, Polarizability, Optical Basicity, and Dispersion Parameters of B2O3 – SiO2 – Bi2O3 – TiO2 Glasses. Silicon 2022, 14, 5057–5065. https://doi.org/10.1007/s12633-021-01309-8.Search in Google Scholar

3. Alrowaili, Z.; Al-Baradi, A. M.; Sayed, M.; Mossad Ali, A.; Abdel Wahab, E.; Al-Buriahi, M.; Shaaban, K. S. The Impact of Fe2O3 on the Dispersion Parameters and gamma/Fast Neutron Shielding Characteristics of Lithium Borosilicate Glasses. Optik 2021, 249, 168259. https://doi.org/10.1016/j.ijleo.2021.168259.Search in Google Scholar

4. Mahmoud, K.; Alsubaie, A.; Wahab, E. A. A.; Farid, M. A.-R.; Shaaban, K. S. Research on the Effects of Yttrium on Bismuth Titanate Borosilicate Glass System. Silicon 2022, 14, 3419–3427. https://doi.org/10.1007/s12633-021-01125-0.Search in Google Scholar

5. Shaaban, K. S.; Al-Baradi, A. M.; Ali, A. M. The Impact of Cr2O3 on the Mechanical, Physical, and Radiation Shielding Characteristics of Na2B4O7–CaO–SiO2 Glasses. Silicon 2022, 14, 10375–10382. https://doi.org/10.1007/s12633-022-01783-8.Search in Google Scholar

6. Althagafi, T. M.; Sayed, M. A.; Alghasham, H. A.; Al-Harbi, N.; Shaaban, Kh. S. The Impact of Changing the LiF Concentration on Structural, Thermal, Physical, and Optical Properties of CdO—SiO2—B2O3—MoO3—LiF Glasses. Silicon 2023, 15, 7047–7056. https://doi.org/10.1007/s12633-023-02567-4.Search in Google Scholar

7. Shaaban, K. S.; Al-Baradi, A. M.; Ali, A. M. Gamma-Ray Shielding and Mechanical Characteristics of Iron-Doped Lead Phosphosilicate Glasses. Silicon 2022, 14, 8971–8979. https://doi.org/10.1007/s12633-022-01702-x.Search in Google Scholar

8. Shaaban, K. S.; Alomairy, S.; Al-Buriahi, M. S. Optical, Thermal and Radiation Shielding Properties of B2O3–NaF–PbO–BaO–La2O3 Glasses. J. Mater. Sci. Mater. Electron. 2021, 32, 26034–26048. https://doi.org/10.1007/s10854-021-05885-8.Search in Google Scholar

9. Shaaban, K. S.; Alsafi, K.; Aloraini, D. A.; Al-Saleh, W. M.; Almutairi, H. M.; Assem, E. E. Influence of La2O3 on Mechanical Properties and Radiation-Shielding Performance of Magnesium Beryllia-Borosilicate Glass System. Silicon 2024. https://doi.org/10.1007/s12633-024-02897-x.Search in Google Scholar

10. Shaaban, K. S.; Tamam, N.; Alghasham, H. A.; Alrowaili, Z.; Al-Buriahi, M.; Ellakwa, T. E. Thermal, Optical, and Radiation Shielding Capacity of B2O3-MoO3-Li2O- Nb2O5 Glasses. Mater. Today Commun. 2023, 37, 107325. https://doi.org/10.1016/j.mtcomm.2023.107325.Search in Google Scholar

11. Shaaban, K. S.; Alyousef, H. A.; El-Rehim, A. F. A. CeO2 Reinforced B2O3–SiO2–MoO3 Glass System: A Characterization Study Through Physical, Mechanical and Gamma/Neutron Shields Characteristics. Silicon 2022, 14, 12001–12012. https://doi.org/10.1007/s12633-022-02124-5.Search in Google Scholar

