Home Temperature rise in a verging annular die
Article Publicly Available

Temperature rise in a verging annular die

  • Georges R. Younes ORCID logo , A. Jeffrey Giacomin ORCID logo EMAIL logo and Peter H. Gilbert ORCID logo
Published/Copyright: December 19, 2015
Become an author with De Gruyter Brill

Abstract

Plastic pipes, tubes or catheters are extruded by pressure-driven flows through annular dies. Whereas die lands are straight, the section connecting the die land to the extruder either converges or diverges, converging when the product is smaller than the extruder barrel, and diverging when larger. In this paper, we carefully consider the converging or diverging connecting flows, in spherical coordinates, for the most common configuration: the Newtonian pressure-driven flow through the annulus between two coapical coaxial cones. We derive the exact analytical solution for the velocity profile, and then use this to arrive at the exact analytical solution for the temperature rise caused by viscous heating. We care about this rise because it often governs maximum throughput, since pipe makers must protect the melt from thermal degradation. We find that both the velocity profile, and the temperature profile, peak over the same conical surface and this surface is nearer the inner die wall. We also provide analytical expressions for the nonlinear pressure profile and the die cooling requirement. We find that this cooling requirement is always higher on the inner cone.

1 Introduction

Plastic pipes, tubes, catheters or hollow fibers are extruded by pressure-driven flows through annular dies. Whereas die lands are straight, the section connecting the die land to the extruder either converges or diverges, converging when the product is smaller than the extruder barrel, and diverging when larger. We call flows that converge or diverge, verging flows. In this paper, we carefully consider the verging connecting flow, in spherical coordinates, for the most common configuration: the pressure-driven flow through the annulus between two coapical coaxial cones. We explore the analytical solution for the velocity profile, and then use this to calculate the temperature rise caused by viscous dissipation. We care about this rise because it often governs maximum throughput, since pipe makers must keep the melt from degrading. In this paper, we focus specifically on highly viscous nearly Newtonian polymer melts such as extrusion grades of condensation polymers. These would include nylon, polycarbonate or polyester.

Table 1 classifies the literature on pressure-driven converging or diverging annular flow. Whereas the straight annular pipe die lands are rarely concentric (a sag compensating measure [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19]), connecting verging flow geometries are normally coapical and coaxial. Table 2 lists our dimensional variables, and Table 3, the dimensionless ones.

Table 1

Literature on pressure-driven converging or diverging annular flow.

PapersGeometryCoordinatesSolutions forMethodFluidReferences
Bird et al. (1960, 2002)||vr, TaN[1], [2]
Parnaby and Worth (1974)V, ||ΔpaPL[3]
Dijksman and Savenije (1985)V§vr, ΔpaNEqs. (4.9) and (4.10) [4]
Kolitawong and Giacomin (2001)||⇄ ⊚vraN, PL[5]
Liang (2003)Vvr, ΔpaPL[6]
Kolitawong et al. (2011)||⇄ ⊚TnPL[7]
This paperV, Λvr, TaN

a, analytical; n, numerical; N, Newtonian; PL, power-law; T, temperature; V, converging; Λ, diverging; ||, straight; vr , velocity; Δp, pressure drop; γ˙, shear rate; ⊚, cylindrical; ⊙, spherical; §, toroidal; ⇄ ⊚, bipolar cylindrical.

Table 2

Dimensional variables.

Variable nameActual variableDimensionsVariable range
Absolute temperature, inner surfaceT0T≥0
Absolute temperature, initial fluidT0T≥0
Absolute temperature, maximumTmaxT≥0
Absolute temperature, outer surfaceT0T≥0
Absolute temperature, riseTT≥0
Azimuthal component of gravitygφL/t20
Azimuthal component of heat fluxqφM/t30
Azimuthal component of velocityvφL/t0
Characteristic time, Eq. (90)λμ/ρC˜p(Tmax-T0)t>0
Continuity flow functionC(θ)L3/t≤0
Density, meltρM/L3≥0
GravitygL/t2≥0
Heat capacity, constant pressureC˜pL2/t2T≥0
Inner spherical radiusriL≥0
Maximum velocityVmaxL/t>0
Outer spherical radiusroL≥0
PressurepM/Lt2≥0
Pressure dropΔppo-piM/Lt2≥0
Pressure, inner surfacepiM/Lt2≥0
Pressure, outer surfacepoM/Lt2≥0
Radial component in spherical coordinatesrL≥0
Radial component of gravitygrL/t2≤0
Radial component of heat fluxqrM/t3≥0
Radial component of velocityvrL/t
Rate of deformation tensorγ˙__1/t3
Shear rateγ˙1/t
Shear stressτM/Lt2
Shear stress tensorτ__M/Lt23
Spherical polar component of gravitygθL/t20
Spherical polar component of heat fluxqθM/t3
Spherical polar component of velocityvθL/t0
Timett≥0
Thermal conductivitykML/t3T≥0
Thermal diffusivityαk/ρC˜pL2/t≥0
Velocity vectorvL/t3
Viscosity, meltμM/Lt≥0
Volumetric flow rateQL3/t≥0

L, length; M, mass; T, temperature; t, time.

Where τij is the force exerted in the jth direction on a unit area of fluid surface of constant xi by fluid in the region lesser xi on fluid in the region greater xi [2].

Table 3

Dimensionless variables and groups.

Group nameSymbolGroup range
Azimuthal angular coordinateϕ[0; 2π]
Dimensionless continuity constant, Eq. (63)𝓒CμΔpri3
Dimensionless continuity constantCλro3
Dimensionless flow rate, Eq. (3) [3]Ω16(1+tanθitanθo)(1-tanθitanθo)3
Function of ξB, B1
Function of θ, Eqs. (32), (33), (54)a, b, A
Functions of θi and θo , Eqs. (37), (38), (39), (40)ao, ai, bo, bi
Half conical angle, maximumθc[θi ; θo ]
Half conical angle, insideθi[0;π2];θo>θi
Half conical angle, maximum temperatureθmax,T[θi ; θo ]
Half conical angle, maximum velocityθmax,vr[θi ; θo ]
Half conical angle, minimum velocityθmin,vr[θi ; θo ]
Half conical angle, outsideθo[0;π2];θo>θi
Péclet number, Eq. (92)αλ(ro-ri)ro3
Pressure, Eq. (68)𝓟p-piΔp[0; 1]
Pressure dropΔ𝓟ΔpriμVmax
Radial position, Eq. (65)𝓡r-riro-ri[0; 1]
Pressure to viscosity dimensionless number2λΔpμ
Reynolds number, Eq. (130)ReρVmaxriμ>0
Shape factors, Eqs. (73), (74), (6), (70)fco,fci,fL,fs
Spherical angular position, Eq. (56)ξθ-θiθo-θi[0; 1]
Spherical polar angular coordinateθ[0;π2]
Spherical radii ratio, Eq. (2)κri /ro≥0
TemperatureΘT-T0Tmax-T0[0; 1]
Velocity, Eq. (67)𝒱vrμro2(po-pi)ri3
Volumetric flow rate𝒬QVmaxri2

