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Crystal structure of bis(diethylammonium) tridecathiotrimolybdate, (Et2NH2)2[Mo3S13]

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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 241 Issue 2

Abstract

C8H24N2Mo3S13, monoclinic, P21/m (no. 11), a = 10.536(3) Å, b = 19.844(7) Å, c = 13.149(5) Å, β = 108.503(11)°, V = 2607.0 Å3, Z = 4, R gt (F) = 0.0291, wR ref (F2) = 0.0652, T = 223 K.

CCDC no.: 2523086

The molecular structure is shown in the figure. Table 1 contains the crystallographic data and the list of the atoms including atomic coordinates and displacement parameters can be found in the cif-file attached to this article.

Table 1:

Data collection and handling.

Crystal: Brown block
Size: 0.08 × 0.07 × 0.03 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 2.46 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω scans
θmax, completeness: 28.5°, 100 %
N(hkl)measured, N(hkl)unique, Rint: 79359, 6785, 0.077
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 5,141
N(param)refined: 253
Programs: Bruker, 1 SHELX, 2 WinGX, 3 Diamond 4

1 Source of materials

NH 4 2 MoS4 (0.020 g, 0.077 mmol) and Et2NH2Cl (0.050 g, 0.46 mmol) were charged to a Pyrex tube with diameter of 9 mm and about 0.5 mL MeOH was added as a solvent. While the solvent was being frozen, the Pyrex tube was evacuated under vacuum and sealed with the use of a flame. The sealed tube was placed in an oven and heated at 110 °C for one day, then cooled in an ice/water bath for over 6 h. Dark brown block crystals were isolated by filtration and washed with MeOH and diethyl ether several times. Crystals of Et 2 NH 2 2 [Mo3S13] were obtained in 23 % yield, based on the Mo metal used.

2 Experimental details

H atoms were positioned geometrically and treated as riding, with N–H = 0.89, C–H = 0.98 (CH2) and 0.97 (CH3) Å with Uiso(H) = 1.2 Ueq(N) and 1.2 (1.5 for methyl) Ueq(C). H atoms of the CH3 were positioned to be staggered with respect to the shortest other bond to the atom to which the CH3 is attached.

3 Comment

The Mo 3 Q 13 2 − (Q = S, Se) cluster anion has attracted significant interest due not only to its novel structure but also to its diverse applications, such as in catalysis and as a precursor. 5 , 6 Recently, an unsymmetrical mixed tetraalkylammonium cation, BuMe3N+, was reported to be effective in stabilizing the Mo 3 S 13 2 − anion when solvothermal synthetic approaches were employed. 7 In the search for other organic cations capable of such stabilization, we found that the diethylammonium cation, Et2 NH 2 + , can also stabilize the Mo 3 S 13 2 − anion. Herein, we report the preparation and structural characterization of Et 2 NH 2 2 [Mo3S13].

The solvothermal reaction of NH 4 2 MoS 4 with Et2NH2Cl afforded Et 2 NH 2 2 [Mo3S13], which comprises a Mo 3 S 13 2 − anion and two charge-balancing diethylammonium cations. As observed in the synthesis of BuMe 3 N 2 [Mo3S13], the Mo(VI) metal in NH 4 2 MoS 4 appears to be reduced to Mo(IV) through the oxidation of S2− to S 2 2 − , leading to the formation of the [ Mo 4 + 3 (S2−) S 2 2 − 6 2 − species – namely, the Mo 3 S 13 2 −  anion.

In the structure of Et 2 NH 2 2 [Mo3S13], there are two crystallographically independent diethylammonium cations and two Mo 3 S 13 2 − clusters, in which three Mo centers are linked to form a triangle capped by an apical sulfur atom. Three bridging and three terminal disulfide ( S 2 2 − ) ligands complete the formation of the Mo 3 S 13 2 − cluster. In both Mo 3 S 13 2 − clusters, one Mo atom, one apical S atom, one bridging disulfide, and one terminal disulfide ligand lie on a crystallographic mirror plane.