12. Basha, B.; Shaaban, K. S.; Abdel Wahab, E. A. The Effect of Tungsten Ions on the Structural, Elastic Moduli, and Shielding Characteristics of Arsenic Lead Phosphate Glasses. Dig. J. Nanomater. Biostruct. 2023, 18 (2), 713–726. https://doi.org/10.15251/DJNB.2023.182.713.Search in Google Scholar

13. Sayyed, M. I.; Sadeq, M. S.; Shaaban, K. S.; Abd El-Rehim, A. F.; Ali, A. M.; Morshidy, H. Y. Elucidating the Effect of La2O3–B2O3 Exchange on Structure, Optical and Radiation Shielding Improvements of Na2O–NiO–B2O3 Glass. Opt. Mater. 2023, 142, 114051. https://doi.org/10.1016/j.optmat.2023.114051.Search in Google Scholar

14. El-Rehim, A. F. A.; Zahran, H. Y.; Yahia, I. S.; Wahab, E. A. A.; Shaaban, K. S. Structural, Elastic Moduli, and Radiation Shielding of SiO2-TiO2-La2O3-Na2O Glasses Containing Y2O3. J. Mater. Eng. Perform. 2021, 30, 1872–1884. https://doi.org/10.1007/s11665-021-05513-w.10.1007/s11665-021-05513-wSearch in Google Scholar

15. El-Rehim, A. F. A.; Shaaban, K. S. Influence of La2O3 Content on the Structural, Mechanical, and Radiation-Shielding Properties of Sodium Fluoro Lead Barium Borate Glasses. J. Mater. Sci. Mater. Electron. 2021, 32, 4651–4671; https://doi.org/10.1007/s10854-020-05204-7.Search in Google Scholar

16. Aloraini, D. A., Ashour, A., Shaaban, K. S. Effect of Various Na2O-MoO3 Concentrations on the Thermal, Mechanical, and Radiation-Resisting Attributes of Zinc-Borosilicate Glasses. Silicon 2024, 16, 1837–1846; https://doi.org/10.1007/s12633-023-02804-w.Search in Google Scholar

17. Al-Baradi, A. M.; Alotaibi, B. M.; Alharbi, N.; Abd El-Rehim, A. F.; Shaaban, K. S. Gamma Radiation Shielding and Mechanical Studies on Highly Dense Lithium Iron Borosilicate Glasses Modified by Zinc Oxide. Silicon 2022, 14, 10391–10399. https://doi.org/10.1007/s12633-022-01801-9.Search in Google Scholar

18. Shaaban, K. S.; Al-Baradi, A. M.; Alotaibi, B.; El-Rehim, A. Mechanical and Radiation Shielding Features of Lithium Titanophosphate Glasses Doped BaO. J. Mater. Res. Technol. 2023, 23, 756–764. https://doi.org/10.1016/j.jmrt.2023.01.062.Search in Google Scholar

19. Şakar, E.; Özpolat, Ö. F.; Alım, B.; Sayyed, M. I.; Kurudirek, M. Phy-X/PSD: Development of a User-Friendly Online Software for Calculation of Parameters Relevant to Radiation Shielding and Dosimetry. Radiat. Phys. Chem. 2020, 166, 108496. https://doi.org/10.1016/j.radphyschem.Search in Google Scholar

20. Al-Baradi, A. M.; Wahab, E. A. A.; Shaaban, K. S. Preparation and Characteristics of B2O3 – SiO2 – Bi2O3 – TiO2 – Y2O3 Glasses and Glass-Ceramics. Silicon 2022, 14, 5277–5287. https://doi.org/10.1007/s12633-021-01286-y.Search in Google Scholar

21. Saddeek, Y.; Shaaban, K.; Elsaman, R.; El-Taher, A.; Amer, T. Attenuation-Density Anomalous Relationship of Lead Alkali Borosilicate Glasses. Radiat. Phys. Chem. 2018, 150, 182–188. https://doi.org/10.1016/j.radphyschem.2018.04.028.Search in Google Scholar