Parnaby and Worth [3] (see also Problems 5–37 and 5–38 of [20]) used cylindrical coordinates to arrive at the approximate analytical solution for coapical and coaxial converging annular flow of Newtonian fluids, rewritten in spherical coordinates defined in Figure 1 and Table 2 and mindful of our erratum in [3]:

Figure 1: Spherical coordinates for pressure-driven flow through  converging coapical concentric conical annulus (κ=513,$\kappa  = {5 \over {13}},$θi =11°, θo =31°).
Figure 1:

Spherical coordinates for pressure-driven flow through converging coapical concentric conical annulus (κ=513,θi =11°, θo =31°).

(1)2μQ(1-κ3)3πΩri3cos3θotan4θo<Δp<2μQ(1-κ3)3πΩri3cos3θitan4θo (1)

where:

(2)κriro (2)

and for (tanθi/tanθo)>0.6:

(3)Ω16(1+tanθitanθo)(1-tanθitanθo)3 (3)

Dijksman and Savenije [4] used the special toroidal coordinates to find exact analytical solutions for converging and diverging non-coapical and coaxial annular Newtonian flow. By non-coapical, we mean that the conical walls do not share the same apex. They even rewrote the equations of continuity and motion in toroidal coordinates (see Appendices I and II of [4]). For coapical converging Newtonian flows, their equation for the velocity (Eq. (4.9) of [4]), rewritten in spherical coordinates, defined in Figure 1 and Table 2 is:

(4)vr=-3Q(θ-θi)(θ-θi-θo)πr2θo3sinθi (4)

However, Eq. (4) does not satisfy the boundary condition at θo given by Eq. (34). Hence, Eqs. (4.9) and (4.10) of [4] should not be used.

Liang [6] also reached analytical solutions for converging annular flow of power-law fluids. For our case, the Liang exact analytical solution written using the variables defined in Figure 1 and Table 2 is:

(5)Δp=Qμ3πri3fL(1-κ3) (5)

where κ is defined in Eq. (2) and:

(6)fL=12[(θc-θi)3sinθi+(θo-θc)3sinθo-12(θo-θi)2(cosθi-cosθo)] (6)

where θ[=]rad, and in which θc=12(θi+θo) for both ur (r, θi)=0 and ur (r, θo)=0.

In this work, we use spherical coordinates to analyze viscous dissipation in pressure-driven flow through a verging annular plastics extrusion die. We find exact analytical solutions for the steady state velocity and temperature rise profiles.

2 Materials and methods

We consider molten Newtonian plastics, flowing through verging conical annular dies. Figure 1 shows these annuli, between two coaxial coapical cones. Our analysis follows the transport phenomena approach. We explore the analytical solution for the velocity profile, and then use this to calculate the temperature rise caused by viscous dissipation.

3 Analysis

3.1 Velocity profile

3.1.1 Physical intuition

Figures 2 and 3 show that the molten plastic moves in the r-direction only:

Figure 2: Velocity profile for pressure-driven flow through  converging coapical concentric conical annulus (κ=513,$\kappa  = {5 \over {13}},$θi =11°, θo =31°).
Figure 2:

Velocity profile for pressure-driven flow through converging coapical concentric conical annulus (κ=513,θi =11°, θo =31°).

Figure 3: Velocity profile for pressure-driven flow through diverging coapical concentric conical annulus (κ=513,$\kappa  = {5 \over {13}},$θi =11°, θo =31°).
Figure 3:

Velocity profile for pressure-driven flow through diverging coapical concentric conical annulus (κ=513,θi =11°, θo =31°).

(7)vθ=vϕ=0 (7)

where:

(8)v_=(vr(r,θ),0,0);vr(r,θ)0 (8)

for converging flows, and:

(9)v_=(vr(r,θ),0,0);vr(r,θ)0 (9)

for diverging flows.

3.1.2 Equation of continuity in spherical coordinates (r, θ, φ)

From the equation of continuity (Eq. B.4-3 of [2]), for constant density and using Eq. (7) we get:

(10)vr=C(θ)r2 (10)

and differentiating gives:

(11)vrr=-2C(θ)r3 (11)

which we will use to simplify the rr-component of the rate of deformation tensor, and also, to simplify the r-component of the equation of motion.

3.1.3 Equations of motion in spherical coordinates (r, θ, φ)

The r-component of the equation of motion (Eq. B.5-7 of [2]), after applying Eq. (7) and ϕ symmetry, reduces to:

(12)ρvrvrr=-pr-[1r2r(r2τrr)+1rsinθθ(τθrsinθ)-τθθ+τϕϕr]-ρgcosθ (12)

Each relevant component of the rate of deformation tensor (§B.1 of [2]), simplified with Eqs. (8), (9), (10) or (11) then gives:

(13)γ˙rr=2vrr=-4Cr3 (13)
(14)γ˙θθ=2(1rvθθ+vrr)=2vrr=2Cr3γ˙ϕϕ=2(1rsinθvϕϕ+vrr+vθcotθr)=2vrr=Δθθγ˙rθ=rr(vθr)+1rvrθ=1rvrθ=1rθ[C(θ)r2]=1r3Cθ (14)

Hence τθθ =τφφ, so that combining Eq. (12) with Eqs. (10) and (11) yields:

(15)-2ρC2r5=-pr[1r2r(r2τrr)+1rsinθθ(τθrsinθ)-2rτθθ]-ρgcosθ (15)

3.1.4 Eliminating stresses

Combining Eqs. (13) and (14) with the constitutive equation for Newtonian fluids:

(16)τ__=-μγ˙__ (16)

yields:

