Solution properties of polyaniline/carbon particle composites
-
Huseyin Zengin
,
Erdal Bayir
Abstract
This study reports on the synthesis of polymer polyaniline, a conductive polymer by nature, and the preparation of polyaniline/carbon particle (PANI/CP) composites by in situ polymerization. The solution properties and conductivities in solution of synthesized PANI and PANI/CP materials were analyzed. The viscosity of PANI and PANI/CP composite materials in N-methylpyrrolidinone (NMP) solvent at different temperatures was measured to examine their behavior in solution. Initially, the viscosity-molecular weight of PANI polymer was measured and calculated to be 78,521. The viscosities of PANI and PANI/CP composite materials decreased as the temperature increased. However, the viscosities of PANI/CP composite materials increased as the percent CP content in the composites increased. The ionic conductivities and pH changes in NMP solvent, measured at different concentrations of PANI and PANI/CP composite materials, and prepared in different ratios, were measured to investigate their behavior in solution. The ionic conductivities of PANI/CP composite materials increased as the percent CP content in the composites increased. Changes in the pH of PANI/CP composite materials decreased as the percent CP content in the composites increased. The conductivity of PANI/10% CP composite material in solution was greater than that of neat PANI polymer in solution; this indicated that CPs in PANI/10% CP composite materials made important positive contributions to the conductivities.
Acknowledgments
The authors gratefully acknowledge the Scientific and Technical Research Council of Turkey (TUBITAK) for the financial support (project no: 104M367). They also thank the Departments of Chemistry of Gaziantep University and Kahramanmaras Sutcu Imam University.
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©2016 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Review
- The role of poly(acrylic acid) in conventional glass polyalkenoate cements
- Original articles
- Development of a polystyrene latex-based reagent for rheumatoid factor detection
- Biodegradation study of bio-corn flour filled low density polyethylene composites assessed by natural soil
- Efficacy of PU foam materials for scientific investigation in footwear research
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- Solution properties of polyaniline/carbon particle composites
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Artikel in diesem Heft
- Frontmatter
- Review
- The role of poly(acrylic acid) in conventional glass polyalkenoate cements
- Original articles
- Development of a polystyrene latex-based reagent for rheumatoid factor detection
- Biodegradation study of bio-corn flour filled low density polyethylene composites assessed by natural soil
- Efficacy of PU foam materials for scientific investigation in footwear research
- Degradation of PVDF-based composite membrane and its impacts on membrane intrinsic and separation properties
- Fabrication of cellulose fine fiber based membranes embedded with silver nanoparticles via Forcespinning
- Influence of wax content on the electrical, thermal and tribological behaviour of a polyamide 6/graphite composite
- In situ formation of copper nanoparticles in a p(NIPAM-VAA-AAm) terpolymer microgel that retains the swelling behavior of microgels
- Possible application of lead sulfide quantum dot in memory device
- Solution properties of polyaniline/carbon particle composites
- Preparation and characterization of SiO2/fluoroalkyl-trialkoxysilane/2-hydroxyethyl methacrylate/trimethylolpropane triacrylate and SiO2/3-(trimethoxysilyl)propyl methacrylate/ 2-hydroxyethyl methacrylate/trimethylolpropane triacrylate coatings on glass substrates using the sol-gel method
- The performance and morphology of PMMA/SAN/ABS blends
