Home Physical Sciences Crystal structure of bis(μ3-[bis(2-hydroxyethyl)amino]ethan-1-olato-κ6O:O,O′,N,O″:O″)-bis(μ2-2,2′-[(2-hydroxyethyl)azanediyl]di(ethan-1-olato)-κ5O:O,O′,N,O″)-hexakis(nitrato-κ2O,O′)tetrayttrium (III) methanol solvate, C26H62N10O32Y4
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Crystal structure of bis(μ3-[bis(2-hydroxyethyl)amino]ethan-1-olato-κ6O:O,O′,N,O″:O″)-bis(μ2-2,2′-[(2-hydroxyethyl)azanediyl]di(ethan-1-olato)-κ5O:O,O′,N,O″)-hexakis(nitrato-κ2O,O′)tetrayttrium (III) methanol solvate, C26H62N10O32Y4

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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 241 Issue 2

Abstract

C26H62N10O32Y4, monoclinic, P21/n (no. 14), a = 14.196(2) Å, b = 11.1051(17) Å, c = 16.495(3) Å, β = 105.070(2)° V = 2511.0(7) Å3, Z = 2, Rgt(F) = 0.0368, wRref(F2) = 0.0771, T = 296(2) K. CCDC no.: 2453169.

The molecular structure is shown in the figure. Table 1 contains the crystallographic data and the list of the atoms including atomic coordinates and displacement parameters can be found in the cif-file attached to this article.

Table 1:

Data collection and handling.

Crystal: White block
Size: 0.36 × 0.33 × 0.32 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 4.68 mm−1
Diffractometer, scan mode: Bruker Apex-II, φ and ω scans
θmax, completeness: 27.0°, 100 %
N(hkl)measured, N(hkl)unique, Rint: 14434, 5433, 0.041
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 3672
N(param)refined: 353
Programs: Bruker, 1 Shelx, 2 Diamond 3

1 Source of material

All materials were purchased from commercial suppliers and used without further purification. Tris(2-hydroxyethyl)amine (7.46 mg, 0.05 mmol) and Y(NO3)3·6H2O (19.15 mg, 0.05 mmol) in 10 mL of methanol were sealed in a Teflon-lined stainless steel autoclave. The reaction mixture was heated at 120 °C for 24 h and gradually cooled to room temperature. White block-shaped crystals were obtained with a yield of 38 % based on tris(2-hydroxyethyl)amine.

2 Experimental details

The structure was solved and refined with the SHELX programs. Hydrogen atoms were located in geometrically calculated positions. Their Uiso values were set to 1.2Ueq or 1.5Ueq of the parent atoms.

3 Comment

Design and synthesis of lanthanide complexes with novel structures and properties have attracted increasing attention in the fields of molecular magnets, catalysts, ion recognition, or luminescent materials. 4 , 5 , 6 , 7 As is well known, suitable organic ligands play an important role in the construction of metal complexes, in which the specific ligand fields can effectively regulate the molecular physico-chemical properties. In our previous work, some paramagnetic lanthanide complexes based on tris(2-hydroxyethyl)amine ligand have been synthesized and studied. 8 This multidentate chelating ligand can effectively separate central metal ions in high-symmetry coordination geometry. As a continual work, a multinuclear diamagnetic yttrium(III) complex based on tris(2-hydroxyethyl)amine were further prepared and structurally determined. This complex crystallizes in the monoclinic system with P21/n. The asymmetric unit is one half of the tetranuclear complex (see the figure). Y1(III) ion is eight-coordinated by seven oxygen atoms (O1, O1A, O2, O3, O4, O7, and O8) and one nitrogen atom (N1), while Y2(III) ion is nine-coordinated by eight oxygen atoms (O2, O4, O5, O6, O10, O11, O13, and O14) and one nitrogen atom (N2). The Y–N bond and Y–O bond lengths range from 2.569(3) to 2.979(3) Å, and 2.204(2) to 2.589(3) Å, respectively. Central yttrium(III) ions are connected by two μ2-O units from tris(2-hydroxyethyl)amine ligands to form a zigzag-type Y4 core with intramolecular yttrium(III) ions distance of 3.6798(6) Å.

Corresponding author: Feng Gao, School of Chemistry & Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, P.R. China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by Natural Science Foundation of Jiangsu Normal University (14XLR031).