(17)τrr=4μCr3τθθ=-2μCr3τrθ=-μr3Cθ (17)

We can eliminate the stresses from Eq. (15), and since C depends on θ only:

(18)-2ρC2r5=-pr+μr4sinθddθ(dCdθsinθ)-ρgcosθ (18)

Neglecting both fluid inertia and gravity we get:

(19)0=-dpdr+μr4sinθddθ(dCdθsinθ) (19)

for which the variables easily separate:

(20)r4dpdr=μsinθddθ(dCdθsinθ) (20)

and thus:

(21)r4dpdr=C1 (21)

which is easily integrated to give the (nonlinear) pressure profile:

(22)p=C4-C13r3 (22)

from which we learn that the pressure depends at most on r, and which is subject to the pressure boundary conditions:

(23)po=C4-C13ro3 (23)
(24)pi=C4-C13ri3 (24)

where, for converging flows, the outer pressure must exceed the inner:

(25)po>pi (25)

and for diverging:

(26)pi>po (26)

Solving Eqs. (23) and (24):

(27)C1=3(po-pi)ri31-κ3 (27)
(28)C4=po-κ3pi1-κ3 (28)

where κ is defined in Eq. (2). Hence:

(29)p=11-κ3[po-κ3pi-(po-pi)ri3r3] (29)

Returning to the right side of Eq. (20) gives:

(30)d2Cdθ2+cosθsinθdCdθ=C1μ (30)

which has the general real solution:

(31)C=-C12μ(a+b)-C2(a-b)+C3 (31)

where:

(32)alog(1+cosθ) (32)
(33)blog(1-cosθ) (33)

and where C[=]C2[=]C3[=]C1[=]L3/t.

Eq. (31) is subject to the no-slip boundary conditions:

(34)C(θi)=C(θo)=0 (34)

and hence:

(35)0=-C1μ(ao+bo)-2C2(ao-bo)+2C3 (35)
(36)0=-C1μ(ai+bi)-2C2(ai-bi)+2C3 (36)

where C1 is given by Eq. (27), and where:

(37)aolog(1+cosθo) (37)
(38)bolog(1-cosθo) (38)
(39)ailog(1+cosθi) (39)
(40)bilog(1-cosθi) (40)

Solving Eqs. (35) and (36) and substituting the results into Eq. (31) gives:

(41)C=3(po-pi)ri32μ(1-κ3)[-(a+b)+(ao+bo-ai-biao-bo-ai+bi)(a-b)+2(aobi-aiboao-bo-ai+bi)] (41)

Substituting this into Eq. (10) we get the exact solution for the velocity profile in spherical coordinates for pressure-driven flow through conical coapical coaxial annulus:

(42)vr=3(po-pi)ri32μ(1-κ3)r2[-(a+b)+(ao+bo-ai-biao-bo-ai+bi)(a-b)+2(aobi-aiboao-bo-ai+bi)] (42)

be it converging or diverging. Differentiating Eq. (42) and solving for θmin,vr we get:

(43)θmin,vr=arccos(-ao-bo+ai+biao-bo-ai+bi) (43)

For converging (and diverging) flows, θmin,vr<(θi+θo)/2, with θi, θo ∈[0; π/2], and thus the minimum (and maximum) velocity cones are nearer the inner surface than the outer. This is why shear rates γ˙rθ (and thus the shear stresses τ ) on the inner cone are higher than on the outer (for both converging and diverging flows).

We now turn our attention to the ϕ-component of the equation of motion (Eq. B.5-9 of [2]) which, following Subsections 3.1.3 and 3.1.4, and since we are neglecting gravity, gives:

(44)ρ(vϕt+vrvϕr+vθrvϕθ+vϕrsinθvϕϕ+vϕvr+vθvϕcotθr)=-1rsinθpϕ-[1r3r(r3τrϕ)+1rsinθθ(τθϕsinθ)+1rsinθτϕϕϕ+τϕθcotθr] (44)

Eliminating the stresses using:

(45)τrϕ=τθϕ=0τϕϕ=-2μCr3 (45)

we get,

(46)pϕ=0 (46)

from which we learn that the pressure does not depend on ϕ.

Similarly, for the θ-component (Eq. B.5-8 of [2]), by following Subsections 3.1.3 and 3.1.4 we get:

(47)ρ(vθt+vrvθr+vθrvθθ+vϕrsinθvθϕ-vrvθ-vϕ2cotθr)=-1rpθ-[1r3r(r3τrθ)+1rsinθθ(τθθsinθ)+1rsinθτϕθϕ-τϕϕcotθr] (47)

and then using:

(48)τθθ=τϕϕ=-2μCr3τrθ=-μr3Cθτϕθ=0 (48)

to eliminate the stresses gives:

(49)pθ=2μr3dCdθ (49)

and integrating yields:

(50)p=2μCr3+C5(r) (50)

Substituting Eq. (29) into Eq. (50) gives:

(51)11-κ3[po-κ3pi-(po-pi)ri3r3]=2μCr3+C5(r) (51)

Solving for C5 at θ=θo we get:

(52)C5=11-κ3[po-κ3pi-(po-pi)ri3r3]=p(r) (52)

Substituting Eqs. (27), (41) and (52) into Eq. (50) yields the two dimensional nonlinear pressure profile:

(53)p(r,θ)=(po-pi)ri3(1-κ3)r3(A-1)+po-κ3pi1-κ3 (53)

with:

(54)A(θ)3[-(a+b)+(ao+bo-ai-biao-bo-ai+bi)(a-b)+2(aobi-aiboao-bo-ai+bi)] (54)

For most plastics extrusion die designs:

(55)A1 (55)

Therefore Eq. (53) reduces to Eq. (29) and our assumption that p depends on r only (see Subsection 3.1.4) is confirmed.