The two Mo 3 S 13 2 − clusters exhibit nearly identical shape and size. The Mo–Mo bond distances range from 2.710(1) to 2.721(1) Å (average: 2.717 Å) in one cluster, and from 2.708(1) to 2.720(1) Å (average: 2.716 Å) in the other. These average Mo–Mo bond distances are slightly shorter than those reported for Mo 3 S 13 2 − clusters stabilized by BuMe3N+ (2.741 Å), 7 Me4N+ (2.735, 2.733 Å), 8 , 9 Ph4As+ (2.725 Å), 10 NH 4 + (2.722 Å), 11 and Cs+ (2.719 Å), 12 indicating that the Mo 3 S 13 2 − clusters in Et 2 NH 2 2 [Mo3S13] are the most compact among those stabilized by monovalent cations.

The triangular Mo3S3 core formed by three Mo atoms and three bridging disulfide sulfur atoms is nearly planar, with maximum deviations from planarity of 0.114 Å and 0.130 Å in the two respective clusters. The Mo–S and S–S bond distances are consistent with those observed in previously reported Mo 3 S 13 2 − structures. The shortest S⋯H contacts occur between S(18) and H(2NA) at 2.425(1) Å, and between S(7) and H(1NA) at 2.455(1) Å, indicating weak hydrogen bonding interactions between the Mo 3 S 13 2 − clusters and Et2 NH 2 + cations.

Corresponding author: Kang-Woo Kim, Department of Chemistry & Research Institute for Natural Sciences, Incheon National University, Incheon 22012, Korea, E-mail:

Acknowledgements

This work was supported by the Incheon National University Research Grant in 2025.

References

1. Bruker Apex2 and Saint; Bruker AXS Inc.: Madison, Wisconsin, USA, 2012.Search in Google Scholar

2. Sheldrick, G. M. Crystal Structure Refinement with Shelxl. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

3. Farrugia, L. J. WinGX and Ortep for Windows: An Update. J. Appl. Crystallogr. 2012, 45, 849–854; https://doi.org/10.1107/s0021889812029111.Search in Google Scholar

4. Brandenburg, K. Diamond. Visual Crystal Structure Information System; Crystal Impact: Bonn, Germany, 2015.Search in Google Scholar

5. Batool, S.; Nandan, S. P.; Myakala, S. N.; Rajagopal, A.; Schubert, J. S.; Ayala, P.; Naghdi, S.; Saito, H.; Bernardi, J.; Streb, C.; Cherevan, A.; Eder, D. Surface Anchoring and Active Sites of [Mo3S13]2− Clusters as Co-catalysts for Photocatalytic Hydrogen Evolution. ACS Catal. 2022, 12, 6641–6650; https://doi.org/10.1021/acscatal.2c00972.Search in Google Scholar PubMed PubMed Central

6. Islam, T.; Roy, S. C.; Bayat, S.; Weret, M. A.; Hoffman, J. M.; Rao, K. R.; Sawicki, C.; Nie, J.; Alam, R.; Oketola, O.; Donley, C. L.; Kumbhar, A.; Feng, R.; Wiaderek, K. M.; Risko, C.; Amin, R.; Islam, S. M. Mo3S13 Chalcogel: A High-Capacity Electrode for Conversion-Based Li-Ion Batteries. ChemSusChem 2024, 17, e202400084; https://doi.org/10.1002/cssc.202400084.Search in Google Scholar PubMed

7. Kim, K. –W.; Kim, S. Crystal Structure of Bis(N,N,N-trimethylbutanaminium) tridecathiotrimolybdate(2-), (BuMe3N)2[Mo3S13]. Z. Kristallogr. N. Cryst. Struct. 2025, 240, 673–674; https://doi.org/10.1515/ncrs-2025-0193.Search in Google Scholar

8. Lu, S.; Ke, Y.; Li, J.; Zhang, Y. Synthesis, Structure and Characterizations of a Molybdenum Sulfide Complex with Inorganic Cluster [Mo3S13]2−And Organic Amine Me4N+. Cryst. Res. Technol. 2002, 37, 1153–1159; https://doi.org/10.1002/1521-4079(200211)37:11<1153::aid-crat1153>3.0.co;2-4.10.1002/1521-4079(200211)37:11<1153::AID-CRAT1153>3.0.CO;2-4Search in Google Scholar

9. Bensch, W., Schur, M. Crystal Structure of Bis(tetramethylammonium) trismolybdenumtridecasulfide, [N(CH3)4]2Mo3S13. Z. Kristallogr. N. Cryst. Struct. 1997, 212, 303–304; https://doi.org/10.1524/ncrs.1997.212.1.303.Search in Google Scholar