  3. Conflict of interest: The authors declare no conflicts of interest regarding this article.

References

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Received: 2025-06-23
Accepted: 2025-12-10
Published Online: 2025-12-29
Published in Print: 2026-04-24

© 2025 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 4-bromo-7-(diethylamino)-2-oxo-2 H -chromene-3-carbaldehyde C14H14Br3NO3
  4. The crystal structure of 5-benzyl-4-((4-fluorobenzyl)oxy)-1,5-dimethyl-1,5-dihydro-2H-pyrrol-2-one, C20H20FNO2
  5. Crystal structure of bis(μ3-[bis(2-hydroxyethyl)amino]ethan-1-olato-κ6O:O,O′,N,O″:O″)-bis(μ2-2,2′-[(2-hydroxyethyl)azanediyl]di(ethan-1-olato)-κ5O:O,O′,N,O″)-hexakis(nitrato-κ2O,O′)tetrayttrium (III) methanol solvate, C26H62N10O32Y4
  6. Crystal structure of μ4-oxido-tetrakis(μ4-methanolato-κ2O:O′)tetrakis(μ2-N′-(3-ethoxy-2-hydroxy-benzylidene)-2-hydroxy-benzohydrazide κ5N,O,O′:O′,O″)tetracer(III)–methanol–triethylamine (1/2/2), C82H102Ce4N10O23
  7. Crystal structure of bis(acetato-κ1O)-bis(methanol-κ1O)-(1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol) cobalt(II), C34H50Cl2N6O10Co
  8. Crystal structure of poly[(μ4-5-isopropoxyisophthalato-κ4O:O′:O″:O‴)-pyridine-κ1N)zinc(II)] hydrate, C16H17NO6Zn
  9. Crystal structure of catena-poly[(μ2-tetraoxidomolybdato-κ2O:O′)-(3,10-dipropyl-1,3,5,8,11,12-hexaazacyclotetradecane-κ4N,N′,N″,N″″)dicopper(II)]tetrahydrate C14H42CuN6MoO8
  10. Crystal structure of poly[(μ3-2,2′-bipyridine-6,6′-bi(olato)-κ4-N,N′:O:O′)lead(II)], C10H6N2O2Pb
  11. The crystal structure of methyl 4-(3,5-ditrifluoromethylphenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C20H17F6NO3
  12. The crystal structure of 4-[(1E)-2-nitroethenyl]-1,1′-biphenyl, C14H11NO2
  13. Crystal structure of (E)-3′,6′-bis(diethylamino)-2-((1-(thiazol-2-yl)ethylidene)amino)spiro[isoindoline-1,9′-xanthen]-3-one, C33H35N5O2S
  14. Crystal structure of diethyl 2-(4-bromophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19BrO6
  15. The crystal structure of bis(N,N′-bis(2-methoxyphenyl)-1,1-dimethylsilanediamine-(tetrahydrofurane-κ1O)-lithium(I)), C40H56Li2N4O6Si2
  16. Crystal structure of tetracarbonyl-bis(m2-4-fluorophenyltellate-k2S:S)(ethane-1,2-diyl-bis(diephenylphosphane-k2P,P)diiron(II) (Fe-Fe) C42H32F2Fe2O4P2Te2
  17. The crystal structure of (S)-1-(3,4-dimethoxybicyclo[4.2.0]octa-1(6), 2,4-trien-7-yl)-N-methylmethanamine hydrochloride, C12H18ClNO2
  18. The crystal structure of 3-(7,8-dimethoxy-2-oxo-1,2,4,5-tetrahydro-3H-benzo[d]azepin-3-yl)-N-methylpropan-1-aminium chloride monohydrate, C16H27ClN2O4
  19. The crystal structure of 3,4-dimethoxybicyclo[4.2.0]octa-1(6),2,4-triene-7-carbonitrile, C11H11NO2
  20. The crystal structure of 2-aminobutanamide hydrochloride, C4H11ClN2O
  21. The crystal structure of 4-bromo-2,6-dimethoxybenzaldehyde, C9H9BrO3
  22. The crystal structure of Limaprost, C22H36O5
  23. The crystal structure of (2-butyl-benzofuran-3-yl)(4-hydroxy-3,5-diiodophenyl)methanone, C19H16I2O3
