Home Physical Sciences Preparation and characterization of SiO2/fluoroalkyl-trialkoxysilane/2-hydroxyethyl methacrylate/trimethylolpropane triacrylate and SiO2/3-(trimethoxysilyl)propyl methacrylate/ 2-hydroxyethyl methacrylate/trimethylolpropane triacrylate coatings on glass substrates using the sol-gel method
Article
Licensed
Unlicensed Requires Authentication

Preparation and characterization of SiO2/fluoroalkyl-trialkoxysilane/2-hydroxyethyl methacrylate/trimethylolpropane triacrylate and SiO2/3-(trimethoxysilyl)propyl methacrylate/ 2-hydroxyethyl methacrylate/trimethylolpropane triacrylate coatings on glass substrates using the sol-gel method

  • Wei-Ming Chiu , Jhih-Siao Syu , Peir-An Tsai EMAIL logo and Jyh-Horng Wu EMAIL logo
Published/Copyright: July 24, 2015
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 36 Issue 3

Abstract

Organic/inorganic hybrid materials were formed using the sol-gel process, in which SiO2/fluoroalkyl-trialkoxysilane (FAS)/2-hydroxyethyl methacrylate (2-HEMA)/trimethylolpropane triacrylate (TMPTA) and SiO2/3-(trimethoxysilyl)propyl methacrylate (MSMA)/ 2-HEMA/TMPTA thin films were formed on a glass substrate using dip coating. Experimental results revealed that FAS and MSMA improved the pencil hardness of SiO2/2-HEMA/TMPTA thin films without affecting their optical properties. FAS strengthened the hydrophobic and hydrophilic characteristics of SiO2/2-HEMA/TMPTA thin films more than did MSMA. However, an excess of FAS and an increase in withdrawal rates deteriorates the gloss, because both increased the SiO2 content, reducing the reflectivity.

Keywords: gloss; hydrophilic; hydrophobic; sol-gel process
Corresponding authors: Peir-An Tsai, General Education Center, Jen-Teh Junior College of Medicine, Nursing and Management, Houlong, 356, Miaoli County, Taiwan, e-mail: ; and Jyh-Horng Wu, Green Energy and Eco-Technology System Center, Industrial Technology Research Institute, Tainan, Taiwan, e-mail:

References

[1] Shang HM, Wang YS, Limmer J, Chou TP, Takahashi K, Cao GZ. Thin Solid Films 2005, 472, 37–43.10.1016/j.tsf.2004.06.087Search in Google Scholar

[2] Lien SY, Wuu DS, Yeh WC, Liu JC. Sol. Energy Mater. Sol. Cells 2006, 90, 2710–2719.10.1016/j.solmat.2006.04.001Search in Google Scholar

[3] Zhao Q, Dong Y, Wang P, Zhao X. J. Rare Earths 2007, 25, 64–67.10.1016/S1002-0721(07)60525-0Search in Google Scholar

[4] Cheng LP, Chen CC, Lin DJ, Don TM, Huang FH. J. Non-Cryst. Solids 2008, 354, 3828–3835.10.1016/j.jnoncrysol.2008.04.010Search in Google Scholar

[5] Fujishima A, Liu Z, Zhang X, Murakami T. Sol. Energy Mater. Sol. Cells 2008, 92, 1434–1438.10.1016/j.solmat.2008.06.005Search in Google Scholar

[6] Kim JK, Joo W, Kim Y, Jang S. Thin Solid Films 2011, 519, 3804–3808.10.1016/j.tsf.2011.01.107Search in Google Scholar

[7] Yu YY, Chien WC, Tsai TW, Yu HH. Mater. Chem. Phys. 2011, 126, 962–972.10.1016/j.matchemphys.2010.11.056Search in Google Scholar

[8] Hwangbo CK, Sobahan KMA, Park YJ, Kim JJ. Opt. Commun. 2011, 284, 873–876.10.1016/j.optcom.2010.09.075Search in Google Scholar

[9] Purcar V, Stamatin I, Cinteza O, Petcu C, Raditoiu VM, Miclaus TA. Surf. Coat. Technol. 2012,206, 4449–4454.10.1016/j.surfcoat.2012.04.094Search in Google Scholar