3.1.5 Nondimensional velocity and pressure

We begin our nondimensionalization by rearranging:

(56)ξθ-θiθo-θi (56)

from Table 3, to give:

(57)θ=ξ(θo-θi)+θi (57)

which, substituted into Eqs. (32) and (33), yields:

(58)alog[1+cos(ξ(θo-θi)+θi)] (58)
(59)blog[1-cos(ξ(θo-θi)+θi)] (59)

Next, in Eq. (41), we let:

(60)B(ξ,θi,θo)-(a+b)+(ao+bo-ai-biao-bo-ai+bi)(a-b)+2(aobi-aiboao-bo-ai+bi) (60)

so that:

(61)C=BC12μ (61)

Substituting Eq. (27) into Eq. (61), we get:

(62)C=3B(po-pi)ri32μ(1-κ3) (62)

Using this with Table 3 gives:

(63)𝓒Cμ(po-pi)ri33B2(1-κ3) (63)

and thus:

(64)C=𝓒(po-pi)ri3μ (64)

which we will use below. Also letting:

(65)𝓡r-riro-ri=rro-κ1-κ (65)

so that:

(66)r=ro[𝓡(1-κ)+κ] (66)

Substituting Eqs. (64) and (66) into Eq. (10), rearranging, and using Table 3, we get the dimensionless velocity profile:

(67)𝒱vrμro2(po-pi)ri3=𝓒[𝓡(1-κ)+κ]2=3B(ξ)2(1-κ3)[𝓡(1-κ)+κ]2 (67)

where κ is defined in Eq. (2).

Using Table 3 with Eq. (29) and rearranging gives the dimensionless pressure profile:

(68)𝒫p-piΔp=11-κ3[1-κ3[𝓡(1-κ)+κ]3];A1 (68)

3.1.6 Nondimensional 𝒬/Δ𝒫

Integrating Eq. (42) twice, with respect to θ and ϕ, and then rearranging gives:

(69)Δp=Qμ(1-κ3)3πri3fs (69)

where:

(70)fs=(1-ao+bo-ai-biao-bo-ai+bi)[ao(1+cosθo)-ai(1+cosθi)]-(1+ao+bo-ai-biao-bo-ai+bi)[bo(1-cosθo)-bi(1-cosθi)]-2(cosθo-cosθi)(1+aobi-aiboao-bo-ai+bi) (70)

with ao , bo , ai and bi defined in Eqs. (37)–(40). Equation (70) is the first main result of this paper. Using Tables 2 and 3, we adimensionalize Eq. (69) to get:

(71)1-κ33π𝒬Δ𝒫=fs (71)

Figure 10 illustrates Eq. (71) and shows how the dimensionless flow rate per unit pressure drop, fs, changes with the extrusion die shape, θi and θo . Practitioners can use Figure 10 to get the volumetric flow rate graphically, or the pressure drop (see worked example in Section 5).

In Figure 11, we will compare the previous approximate solutions of Parnaby and Worth [3] [Eq. (1)] and of Liang [6] [Eq. (5)] with our exact solution [Eq. (71)]. For this, we must nondimensionalize Eqs. (1) and (5) in the same way as our Eq. (71). For Parnaby and Worth [3] [Eq. (1)], we get:

(72)fci<1-κ33π𝒬Δ𝒫<fco (72)

where:

(73)fcoΩcos3θotan4θo2 (73)
(74)fciΩcos3θitan4θo2 (74)

where Ω is defined in Eq. (3), and for Liang [6] [Eq. (5)], we get:

(75)1-κ33π𝒬Δ𝒫=fL (75)

with fL defined in Eq. (6).

3.2 Temperature rise

In this section, we focus on the temperature rise caused by the viscous dissipation associated with the velocity profile given by our exact solution, Eq. (42). Specifically, we consider melt entering the conical die (illustrated in Figures 1, 4 and 5) at a uniform temperature T0 and with isothermal inner and outer conical surfaces also at T0. We are, of course, aware that the extrusion die surfaces can be controlled with other thermal boundary conditions. These conditions lie beyond the scope of this work.

3.2.1 Physical intuition

Figures 4 and 5 show how the temperature profile evolves in the dies for converging and diverging flows. When viscous dissipation matters, the temperature rises as the melt flows from ro to ri (ri to ro) for converging (diverging) flows. Not unlike vr (r, θ), the temperature also depends on both r and θ, T(r, θ). Thus, for converging flows through isothermal die walls we have:

Figure 4: Temperature rise profile for pressure-driven flow through  converging coapical concentric conical annulus (κ=513,$\kappa  = {5 \over {13}},$θi =11°, θo =31°).
Figure 4:

Temperature rise profile for pressure-driven flow through converging coapical concentric conical annulus (κ=513,θi =11°, θo =31°).

Figure 5: Temperature rise profile for pressure-driven flow through  diverging coapical concentric conical annulus (κ=513,$\kappa  = {5 \over {13}},$θi =11°, θo =31°).
Figure 5:

Temperature rise profile for pressure-driven flow through diverging coapical concentric conical annulus (κ=513,θi =11°, θo =31°).

(76)Tr<0 (76)

and:

(77)T(ro,θ)=T(r,θο)=T(r,θi)=T0 (77)

whereas for diverging flows we have:

(78)Tr>0 (78)

and:

(79)T(ri,θ)=T(r,θο)=T(r,θi)=T0 (79)

For both converging and diverging flows, we define:

(80)Tθ|Tmax(r)=0;θθmax,T(r) (80)

which defines the hottest surface in the flowing melt, which is at most a function of r.

3.2.2 Viscous dissipation term in spherical coordinates (r, θ, φ)

We begin by combining the general expression for the viscous dissipation in spherical coordinates (Eq. (C) of Table A.7-3 of [2]) with our physical intuition for the velocity, Eq. (7):

(81)(τ:v)=τrr(vrr)+τθθ(vrr)+τϕϕ(vrr)+τrθ(1rvrθ)+τrϕ(1rsinθvrϕ) (81)

which when combined with the velocity profile and its derivative, Eqs. (10) and (11), gives:

(82)(τ:v)=τrr(vrr)+τθθ(vrr)+τϕϕ(vrr)+τrθ(1rvrθ) (82)

from which we eliminate the stresses using Eqs. (17), (45), τrr =-2τθθ and τφφ=τθθ to get:

(83)(τ:v)=-μr6[12C2+(dCdθ)2] (83)

which we will use in Subsection 3.2.3, and where the exact solution for C is given by Eq. (41).