  24. The crystal structure of dimethylammonium poly[(μ2-sulfonato-κ2O:O′)-(μ3-5′- carboxy-2,2′-bipyridine-5-carboxylato- κ3N,N:O′)-copper(II)], C14H15N3O8SCu
  25. The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate n-hexane solvate, C124H156K4P8S8, 2(C6H14)
  26. The crystal structure of chlorido-(2,7,12-trimethyl-3,7,11,17-tetra-azabicyclo(11.3.1)heptadeca1 (17),2,11,13,15-pentaene-κ4N,N′,N′,N′′′)copper(II) perchlorate hydrate, C16H26Cl2CuN4O5
  27. The crystal structure of chlorido-(2,4-dichloro-6-formylphenolato-κ2O,O′)-(2,2′-bipyridine-κ2N,N′)-copper(II), C17H11Cl3CuN2O2
  28. The crystal structure of poly[diaqua-bis(μ2-3,5-dichloroisonicotinato-κ2O:N)cobalt] tetrahydrate
  29. Crystal structure of (E)-(4-(1-phenylhept-1-en-2-yl)-1H-pyrrole-3-carbonyl) ferrocene, C28H29FeNO
  30. Crystal structure of tert-butyl 5-allyl-4-hydroxyisoindoline-2-carboxylate, C16H21NO3
  31. The crystal structure of S,S′-bis(2-(2-benzoselenazolyl)phenyl)disulfide, C26H16N2S2Se2
  32. Crystal structure of 1,1,6a,7,12,12a-hexamethyl-6,6a,7,8,9,12,12a,12b-octahydro-1H-cyclopropa[7,8] naphtho[2,3-b]naphtho[2,1-d]furan-2,4,5(1aH)-trione, C27H30O4
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  36. Crystal structure of 1-bromo-5-(2,2-difluoropropyl)-5-methylbenzo[4,5]imidazo [2,1-a]isoquinolin-6(5H)-one, C19H15BrF2N2O
  37. Crystal structure of (tert-butoxycarbonylmethyl)triphenylphosphonium chloride, C24H26ClO2P
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  39. The crystal structure of aminoguanidinium 3-nitro-1,2,4-triazol-5-one
  40. Crystal structure of 1,1′-(phenazine-5,10-diyl)bis(butan-1-one), C20H22N2O2
  41. Crystal structure of trans-diaqua-bis(5-bromopyridine-2-carboxylato k2N,O)iron(III) nitrate monohydrate, C12H12Br2FeN3O10
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  58. Crystal structure of N-(3-chlorophenyl)-3-methyl-4-nitrobenzamide, C14H11ClN2O3
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  60. Ethyl (E)- (4R,4aS,6aR,9S,11aR,11bS)-8-(propargyloxyimino)-4,9,11b-trimethyl-6a,9-methanocyclohepta[a]naphthalene-4-carboxylate, C25H37NO3
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https://doi.org/10.1515/ncrs-2025-0283
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 4-bromo-7-(diethylamino)-2-oxo-2 H -chromene-3-carbaldehyde C14H14Br3NO3
  4. The crystal structure of 5-benzyl-4-((4-fluorobenzyl)oxy)-1,5-dimethyl-1,5-dihydro-2H-pyrrol-2-one, C20H20FNO2
  5. Crystal structure of bis(μ3-[bis(2-hydroxyethyl)amino]ethan-1-olato-κ6O:O,O′,N,O″:O″)-bis(μ2-2,2′-[(2-hydroxyethyl)azanediyl]di(ethan-1-olato)-κ5O:O,O′,N,O″)-hexakis(nitrato-κ2O,O′)tetrayttrium (III) methanol solvate, C26H62N10O32Y4
  6. Crystal structure of μ4-oxido-tetrakis(μ4-methanolato-κ2O:O′)tetrakis(μ2-N′-(3-ethoxy-2-hydroxy-benzylidene)-2-hydroxy-benzohydrazide κ5N,O,O′:O′,O″)tetracer(III)–methanol–triethylamine (1/2/2), C82H102Ce4N10O23
  7. Crystal structure of bis(acetato-κ1O)-bis(methanol-κ1O)-(1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol) cobalt(II), C34H50Cl2N6O10Co