22. Abdel Wahab, E. A.; Shaaban, K. S. Structural and Optical Features of Aluminum Lead Borate Glass Doped with Fe2O3. Appl. Phys. A 2021, 127, 956. https://doi.org/10.1007/s00339-021-05062-y.Search in Google Scholar

23. Alomairy, S.; Aboraia, A. M.; Shaaban, E. R.; Shaaban, K. S. Comparative Studies on Spectroscopic and Crystallization Properties of Al2O3 -Li2O- B2O3-TiO2 Glasses. Braz. J. Phys. 2021, 51, 1237–1248. https://doi.org/10.1007/s13538-021-00928-1.10.1007/s13538-021-00928-1Search in Google Scholar

24. Shaaban, K. S.; Alotaibi, B. M.; Al-Baradi, A. M.; Yousef El Sayed, A. A. Exploration of the Glass Domain in the SiO2-B2O3-TiO2-La2O3 System. Silicon 2023, 15, 4409–4416. https://doi.org/10.1007/s12633-023-02351-4.Search in Google Scholar

25. Wahab, E. A. A.; Shaaban, K. S.; Al-Baradi, A. M. Enhancement of Optical and Physical Parameters of Lead Zinc Silicate Glasses by Doping W+3 Ions. Silicon 2022, 14, 4915–4924. https://doi.org/10.1007/s12633-021-01236-8.Search in Google Scholar

26. Sayed, M. A.; Ali, A. M.; Abd El-Rehim, A. F.; Wahab, E. A. A.; Shaaban, K. S. Dispersion Parameters, Polarizability, and Basicity of Lithium Phosphate Glasses. J. Electron. Mater. 2021, 50, 3116–3128. https://doi.org/10.1007/s11664-021-08921-9.Search in Google Scholar

27. Al-Baradi, A. M.; El-Rehim, A. F. A.; Alrowaili, Z. A.; Al-Buriahi, M. S.; Shaaban, K. S. FT-IR and Gamma Shielding Characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO Glasses. Silicon 2021, 14 (12), 7043–7051. https://doi.org/10.1007/s12633-021-01481-x.10.1007/s12633-021-01481-xSearch in Google Scholar

28. Shaaban, K. S.; Althagafi, T. M.; Ashour, A.; Alalawi, A.; Al-Buriahi, M.; Ibraheem, A. A. The Role of Nb2O5 on Structural, Mechanical, and Gamma-Ray Shielding Characteristics of Lithium Molybdenum Borate Glasses. Radiat. Phys. Chem. 2024, 216, 111440. https://doi.org/10.1016/j.radphyschem.2023.111440.Search in Google Scholar

29. Shaaban, K. S.; Al-Harbi, N.; Alyousef, H. A.; Al-Baradi, A. M.; Ali, A. M.; Abdel Wahab, E. Thermal, Mechanical Characteristics as Well as Gamma-Ray Shielding Capabilities of Sodium-Barium Borosilicate Glasses with Y3+ Ions. Radiat. Phys. Chem. 2023, 212, 111086. https://doi.org/10.1016/j.radphyschem.2023.111086.Search in Google Scholar

30. Alghasham, H. A.; Ismail, Y. A.; Aloraini, D. A.; Shaaban, K. Elucidating the Influences of MoO3 in Na2O- ZnO - B2O3 - SiO2: Fabrication, Optical, and γ-Ray Protection Properties for the Novel High-Density Glasses. Mater. Today Commun. 2024, 38, 107840. https://doi.org/10.1016/j.mtcomm.2023.107840.Search in Google Scholar

31. Shaaban, K. S.; Alotaibi, B. M.; Yousef, E. S. Effect of La2O3 Concentration on the Structural, Optical and Radiation-Shielding Behaviors of Titanate Borosilicate Glasses. J. Electron. Mater. 2023, 52, 3591–3603. https://doi.org/10.1007/s11664-023-10347-4.Search in Google Scholar