10. Müller, A.; Wittneben, V.; Krickemeyer, E.; Bögge, H.; Lemke, M. Studies on the Triangular Cluster [Mo3S13]2−: Electronic Structure (Xα Calculations, XPS), Crystal Structure of (Ph4As)2[Mo3S13] 2CH3CN and a Refinement of the Crystal Structure of (NH4)[Mo3S13] H2O. Z. Anorg. Allg. Chem. 1991, 605, 175–188.10.1002/chin.199210030Search in Google Scholar

11. Müller, A., Pohl, S., Dartmann, M., Cohen, J. P., Bennett, J. M., Kirchner, R. M. Crystal Structure of (NH4)2 [Mo3S(S2)6] Containing the Novel Isolated Cluster [Mo3S13]2−. Z. Naturforsch. 1979, 34b, 434–436.10.1515/znb-1979-0315Search in Google Scholar

12. Raymond, C. C.; Dorhout, P. K.; Miller, S. M. Hydrothermal Synthesis of a Mixed-Cluster Molybdenum Polysulfide: Cs4[Mo3S(S2)6] [Mo3S(S2)5 (S4)]·0.5H2O. Inorg. Chem. 1994, 33, 2703–2704; https://doi.org/10.1021/ic00091a002.Search in Google Scholar
Received: 2025-11-18
Published Online: 2026-01-30
Published in Print: 2026-04-24

