Startseite The preparations of nanoporous carbon with multi-heteroatoms co-doping from black liquor powders for supercapacitors
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The preparations of nanoporous carbon with multi-heteroatoms co-doping from black liquor powders for supercapacitors

  • Pengfei Hao ORCID logo , Yanjie Yi , Youming Li und Yi Hou EMAIL logo
Veröffentlicht/Copyright: 22. Oktober 2021
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Abstract

A green and economically viable route without any additional activation agents and templates has been developed to synthesize biomass-derived nanoporous carbon for superior electric double-layer capacitors via direct pyrolysis of dried black liquor powders, which is the main waste in pulping and paper-making industry. The resulting carbon materials present hierarchical porosity and moderate specific surface area of 1134  m 2 g 1 , as well as multi-heteroatoms co-doping such as N, S, Na and K, which exist originally in black liquor. When evaluated as electrode materials for supercapacitors in 6 M KOH aqueous electrolyte, the-prepared carbon samples deliver a significantly high gravimetric capacitance of 331  F g 1 at 0.5  A g 1 in a three-electrode system. Moreover, the fabricated symmetric supercapacitor also possesses a gravimetric capacitance of 211  F g 1 at 0.5  A g 1 , with an impressive long-term cycling stability of 92 % capacitance retention after 3000 cycles. This work explores a suitable and scalable approach for mass production of high-performance electrode materials with industrial wastes on the base of cost-efficiency and environment-friendship.


Article note

Pengfei Hao and Yanjie Yi contributed equally to this work.


Award Identifier / Grant number: 2021A1515010645

Award Identifier / Grant number: 2020A1414010123

Award Identifier / Grant number: 2019A0103008

Award Identifier / Grant number: 201803010080

Funding statement: The authors are grateful for the support of the Science and Technology Planning Project of Guangdong Province (2021A1515010645, 2020A1414010123, 2019A0103008) the Science and Technology Planning Project of Guangzhou City, China (201803010080).

  1. Author contributions: All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Pengfei Hao, Yanjie Yi, Youming Li and Yi Hou. The first draft of the manuscript was written by Pengfei Hao and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

  2. Conflict of interest: The authors declare that they have no competing interests.

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Received: 2021-08-23
Accepted: 2021-09-25
Published Online: 2021-10-22
Published in Print: 2022-03-28

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Chemical pulping
  3. Evaluation of fines separation from unbleached softwood kraft pulp using microperforated hole screens
  4. Evaluation of pulp and paper making properties of Caesalpinia decapetela
  5. Novel bulking technologies for cellulose fibres
  6. Mechanical pulping
  7. Interpretation of force profiles in mill-scale LC refining
  8. Effects of plate wear on bar forces and fiber properties in a mill scale LC-refiner
  9. Paper technology
  10. Research on the physical properties of calcium sulfate whisker and the effects of its addition on paper and its printing performance
  11. Preparation and properties of an intelligent adjustable functional paper for organic cultural relics
  12. Paper chemistry
  13. Application of DSA to improve strength of thermomechanical pulp blended paper
  14. Coating
  15. The influence of pigment modulus on failure resistance of paper barrier coatings
  16. Effect of filler additions on pilot-scale extrusion coating of paperboard with PLA-based blends
  17. Packaging
  18. Influence of paper properties on adhesive strength of starch gluing
  19. Environmental impact
  20. Interfering elements on determination of hexavalent chromium in paper materials with UV-vis spectrophotometry
  21. Nanotechnology
  22. Enhanced mechanical and gas barrier performance of plasticized cellulose nanofibril films
  23. Lignin
  24. The preparations of nanoporous carbon with multi-heteroatoms co-doping from black liquor powders for supercapacitors
  25. Miscellaneous
  26. Hybrid films from plant and bacterial nanocellulose: mechanical and barrier properties
  27. Mass-balance based soft sensor for monitoring ash content at two-ply paperboard manufacturing
  28. Investigation of the effect of light fastness on the color changes of maps prepared by electrophotographic digital printing
  29. Bulking of cellulose fibres – a review
  30. Preparation of O-HACC/HEC-acrylate emulsion and its application in paper protection
  31. Mineral-filled biopolyester coatings for paperboard packaging materials: barrier, sealability, convertability and biodegradability properties
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