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Synergistic effect of oxidized low-dimensional carbon nanomaterials on the properties of polysulfone composite membrane

  • Jin Xu ORCID logo EMAIL logo , Fei Wang , Chunting Wang , Qi Zhang and Yan He
Published/Copyright: June 11, 2021
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Abstract

Using the immersion phase inversion process, polysulfone (PSF), grapheme oxide (GO) and modified carbon nanotubes (MCNTs) were dissolved in 1-methyl-2-pyrrolidone (NMP) to prepare nanocomposite membranes. The GO-MCNTs blended PSF membranes were characterized by several analytical methods, such as morphology analysis, group characteristic peak test, hydrophilic measurement and permeation tests, and the synergistic effect of GO and MCNTs on the membrane performance was investigated. Microscope images depict two-layer structure of the composite membrane, in which, the lower layer is finger like porous layer, and the upper layer is a thinner separation layer. M-CNTs have great influence on formation of the upper separation layer, while the hydrophilic nature of GO results in the formation of the lower supporting layer, which changes from finger shaped hole to honeycomb pore. The change of membrane structure not only improves the surface hydrophilicity, but also promotes the membrane performance. In particular, the composite membrane (mGO:MCNTs = 2:1) exhibits a much smaller contact angle (48.01°), a high permeation flux (33.25 L/m2·h) and superior rejection rate (95.2%). Furthermore, the fine compaction performance of composite membrane also provides great potential application prospects in water treatment.


Corresponding author: Jin Xu,College of Electromechanical Engineering, Shandong Engineering Laboratory for Preparation and Application of High-performance Carbon Materials, Qingdao University of Science and Technology, Qingdao, 266061, China, E-mail:

Funding source: Taishan Scholar Foudation of Shandong Province (China)

Award Identifier / Grant number: ts20190937

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the Taishan Scholar Foudation of Shandong Province, China (no. ts20190937).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-01-27
Accepted: 2021-05-04
Published Online: 2021-06-11
Published in Print: 2021-08-26

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 11.10.2025 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2021-0014/html
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