3.2.3 Equation of energy in spherical coordinates (r, θ, φ)

We begin by simplifying the equation of energy written in terms of temperature for an incompressible fluid (Eq. B.8-3 of [2]), with ϕ symmetry for the longitudinal heat flux, qφ, gives:

(84)ρC^pvrTr=-[1r2r(r2qr)+1rsinθθ(qθsinθ)]-(τ:v) (84)

Eliminating the heat fluxes using Fourier’s law (Eqs. B.2-7 and B.2-8 of [2]) we get:

(85)ρC^pvrTr=k[1r2r(r2Tr)+1rsinθθ(1rTθsinθ)]-(τ:v) (85)

Now, if we assume that axial conduction is negligible (with respect to radial convection):

(86)ρC^pvrTrk1r2r(r2Tr) (86)

then:

(87)vrTr=αrsinθθ(1rTθsinθ)-1ρC^p(τ:v) (87)

where αk/ρC^p is the thermal diffusivity (see Table 2). Substituting Eqs. (10) and (83) into (87) and rearranging gives:

(88)CTr=αsinθθ(sinθTθ)+1ρC^pμr4[12C2+(dCdθ)2] (88)

which is subject to the boundary conditions given by Eqs. (77) and (79).

3.2.4 Dimensionless temperature rise

Using Tables 2 and 3, we rewrite Eq. (88) as:

(89)Θ𝓡=αro(1-κ)Csinθθ(sinθΘθ)+[μρC^p(Tmax-T0)](1-κ)ro3[𝓡(1-κ)+κ]4[12C+1C(dCdθ)2] (89)

which uncovers the characteristic time:

(90)λμρC^p(Tmax-T0) (90)

so that:

(91)Θ𝓡=sinθθ(sinθΘθ)+λ(1-κ)ro3[𝓡(1-κ)+κ]4[12C+1C(dCdθ)2] (91)

where we have also uncovered the Péclet number:

(92)αλ(ro-ri)ro3 (92)

Further, using Table 3, yields:

(93)Θ𝓡=sinθθ(sinθΘθ)+1-κ[𝓡(1-κ)+κ]4[12+1(ddθ)2] (93)

which we will use presently.

In this Subsection, we begin by neglecting conduction in the θ-direction, and finish with an exact analytical solution for the temperature rise that is consistent with isothermal, inner and outer die walls, Eqs. (77) and (79). Neglecting conduction in the θ-direction (Pé≪1), Eq. (93) reduces to:

(94)Θ𝓡=1-κ[𝓡(1-κ)+κ]4[12+1(ddθ)2] (94)

and has the exact solution:

(95)Θ=C6-13[𝓡(1-κ)+κ]3[12+1(ddθ)2] (95)

subject to the entrance condition, which for converging flows is:

(96)Θ(𝓡o)=Θ(ro-riro-ri)=Θ(1)=0 (96)

so that:

(97)Θ=[1-1[𝓡(1-κ)+κ]3][4+13(ddθ)2] (97)

and for diverging flows is:

(98)Θ(𝓡i)=Θ(ri-riro-ri)=Θ(0)=0 (98)

so that:

(99)Θ=[1κ3-1[𝓡(1-κ)+κ]3][4+13(ddθ)2] (99)

Using Eq. (133), proven in Appendix 7.2, we get:

(100)(d𝓒dξ)2=(ddθ)2=0;A21 (100)

which, when applied to Eqs. (97) and (99) gives:

(101)Θ=4[1-1[𝓡(1-κ)+κ]3];A21 (101)
(102)Θ=4[1κ3-1[𝓡(1-κ)+κ]3];A21 (102)

where the condition A≪1 [Eqs. (54) and (55)] on our pressure and velocity [Eqs. (29) and (42)], upon which Eqs. (101) and (102) are based, is already sufficient for A2≪1. The reader is reminded that, for most plastics extrusion die designs, A≪1.

Since ℂ(θo)=ℂ(θi)=0, the temperature rise on the die surfaces is also zero, Θ(θo)=Θ(θi)=0. In other words, Eqs. (101) and (102) are exactly consistent with the isothermal wall boundary conditions Eqs. (77) and (79), which we have yet to use.

Using Table 3, Eqs (101) and (102) become:

(103)Θ=[2λ(po-pi)κ3μ(1-κ3)][1-1[𝓡(1-κ)+κ]3]A (103)
(104)Θ=[2λ(po-pi)κ3μ(1-κ3)][1κ3-1[𝓡(1-κ)+κ]3]A (104)

with A already defined in Eq. (54). We next differentiate Eqs. (103) and (104) to get the hottest surface in the flowing melt:

(105)θmax,T=arccos(-ao-bo+ai+biao-bo-ai+bi) (105)

which is conical, and which matches the velocity minimum cone, θ=θmin,vr, given by Eq. (43). We thus find that the temperature maximum cone θ=θmax,T is nearer the inner surface than the outer.

Using Table 3 to rewrite Eqs. (103) and (104) we get:

(106)Θ(𝓡,ξ)=(κ31-κ3)[1-1[𝓡(1-κ)+κ]3]B1 (106)
(107)Θ(𝓡,ξ)=(κ31-κ3)[1κ3-1[𝓡(1-κ)+κ]3]B1 (107)

Eqs. (106) and (107) give the nondimensional temperature rise for converging and diverging flows, respectively, and these are thus the second main result of this work. Equations (106) and (107) are exactly consistent with the isothermal wall boundary conditions Eqs. (77) and (79). In Section 4, we will differentiate Eqs. (106) and (107) to calculate the corresponding cooling requirement for conical die surfaces.

4 Results and discussion

In this section, we will illustrate and discuss the main results of our analysis in Section 3. We graph the velocity and then the temperature profiles for a specific die design: θi =10°, θo =15° and κ=15. We further compare our exact solution [Eq. (71)] for the throughput per unit pressure drop with prior approximations of Parnaby and Worth [3] [Eq. (72)] and of Liang [6] [Eq. (75)]. We will close Section 4 with a dimensionless graph for Eq. (71) that is specifically for practitioners of plastic pipe extrusion die design.

4.1 Velocity profile

In the next two subsections, we discuss Figures 6 and 7, which illustrate the velocity profiles for converging and diverging dies.

Figure 6: Dimensionless velocity profile [Eq. (67)] for pressure-driven flow through converging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,$\kappa  = {1 \over 5},$θi =10°, θo =15°).
Figure 6:

Dimensionless velocity profile [Eq. (67)] for pressure-driven flow through converging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,θi =10°, θo =15°).

Figure 7: Dimensionless velocity profile [Eq. (67)] for pressure-driven flow through diverging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,$\kappa  = {1 \over 5},$θi =10°, θo =15°).
Figure 7:

Dimensionless velocity profile [Eq. (67)] for pressure-driven flow through diverging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,θi =10°, θo =15°).