© 2025 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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https://doi.org/10.1515/ncrs-2025-0490
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  2. New Crystal Structures
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  18. The crystal structure of 3-(7,8-dimethoxy-2-oxo-1,2,4,5-tetrahydro-3H-benzo[d]azepin-3-yl)-N-methylpropan-1-aminium chloride monohydrate, C16H27ClN2O4
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  20. The crystal structure of 2-aminobutanamide hydrochloride, C4H11ClN2O
  21. The crystal structure of 4-bromo-2,6-dimethoxybenzaldehyde, C9H9BrO3
  22. The crystal structure of Limaprost, C22H36O5
  23. The crystal structure of (2-butyl-benzofuran-3-yl)(4-hydroxy-3,5-diiodophenyl)methanone, C19H16I2O3
  24. The crystal structure of dimethylammonium poly[(μ2-sulfonato-κ2O:O′)-(μ3-5′- carboxy-2,2′-bipyridine-5-carboxylato- κ3N,N:O′)-copper(II)], C14H15N3O8SCu
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  26. The crystal structure of chlorido-(2,7,12-trimethyl-3,7,11,17-tetra-azabicyclo(11.3.1)heptadeca1 (17),2,11,13,15-pentaene-κ4N,N′,N′,N′′′)copper(II) perchlorate hydrate, C16H26Cl2CuN4O5
  27. The crystal structure of chlorido-(2,4-dichloro-6-formylphenolato-κ2O,O′)-(2,2′-bipyridine-κ2N,N′)-copper(II), C17H11Cl3CuN2O2
  28. The crystal structure of poly[diaqua-bis(μ2-3,5-dichloroisonicotinato-κ2O:N)cobalt] tetrahydrate
  29. Crystal structure of (E)-(4-(1-phenylhept-1-en-2-yl)-1H-pyrrole-3-carbonyl) ferrocene, C28H29FeNO
  30. Crystal structure of tert-butyl 5-allyl-4-hydroxyisoindoline-2-carboxylate, C16H21NO3
  31. The crystal structure of S,S′-bis(2-(2-benzoselenazolyl)phenyl)disulfide, C26H16N2S2Se2
  32. Crystal structure of 1,1,6a,7,12,12a-hexamethyl-6,6a,7,8,9,12,12a,12b-octahydro-1H-cyclopropa[7,8] naphtho[2,3-b]naphtho[2,1-d]furan-2,4,5(1aH)-trione, C27H30O4
  33. The crystal structure of catena-poly[bis(1-benzyl-1,2,3-triazole-4,5-dicarboxylato-κ4N,O,O′:O′′)-bis(μ2-1, 2-di(4-pyridyl)propane-κ2N : N′)zinc(II)], C24H21N5O4Zn
  34. Crystal structure of N-(2-(1-phenylvinyl)phenyl)–N-tosylacrylamide, C24H21NO3S
  35. The crystal structure of ethylenediammonium bis(4-isopropyltropolonate)
  36. Crystal structure of 1-bromo-5-(2,2-difluoropropyl)-5-methylbenzo[4,5]imidazo [2,1-a]isoquinolin-6(5H)-one, C19H15BrF2N2O
  37. Crystal structure of (tert-butoxycarbonylmethyl)triphenylphosphonium chloride, C24H26ClO2P
  38. Hydrothermal synthesis and crystal structure of poly{tris(μ2-cis -1,4–cyclohexanedicarboxylato)-κ2O: O′] -bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N″]trizinc(II)} trihydrate, C60H72N12O15Zn3
  39. The crystal structure of aminoguanidinium 3-nitro-1,2,4-triazol-5-one
  40. Crystal structure of 1,1′-(phenazine-5,10-diyl)bis(butan-1-one), C20H22N2O2
  41. Crystal structure of trans-diaqua-bis(5-bromopyridine-2-carboxylato k2N,O)iron(III) nitrate monohydrate, C12H12Br2FeN3O10
  42. Crystal structure of [1-(diaminomethylene)thiouron-1-ium] maleate
  43. Crystal structure of bis(diethylammonium) tridecathiotrimolybdate, (Et2NH2)2[Mo3S13]
  44. The crystal structure of methyl 4-(4-(methanesulfonyl)phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C21H25NO5S
  45. Crystal structure of catena-poly[µ2-(9,10-di(4-pyridyl)anthracene)-bis(nitrato-κ1O)-bis(N,N-dimethylformamide-κ1O)cadmium(II)], C30H30CdN6O8
  46. Crystal structure of [N,N′-bis(4-bromosalicylidene)-2,2-dimethylpropane-1,3-diaminato]nickel(II) ethanol monosolvate
  47. The crystal structure of bis(N,N,N′,N′-tetramethyl-1,8-naphthalenediamine)tetrabromidomanganate(II), C28H38Br4MnN4
  48. The crystal structure of ((1E,3Z,6R,7R)-6-(2-(furan-3-yl)ethyl)-6,7-dimethyl-10-methylenecyclodeca-1,3-dien-1-yl)(4-(4-methylbenzyl)piperazin-1-yl)methanone, C32H42N2O2
  49. Crystal structure of tert-butyl (S)-(1-(4-(tert-butoxy)phenyl)-4-diazo-3-oxobutan-2-yl)carbamate, C19H27N3O4
  50. The crystal structure of 2-[4,5-bis(4-bromophenyl)-1H-imidazol-2-yl]-4-bromophenol ethanol solvate, C23H18Br3N2O2
  51. Crystal structure of (3R)-N-((2S,4R,5S)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl) tetrahydro-2H-pyran-4-yl)-3-hydroxydecanamide, C18H38N2O9
  52. Crystal structure of 4-((triphenylphosphonio)methyl)pyridin-1-ium octachlorodiantimonate, C24H22Cl8NPSb2
  53. Crystal structure of bis(2,3,5-triphenyl-2,3-dihydro-1H-tetrazol-1-ium) tetrabromidocadmate(II), C38H30Br4CdN8
  54. Crystal structure of 6–O,8–O-ditigloyl-6β,8α,11-trihydroxygermacra-1(10)E,4E-diene, C25H38O5
  55. Crystal structure of 4-ethyl-3-oxo-3,4-dihydro-6-carbonitrile, C11H9N3O
  56. Crystal structure of 1α,5α-dihydroxy-1-deoxo-13-deoxyenmein, C20H28O6
  57. Synthesis and crystal structure of (4a)-10-hydroxy-heptamethyl–N′-(4-fluorobenzylidene) octadecahydropicene-4a-carbohydrazide monohydrate, C37H53FN2O3
  58. Crystal structure of N-(3-chlorophenyl)-3-methyl-4-nitrobenzamide, C14H11ClN2O3
  59. Crystal structure of trichlorido-2-(4-pyridinium)bis(4-pyridyl)amine zinc(II), [Zn(C15H13N4)Cl3]
  60. Ethyl (E)- (4R,4aS,6aR,9S,11aR,11bS)-8-(propargyloxyimino)-4,9,11b-trimethyl-6a,9-methanocyclohepta[a]naphthalene-4-carboxylate, C25H37NO3
  61. The crystal structure of GaMn3B6O13(OH)
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