[10] Nakagawa T, Soga M. J. Non-Cryst. Solids 1999, 260, 167–174.10.1016/S0022-3093(99)00594-3Search in Google Scholar

[11] Akamatsu Y, Makita K, Inaba H, Miinami T. Thin Solid Films 2001, 389, 138–145.10.1016/S0040-6090(01)00901-4Search in Google Scholar

[12] Hess DW, Wong CP, Xiu Y. J. Colloid Interface Sci. 2008, 326, 465–470.10.1016/j.jcis.2008.06.042Search in Google Scholar PubMed

[13] Chang FC, Sheen YC, Chang WH, Chen WC, Chang YH, Huang YC. Mater. Chem. Phys. 2009, 114, 63–68.10.1016/j.matchemphys.2008.07.132Search in Google Scholar

[14] Wu YL, Ngian SK, Chen Z, Xuan DTT. Appl. Surf. Sci. 2011, 257, 2965–2969.10.1016/j.apsusc.2010.10.101Search in Google Scholar

[15] Basu BJ, Kumar VD, Anandan C. Appl. Surf. Sci. 2012, 261, 807–814.10.1016/j.apsusc.2012.08.103Search in Google Scholar

Received: 2015-5-7
Accepted: 2015-6-25
Published Online: 2015-7-24
Published in Print: 2016-4-1

©2016 by De Gruyter

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. The role of poly(acrylic acid) in conventional glass polyalkenoate cements
  4. Original articles
  5. Development of a polystyrene latex-based reagent for rheumatoid factor detection
  6. Biodegradation study of bio-corn flour filled low density polyethylene composites assessed by natural soil
  7. Efficacy of PU foam materials for scientific investigation in footwear research
  8. Degradation of PVDF-based composite membrane and its impacts on membrane intrinsic and separation properties
  9. Fabrication of cellulose fine fiber based membranes embedded with silver nanoparticles via Forcespinning
  10. Influence of wax content on the electrical, thermal and tribological behaviour of a polyamide 6/graphite composite
  11. In situ formation of copper nanoparticles in a p(NIPAM-VAA-AAm) terpolymer microgel that retains the swelling behavior of microgels
  12. Possible application of lead sulfide quantum dot in memory device
  13. Solution properties of polyaniline/carbon particle composites
  14. Preparation and characterization of SiO2/fluoroalkyl-trialkoxysilane/2-hydroxyethyl methacrylate/trimethylolpropane triacrylate and SiO2/3-(trimethoxysilyl)propyl methacrylate/ 2-hydroxyethyl methacrylate/trimethylolpropane triacrylate coatings on glass substrates using the sol-gel method
  15. The performance and morphology of PMMA/SAN/ABS blends
https://doi.org/10.1515/polyeng-2015-0197
Keywords for this article
gloss; hydrophilic; hydrophobic; sol-gel process

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. The role of poly(acrylic acid) in conventional glass polyalkenoate cements
  4. Original articles
  5. Development of a polystyrene latex-based reagent for rheumatoid factor detection
  6. Biodegradation study of bio-corn flour filled low density polyethylene composites assessed by natural soil
  7. Efficacy of PU foam materials for scientific investigation in footwear research
  8. Degradation of PVDF-based composite membrane and its impacts on membrane intrinsic and separation properties
  9. Fabrication of cellulose fine fiber based membranes embedded with silver nanoparticles via Forcespinning
  10. Influence of wax content on the electrical, thermal and tribological behaviour of a polyamide 6/graphite composite
  11. In situ formation of copper nanoparticles in a p(NIPAM-VAA-AAm) terpolymer microgel that retains the swelling behavior of microgels
  12. Possible application of lead sulfide quantum dot in memory device
  13. Solution properties of polyaniline/carbon particle composites
  14. Preparation and characterization of SiO2/fluoroalkyl-trialkoxysilane/2-hydroxyethyl methacrylate/trimethylolpropane triacrylate and SiO2/3-(trimethoxysilyl)propyl methacrylate/ 2-hydroxyethyl methacrylate/trimethylolpropane triacrylate coatings on glass substrates using the sol-gel method
  15. The performance and morphology of PMMA/SAN/ABS blends
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 21.2.2026 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2015-0197/html
Scroll to top button