32. Shaaban, K. S.; Basha, B.; Alrowaili, Z. A.; Al-Buriahi, M. S.; Abdel Wahab, E. A. A Closer Inspection of the Structural, Mechanical, Optical and Radiation Shielding Properties of GeO2-Doped Magnesium-Telluroborate Glasses. Radiochim. Acta. 2023, 111 (9), 713–724. https://doi.org/10.1515/ract-2023-0140.Search in Google Scholar

33. Shaaban, K. S.; Aloraini, D. A.; Alsafi, K.; Almutairi, H. M.; Al-Saleh, W. M.; Alzahrani, A. S. Role of CeO2 in the Enhancement of the Properties of the SiO2-B2O3-BaO-Li2O-Glass System: Structural, Mechanical and Radiation Shielding Study. Mater. Today Commun. 2024, 38, 108309. https://doi.org/10.1016/j.mtcomm.2024.108309.Search in Google Scholar

34. Shaaban, K.; Alotaibi, B.; Alharbi, N.; Alrowaili, Z.; Al-Buriahi, M.; Makhlouf, S. A.; Abd El-Rehim, A. Physical, Optical, and Radiation Characteristics of Bioactive Glasses for Dental Prosthetics and Orthopaedic Implants Applications. Radiat. Phys. Chem. 2022, 193, 109995. https://doi.org/10.1016/j.radphyschem.2022.109995.Search in Google Scholar

35. Alrowaili, Z. A.; Ali, A. M.; Al-Baradi, A. M.; Al-Buriahi, M. S.; Wahab, E. A. A.; Shaaban, K. S. A Significant Role of MoO3 on the Optical, Thermal, and Radiation Shielding Characteristics of B2O3–P2O5–Li2O Glasses. Opt. Quant. Electron. 2022, 54, 88. https://doi.org/10.1007/s11082-021-03447-0.Search in Google Scholar

36. Alothman, M. A.; Alrowaili, Z. A.; Alzahrani, J. S.; Wahab, E. A. A.; Olarinoye, I. O.; Sriwunkum, C.; Shaaban, K. S.; Al-Buriahi, M. S. Significant Influence of MoO3 Content on Synthesis, Mechanical, and Radiation Shielding Properties of B2O3-Pb3O4-Al2O3 Glasses. J. Alloys Compd. 2021, 882, 160625. https://doi.org/10.1016/j.jallcom.2021.160625.10.1016/j.jallcom.2021.160625Search in Google Scholar

37. Shaaban, K. S.; Al-Baradi, A. M.; Alotaibi, B.; El-Rehim, A. Mechanical and Radiation Shielding Features of Lithium Titanophosphate Glasses Doped BaO. J. Mater. Res. Technol. 2023, 23, 756–764. https://doi.org/10.1016/j.jmrt.2023.01.062.Search in Google Scholar

38. Shaaban, K. S.; Al-Baradi, A. M.; Ali, A. M. Physical, Optical, and Advanced Radiation Absorption Characteristics of Cadmium Lead Phosphate Glasses Containing MoO3. J. Mater. Sci. Mater. Electron. 2022, 33, 3297–3305. https://doi.org/10.1007/s10854-021-07530-w.Search in Google Scholar

39. Alrowaili, Z.; Al-Baradi, A. M.; Sayed, M.; Mossad Ali, A.; Abdel Wahab, E.; Al-Buriahi, M.; Shaaban, K. The Impact of Fe2O3 on the Dispersion Parameters and Gamma/Fast Neutron Shielding Characteristics of Lithium Borosilicate Glasses. Optik 2021, 249, 168259. https://doi.org/10.1016/j.ijleo.2021.168259.Search in Google Scholar

40. Shaaban, K. S.; Al-Baradi, A. M.; Ali, A. M. Investigation of BaO Reinforced TiO2–P2O5–li2O Glasses for Optical and Neutron Shielding Applications. RSC Adv. 2022, 12 (5), 3036–3043. https://doi.org/10.1039/D2RA00171C.Search in Google Scholar