4.1.1 Converging flows

The accelerating velocity for converging die flows is negative, and the pressure drop in Eq. (42), is positive. Figure 6 illustrates the velocity profile shape for a particular converging die design. We see that the minimum velocity cone is nearer the inner surface. Using Eq. (43) for the specific die considered, this minimum velocity cone is θmin,vr12.42°, which is just inside the midcone, θ=12.5°.

4.1.2 Diverging flows

The decelerating velocity for diverging die flows is positive, and the pressure drop in Eq. (42) is negative. Figure 7 illustrates the velocity profile shape for a specific diverging die design. We see that the maximum velocity cone is nearer the inner surface. Using Eq. (43) for the specific die considered, this maximum velocity cone is θmax,vr12.42°, which is just inside the midcone, θ=12.5°.

4.2 Temperature rise profile

In the following two subsections, we discuss Figures 8 and 9, which illustrate the temperature rise profiles in the converging and diverging dies.

Figure 8: Dimensionless temperature rise profile [Eq. (106)] for pressure-driven flow through converging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,$\kappa  = {1 \over 5},$θi =10°, θo =15°).
Figure 8:

Dimensionless temperature rise profile [Eq. (106)] for pressure-driven flow through converging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,θi =10°, θo =15°).

Figure 9: Dimensionless temperature rise profile [Eq. (107)] for pressure-driven flow through diverging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,$\kappa  = {1 \over 5},$θi =10°, θo =15°).
Figure 9:

Dimensionless temperature rise profile [Eq. (107)] for pressure-driven flow through diverging coapical concentric conical annulus for different dimensionless conical half angles and dimensionless radial positions (κ=15,θi =10°, θo =15°).

4.2.1 Converging flows

In Figure 8, we plot the dimensionless temperature rise per unit pressure drop, Θ(𝓡,ξ)/ which shows the shape of the temperature rise for a specific converging die design. The surface of maximum temperature rise is conical θmax,T=θmin,vr12.42°, which matches the minimum velocity cone. Figure 8 also shows that the wall temperatures are constant at T0 and thus the walls are isothermal. To achieve this condition, to compensate for viscous heating, the walls must be cooled.

The expression for the required heat flux for cooling is given by (Eq. B.2-8 of [2]):

(108)qθ=-k1rTθ (108)

Substituting Eq. (106), into Eq. (108), and evaluating the result for the inner surface gives the cooling load requirement:

(109)qθi=4kΔpκ3ρC˜p(1-κ3)sinθi(1r-ro3r4)(cosθi+ao+bo-ai-biao-bo-ai+bi) (109)

and for the outer surface:

(110)qθo=4kΔpκ3ρC˜p(1-κ3)sinθo(1r-ro3r4)(cosθo+ao+bo-ai-biao-bo-ai+bi) (110)

From Eqs. (109) and (110), we conclude that the cooling load at the inner die cone must be higher than for the outer.

4.2.2 Diverging flows

In Figure 9, we plot the dimensionless temperature rise per unit pressure drop, -Θ(𝓡,ξ)/, which shows the shape of the temperature rise for a specific diverging die design. The surface of maximum temperature rise is conical θmax,T=θmax,vr12.42°, which matches the maximum velocity cone. Figure 9 also shows that the wall temperatures are constant at T0 and thus the walls are isothermal. To achieve this condition, to compensate for viscous heating, the walls must be cooled.

Substituting Eq. (107), into Eq. (108), and evaluating the result for the inner surface gives the cooling load requirement:

(111)qθi=4kΔpκ3ρC˜p(1-κ3)sinθi(1rκ3-ro3r4)(cosθi+ao+bo-ai-biao-bo-ai+bi) (111)

and for the outer surface:

(112)qθo=4kΔpκ3ρC˜p(1-κ3)sinθo(1rκ3-ro3r4)(cosθo+ao+bo-ai-biao-bo-ai+bi) (112)

From Eqs. (111) and (112), we conclude that the cooling at the inner die cone must be higher than for the outer.

4.3 Throughput per unit pressure drop

In this section, we use Figure 10 to compare our exact solution [Eq. (71)] for the throughput per unit pressure drop with prior approximations of Parnaby and Worth [3] [Eq. (72)] and of Liang [6] [Eq. (75)]. Figure 10 has been constructed for: 110°≤θi ≤15°, θo =15° and κ=15, which includes the special basis θi =10°, θo =15° and κ=15 that we used for Figures 69. For these conditions, Figure 10 shows that whereas the cylindrical approximation of Parnaby and Worth [3] [Eq. (72)] slightly overpredicts the flow rate, Liang [6] [Eq. (75)] grossly overpredicts. Figure 11 charts the flow rate per unit pressure drop predicted by our exact solution, Eq. (71). We provide this dimensionless graph specifically for plastic pipe extrusion die designers. We will use Figure 11 presently.

Figure 10: Shape factors (dimensionless volumetric flow rate), fs [Eq. (71)], (fci, fco)$(f_c^i,{\rm{ }}f_c^o)$ [Eq. (72)], fL [Eq. (75)], vs. θi in radians and parameterized with θo =15°=π/12 rad.
Figure 10:

Shape factors (dimensionless volumetric flow rate), fs [Eq. (71)], (fci,fco) [Eq. (72)], fL [Eq. (75)], vs. θi in radians and parameterized with θo =15°=π/12 rad.

Figure 11: Shape factor (dimensionless volumetric flow rate), fs vs. cosθo and parameterized with cosθi [Eq. (71)].
Figure 11:

Shape factor (dimensionless volumetric flow rate), fs vs. cosθo and parameterized with cosθi [Eq. (71)].

5 Worked example

An engineer gathers the following process details for her polycarbonate pipe extrusion line, and specifically for the converging connection between her extruder and her straight annular die land: θo =31.0°, θi =11.0°, ro =0.130 m and ri =0.0500 m, with the throughput of ρQ=-0.0100 kg/s, and the material properties at the operating temperature are μ=1.10×107 Pa·s, ρ=900 kg/m3, C˜p=1.60×103 J/kg-°C and k=0.1 W/m.

She wants to estimate (i) the required pressure drop for the given throughput and (ii) the temperature rise in the die.