  8. Crystal structure of poly[(μ4-5-isopropoxyisophthalato-κ4O:O′:O″:O‴)-pyridine-κ1N)zinc(II)] hydrate, C16H17NO6Zn
  9. Crystal structure of catena-poly[(μ2-tetraoxidomolybdato-κ2O:O′)-(3,10-dipropyl-1,3,5,8,11,12-hexaazacyclotetradecane-κ4N,N′,N″,N″″)dicopper(II)]tetrahydrate C14H42CuN6MoO8
  10. Crystal structure of poly[(μ3-2,2′-bipyridine-6,6′-bi(olato)-κ4-N,N′:O:O′)lead(II)], C10H6N2O2Pb
  11. The crystal structure of methyl 4-(3,5-ditrifluoromethylphenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C20H17F6NO3
  12. The crystal structure of 4-[(1E)-2-nitroethenyl]-1,1′-biphenyl, C14H11NO2
  13. Crystal structure of (E)-3′,6′-bis(diethylamino)-2-((1-(thiazol-2-yl)ethylidene)amino)spiro[isoindoline-1,9′-xanthen]-3-one, C33H35N5O2S
  14. Crystal structure of diethyl 2-(4-bromophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19BrO6
  15. The crystal structure of bis(N,N′-bis(2-methoxyphenyl)-1,1-dimethylsilanediamine-(tetrahydrofurane-κ1O)-lithium(I)), C40H56Li2N4O6Si2
  16. Crystal structure of tetracarbonyl-bis(m2-4-fluorophenyltellate-k2S:S)(ethane-1,2-diyl-bis(diephenylphosphane-k2P,P)diiron(II) (Fe-Fe) C42H32F2Fe2O4P2Te2
  17. The crystal structure of (S)-1-(3,4-dimethoxybicyclo[4.2.0]octa-1(6), 2,4-trien-7-yl)-N-methylmethanamine hydrochloride, C12H18ClNO2
  18. The crystal structure of 3-(7,8-dimethoxy-2-oxo-1,2,4,5-tetrahydro-3H-benzo[d]azepin-3-yl)-N-methylpropan-1-aminium chloride monohydrate, C16H27ClN2O4
  19. The crystal structure of 3,4-dimethoxybicyclo[4.2.0]octa-1(6),2,4-triene-7-carbonitrile, C11H11NO2
  20. The crystal structure of 2-aminobutanamide hydrochloride, C4H11ClN2O
  21. The crystal structure of 4-bromo-2,6-dimethoxybenzaldehyde, C9H9BrO3
  22. The crystal structure of Limaprost, C22H36O5
  23. The crystal structure of (2-butyl-benzofuran-3-yl)(4-hydroxy-3,5-diiodophenyl)methanone, C19H16I2O3
  24. The crystal structure of dimethylammonium poly[(μ2-sulfonato-κ2O:O′)-(μ3-5′- carboxy-2,2′-bipyridine-5-carboxylato- κ3N,N:O′)-copper(II)], C14H15N3O8SCu
  25. The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate n-hexane solvate, C124H156K4P8S8, 2(C6H14)
  26. The crystal structure of chlorido-(2,7,12-trimethyl-3,7,11,17-tetra-azabicyclo(11.3.1)heptadeca1 (17),2,11,13,15-pentaene-κ4N,N′,N′,N′′′)copper(II) perchlorate hydrate, C16H26Cl2CuN4O5
  27. The crystal structure of chlorido-(2,4-dichloro-6-formylphenolato-κ2O,O′)-(2,2′-bipyridine-κ2N,N′)-copper(II), C17H11Cl3CuN2O2
  28. The crystal structure of poly[diaqua-bis(μ2-3,5-dichloroisonicotinato-κ2O:N)cobalt] tetrahydrate
  29. Crystal structure of (E)-(4-(1-phenylhept-1-en-2-yl)-1H-pyrrole-3-carbonyl) ferrocene, C28H29FeNO
  30. Crystal structure of tert-butyl 5-allyl-4-hydroxyisoindoline-2-carboxylate, C16H21NO3
  31. The crystal structure of S,S′-bis(2-(2-benzoselenazolyl)phenyl)disulfide, C26H16N2S2Se2
  32. Crystal structure of 1,1,6a,7,12,12a-hexamethyl-6,6a,7,8,9,12,12a,12b-octahydro-1H-cyclopropa[7,8] naphtho[2,3-b]naphtho[2,1-d]furan-2,4,5(1aH)-trione, C27H30O4