41. Shaaban, K.; Alzahrani, A. S.; Aloraini, D. A.; Ismail, Y. A. Radiation Attenuation and Optical Behaviors of Glass System: 21SiO2–49B2O3–13ZnO-(17-x)Na2O-xWO3. Opt. Mater. 2024, 148, 114852. https://doi.org/10.1016/j.optmat.2024.114852.Search in Google Scholar

42. Alotaibi, B.; Alhuzaymi, T. M.; Alotiby, M. F.; Makhlouf, S. A.; Shaaban, K.; Abdel Wahab, E. Optical Structural and Radiation Shielding Efficiency of Vanadium-Doped LZBS Glass. Optik 2024, 301, 171689. https://doi.org/10.1016/j.ijleo.2024.171689.Search in Google Scholar

43. Oto, B.; Gür, A.; Kavaz, E.; Çakır, T.; Yaltay, N. Determination of Gamma and Fast Neutron Shielding Parameters of Magnetite Concretes. Prog. Nucl. Energy 2016, 92, 71–80. https://doi.org/10.1016/j.pnucene.2016.06.011.Search in Google Scholar

44. Alsafi, K.; Ismail, Y. A.; Aloraini, D. A.; Almutairi, H. M.; Al-Saleh, W. M.; Shaaban, K. S. Exploring the Radiation Shielding Properties of B2O3-SiO2-ZnO-Na2O-WO3 Glasses: A Comprehensive Study on Mechanical, Gamma, and Neutron Attenuation Characteristics. Prog. Nucl. Energy 2024, 170, 105151. https://doi.org/10.1016/j.pnucene.2024.105151.Search in Google Scholar

45. Almutairi, H. M.; Aloraini, D. A.; Alsafi, K.; Al-Saleh, W. M.; Alzahrani, A. S.; Shaaban, K. S. Impact of the La2O3 Addition on the Structure, Mechanical and Radiation Attenuation Features of La2O3–ZnO–SiO2–B2O3 Glass. Silicon 2024. https://doi.org/10.1007/s12633-024-02900-5.Search in Google Scholar

46. Aloraini, D. A.; Almutairi, H. M.; Alzahrani, A. S.; Shaaban, K. S.; Abdel Wahab, E. Enhancement the Structural, Mechanical and Radiation Shielding of Borosilicate Glasses Doped Vanadium Ions. Silicon 2024. https://doi.org/10.1007/s12633-024-02855-7.Search in Google Scholar

47. Sayed, M. A.; Basha, B.; Al-HarbiShaaban, N. K. S. Investigation of Elastic Moduli and Gamma-Ray Shielding Parameters of P2O5-SiO2-BaO Glasses Doped With Varying WO3. Silicon 2023, 15, 6463–6471. https://doi.org/10.1007/s12633-023-02537-w.Search in Google Scholar

48. Alzahrani, A. S.; Aloraini, D. A.; Wahab, E. A. A.; Shaaban, K. S. Investigation of the Structural, Elastic, and Radiation Shielding Properties of the SiO2 –Pb3O4–ZnO –Y2O3 Glass System. Silicon 2024. https://doi.org/10.1007/s12633-024-02846-8.Search in Google Scholar

49. Mostafa, A. M. A.; Issa, S. A. M.; El Agammy, E. F.; Zakaly, H. M. H.; Alotaibi, B. M.; Gharghar, F. Effect of BaO Addition on Gamma Radiation Shielding Performance of Sodium Barium Borate Glasses Using FLUKA Code and PhyX/PSD Platform. Radiat. Phys. Chem. 2023, 206, 110766. https://doi.org/10.1016/j.radphyschem.2023.110766.Search in Google Scholar

Received: 2024-01-02
Accepted: 2024-03-20
Published Online: 2024-04-05
Published in Print: 2024-09-25

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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