(i) Using Eq. (54), she first gets A(θmin,vr)=A(20.2°)=-0.0941 which satisfies Eq. (55). She then interpolates Figure 11 with cos θi =0.982 and cos θo =0.857 to get, for our exact solution:

(113)fs-10-2.59-0.00257 (113)

For this same die, the cylindrical approximations [Eqs. (73) and (74)] give:

(114)fci-0.0253 (114)
(115)fco-0.0168 (115)

and the Liang approximation [Eq. (6)] gives:

(116)fL-0.187 (116)

Combining Eq. (71) with Δ𝓟Δpri/(μVmax) and 𝓠Q/(Vmaxri2) from Table 3 and rearranging gives the pressure drop:

(117)-Δp=-Qμ(1-κ3)3πri3fs=-ρQμ(1-(ri/ro)3)3πρri3fs (117)

Inserting the given die geometry, physical properties and Eq. (113) into Eq. (117):

(118)-Δp=-(-0.0100 kg/s)1.10×107 Pas(1-(0.0500/0.130)3)3π(900 kg/m3)(0.0500 m)3(-0.00257)=-3.81×107 Pa (118)

which the engineer must use to get the required throughput.

(ii) Using Eqs. (106), (90) and P≡2λΔp/μ, 𝓡r-ri/ro-ri and ξθ-θi /θo -θi from Table 3, she gets the expression for the temperature rise in the converging die:

(119)T-T0=[2Δpκ3ρC˜p(1-κ3)][1-ro3r3]A (119)

and since the temperature peaks at ri :

(120)Tmax-T0=-2AΔpρC˜p (120)

Inserting the physical properties, A and Eq. (118) into Eq. (120), she gets:

(121)Tmax-T0=-2(-0.0941)3.81×107 Pa(900 kg/m3)1.60×103 J/kg-°C=4.98°C (121)

which she can then add to the temperature rise for the die land, to see if her polymer extrudate will exceed its degradation point.

At the end, she verifies the two flow conditions: Re≪1 and Pé≪1. Using Eqs. (130):

(122)ReρVmaxriμ (122)

where Vmax is calculated using Eq. (42):

(123)Vmax=|vr(ri,θmin,vr)|=|ΔpAri2μ(1(ri/ro)3)| (123)
(124)Vmax=|vr(0.0500 m,20.2°)|=|3.81×107 Pa(-0.0941)0.0500 m2(1.10×107 Pas)(1-(0.0500/0.013)3)|=0.0086 m/s (124)

She gets, after inserting Eq. (124) and the physical properties into Eq. (122):

(125)Re=(900 kg/m3)0.0086 m/s (0.0500 m)1.10×107Pas=3.52×10-8 (125)

which is ≪1.

She then uses Eq. (92) and Table 2 to get:

(126)Pé=kμ(ro-ri)(ρC˜p)2ro3(Tmax-T0) (126)

Inserting Eq. (121) and the physical properties into Eq. (126) gives:

(127)=(0.1 W/m)1.10×107Pas(0.130 m-0.0500 m)(900 kg/m3)2(1.60×103 J/kg-°C)2(0.130 m)34.98°C=3.88×10-6 (127)

which is also ≪1.

This specific worked example happens to be the one we chose to illustrate in Figure 1.

6 Conclusion

This paper attacks the problem relevant to the connection between a plastics extruder and a pipe extrusion die: the pressure-driven flows, converging or diverging, through the annulus between coapical coaxial cones. Using the transport phenomena approach we arrive at (1) an exact solution for the velocity profile [Eq. (67)] which we integrate to get (2) the throughput per unit pressure drop [Eq. (75)] and (3) the temperature rise [Eqs. (106) and (107)]. We care about this rise because it often governs maximum throughput, since pipe makers must keep the melt from degrading. Equation (75) and Eqs. (106) and (107) are the two main results of this work, which we cast in dimensionless terms (see Table 3) and which we illustrate in Figures 8, 9 and 11.

Our first main result, the exact solution for the throughput [Eq. (75)] is subject to the dimensionless constraints on the geometry, A≪1, on the flow field, Re≪1 (see Appendix 7.1), that is that fluid inertia be negligible. We find that these constraints normally apply to plastic pipe extrusion. Our second main result, the exact solution for the temperature rise [Eqs. (106) and (107)], is subject to the dimensionless constraints, A≪1, and on the flow field, Pé≪1, that is, that latitudinal conduction is negligible relative to radial convection. We find this exact solution for the temperature rise to be consistent with isothermal, inner and outer die walls, and we thus calculate the corresponding heat flux requirements for cooling [Eqs. (109)–(112)]. To teach practitioners how to use our main results, we crafted Figure 11 and our two-part worked example (see Section 5).

We are unaware of any temperature rise measurements on flow through conical annuli, with which Eqs. (106) and (107) might be compared. Whereas we do find flow rate measurements reported for non-Newtonian fluids pumped through converging dies [6], we find none for Newtonian fluids, with which Eq. (75) might be compared. Moreover, the non-Newtonian flow rate measurements that we do find [6] are for only a slight convergent conical die (θo =12°, θi =10° and κ12).

In this paper, we have focused on the extrusion of pipe, or tubing, or catheters. We close by noting that our work will be at least as useful to those designing diverging dies for blow molding [21], [22], [23], [24].


Corresponding author: A. Jeffrey Giacomin, Chemical Engineering Department, Queen’s University, Kingston, ON K7L 3N6, Canada; Polymers Research Group, Queen’s University, Kingston, ON K7L 3N6, Canada; and Mechanical and Materials Engineering Department, Queen’s University, Kingston, ON K7L 3N6, Canada, e-mail: .

Acknowledgments

A. Jeffrey Giacomin is indebted to the Faculty of Applied Science and Engineering of Queen’s University at Kingston, for its support through a Research Initiation Grant. This research was undertaken, in part, thanks to support from the Canada Research Chairs program of the Government of Canada for the Natural Sciences and Engineering Research Council of Canada Tier 1 Canada Research Chair in Rheology. Georges R. Younes acknowledges Mrs. Nadia Moufarrej of the Faculty of Engineering and Architecture of the American University of Beirut for her invaluable support.

7 Appendices

7.1 Reynolds number

In this paper, to obtain our main results [Eq. (75)], we neglected fluid inertia. In this appendix, we closely examine this assumption by defining the Reynolds number for the pressure-driven flows, converging or diverging, through the annulus between coapical coaxial cones. Retaining the inertial terms in Eq. (18) and still neglecting gravity, and since p(r), gives:

(128)ρCμr=r42Cμdpdr-12Csinθddθ(dCdθsinθ) (128)

which, using Table 3, can be rewritten as:

(129)Reκ𝓒Δ𝓟=r4[R(1-κ)+κ]2Cμdpdr-(R(1-κ)+κ2Csinθ)ddθ(dCdθsinθ) (129)

in which we have uncovered the Reynolds number for pressure-driven flows through the annulus between coapical coaxial cones:

(130)ReρVmaxriμ (130)

Since for most polymeric liquids the viscosity μ is large, Re≪1.

7.2 Latitudinal symmetry of𝓒

Using Table 3 to adimensionalize Eq. (49) and rearranging we get:

(131)𝓟ξ=2κ3[𝓡(1-κ)+κ]3d𝓒dξ (131)

Since 𝓟(𝓡):

(132)0=1[𝓡(1-κ)+κ]3d𝓒dξ (132)

and thus:

(133)d𝓒dξ=0=ddθ (133)

since 𝓒 is proportional to ℂ and since ξ is just normalized θ.

References

[1] Bird RB, Stewart WE, Lightfoot EN. Transport Phenomena. 1st ed., Wiley: New York, 1960.Search in Google Scholar

[2] Bird RB, Stewart WE, Lightfoot EN. Transport Phenomena, 2nd ed., John Wiley & Sons: New York, 2002.Search in Google Scholar

[3] Parnaby J, Worth RA. Proc. Inst. Mech. Eng. 1974, 188, 357–364. Erratum: In Eq. (4), η0 should be 10.1243/PIME_PROC_1974_188_041_02Search in Google Scholar

[4] Dijksman JF, Savenije EPW. Rheol. Acta 1985, 24, 105–118.10.1007/BF01333237Search in Google Scholar

[5] Kolitawong C, Giacomin AJ. Polym.-Plast. Technol. Eng. 2001, 40, 363–384.10.1081/PPT-100000254Search in Google Scholar

[6] Liang JZ. Polym.Test. 2003, 22, 497–501. Erratum: In Table 1, the unit for K should be (Pa sn) instead of (Pas). Addendum: In Eq. (11) in [16] and Eq. (6) in this paper, θ[=]rad.10.1016/S0142-9418(02)00103-4Search in Google Scholar

[7] Kolitawong C, Kananai N, Giacomin AJ, Nontakaew U. J. Non-Newtonian Fluid Mech. 2011, 166, 133–144.10.1016/j.jnnfm.2010.11.004Search in Google Scholar

[8] Githuku DN, Giacomin AJ. J. Eng. Mater. Technol. 1992, 114, 81–83.10.1115/1.2904145Search in Google Scholar

[9] Githuku DN, Giacomin AJ. J. Eng. Mater. Technol. 1993, 115, 433–439.10.1115/1.2904242Search in Google Scholar

[10] Githuku DN, Giacomin AJ. Int. Polym. Process. 1992, 7, 140–143.10.3139/217.920140Search in Google Scholar

[11] Githuku DN, Giacomin AJ. In Proceedings, First International Conference on Transport Phenomena in Processing, Pacific Institute for Thermal Engineering, Honolulu, HI (March 22-26, 1992), Guceri SI, Ed., Technomic Publishers Inc.: Lancaster, PA, 1992, pp 997–1012.Search in Google Scholar

[12] Githuku DN, Giacomin AJ. Proceedings, Polymer Processing Society, Seventh Annual Meeting, Hamilton, Canada, April 21–24, 1991, p 260.Search in Google Scholar

[13] Giacomin AJ, Doshi SR. In SPE Tech. Paper, XXXIV, Society of Plastics Engineers, Proc. 46th Annual Tech. Conf. & Exhib., Atlanta, GA, 1988, pp 38–40.Search in Google Scholar

[14] Kolitawong C, Giacomin AJ, Nontakaew U. Polym. Eng. Sci. 2013, 53, 2205–2218.10.1002/pen.23464Search in Google Scholar

[15] Pittman JFT, Whitham GP, Beech S, Gwynn D. Int. Polym. Process. 1994, 9, 130–140.10.3139/217.940130Search in Google Scholar

[16] Pittman JFT, Farah IA. Plast. Rubber Compos. Process. Appl. 1996, 25, 305–312.Search in Google Scholar

[17] Pittman JFT, Whitham GP, Farah IA. Polym. Eng. Sci. 1995, 35, 921–928.10.1002/pen.760351106Search in Google Scholar

[18] Pittman JFT, Farah IA. Computer Simulation of the Cooling Process in Plastic Pipe Manufacture, Including Sag, Thermal Stress and Morphology, Proc. Plastic Pipes IX (Inst. Materials) Edinburgh 1995, 364–371.Search in Google Scholar

[19] Saengow C, Giacomin AJ, Kolitawong C. J. Non-Newtonian Fluid Mech. 2015, 223, 176–199.10.1016/j.jnnfm.2015.05.009Search in Google Scholar

[20] Middleman S. Fundamentals of Polymer Processing. McGraw-Hill: New York, 1977, pp 120–121. Addendum: In Problem 5-37, Y≡y0/y1≡y0/(y0+L), κri /ro ≡tan α/tan β and R0≡y0 tan β.Search in Google Scholar

[21] Stanfill KO. Measurement of Nonlinear Viscoelastic Shear Properties of High Density Polyethylene Programmed Parison Blow Molding Resins Using a Unique Mode Switch Test, Master’s Thesis, Texas A&M University, Mechanical Engineering Dept., College Station, TX (March, 1992).Search in Google Scholar

[22] Giacomin AJ, Jeyaseelan RS, Stanfill KO. Polym. Eng. Sci. 1994, 34, 888–893.10.1002/pen.760341104Search in Google Scholar

[23] Garcia-Rejon A, Dealy JM. Polym. Eng. Sci. 1982, 22, 158–165.10.1002/pen.760220305Search in Google Scholar

[24] Luo XL, Mitsoulis E. J. Rheol. 1989, 33, 1307–1327.10.1122/1.550053Search in Google Scholar

Received: 2015-9-8
Accepted: 2015-9-28
Published Online: 2015-12-19
Published in Print: 2016-9-1

©2016 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 13.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2015-0382/html
Scroll to top button