  33. The crystal structure of catena-poly[bis(1-benzyl-1,2,3-triazole-4,5-dicarboxylato-κ4N,O,O′:O′′)-bis(μ2-1, 2-di(4-pyridyl)propane-κ2N : N′)zinc(II)], C24H21N5O4Zn
  34. Crystal structure of N-(2-(1-phenylvinyl)phenyl)–N-tosylacrylamide, C24H21NO3S
  35. The crystal structure of ethylenediammonium bis(4-isopropyltropolonate)
  36. Crystal structure of 1-bromo-5-(2,2-difluoropropyl)-5-methylbenzo[4,5]imidazo [2,1-a]isoquinolin-6(5H)-one, C19H15BrF2N2O
  37. Crystal structure of (tert-butoxycarbonylmethyl)triphenylphosphonium chloride, C24H26ClO2P
  38. Hydrothermal synthesis and crystal structure of poly{tris(μ2-cis -1,4–cyclohexanedicarboxylato)-κ2O: O′] -bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N″]trizinc(II)} trihydrate, C60H72N12O15Zn3
  39. The crystal structure of aminoguanidinium 3-nitro-1,2,4-triazol-5-one
  40. Crystal structure of 1,1′-(phenazine-5,10-diyl)bis(butan-1-one), C20H22N2O2
  41. Crystal structure of trans-diaqua-bis(5-bromopyridine-2-carboxylato k2N,O)iron(III) nitrate monohydrate, C12H12Br2FeN3O10
  42. Crystal structure of [1-(diaminomethylene)thiouron-1-ium] maleate
  43. Crystal structure of bis(diethylammonium) tridecathiotrimolybdate, (Et2NH2)2[Mo3S13]
  44. The crystal structure of methyl 4-(4-(methanesulfonyl)phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C21H25NO5S
  45. Crystal structure of catena-poly[µ2-(9,10-di(4-pyridyl)anthracene)-bis(nitrato-κ1O)-bis(N,N-dimethylformamide-κ1O)cadmium(II)], C30H30CdN6O8
  46. Crystal structure of [N,N′-bis(4-bromosalicylidene)-2,2-dimethylpropane-1,3-diaminato]nickel(II) ethanol monosolvate
  47. The crystal structure of bis(N,N,N′,N′-tetramethyl-1,8-naphthalenediamine)tetrabromidomanganate(II), C28H38Br4MnN4
  48. The crystal structure of ((1E,3Z,6R,7R)-6-(2-(furan-3-yl)ethyl)-6,7-dimethyl-10-methylenecyclodeca-1,3-dien-1-yl)(4-(4-methylbenzyl)piperazin-1-yl)methanone, C32H42N2O2
  49. Crystal structure of tert-butyl (S)-(1-(4-(tert-butoxy)phenyl)-4-diazo-3-oxobutan-2-yl)carbamate, C19H27N3O4
  50. The crystal structure of 2-[4,5-bis(4-bromophenyl)-1H-imidazol-2-yl]-4-bromophenol ethanol solvate, C23H18Br3N2O2
  51. Crystal structure of (3R)-N-((2S,4R,5S)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl) tetrahydro-2H-pyran-4-yl)-3-hydroxydecanamide, C18H38N2O9
  52. Crystal structure of 4-((triphenylphosphonio)methyl)pyridin-1-ium octachlorodiantimonate, C24H22Cl8NPSb2
  53. Crystal structure of bis(2,3,5-triphenyl-2,3-dihydro-1H-tetrazol-1-ium) tetrabromidocadmate(II), C38H30Br4CdN8
  54. Crystal structure of 6–O,8–O-ditigloyl-6β,8α,11-trihydroxygermacra-1(10)E,4E-diene, C25H38O5
  55. Crystal structure of 4-ethyl-3-oxo-3,4-dihydro-6-carbonitrile, C11H9N3O
  56. Crystal structure of 1α,5α-dihydroxy-1-deoxo-13-deoxyenmein, C20H28O6
  57. Synthesis and crystal structure of (4a)-10-hydroxy-heptamethyl–N′-(4-fluorobenzylidene) octadecahydropicene-4a-carbohydrazide monohydrate, C37H53FN2O3
  58. Crystal structure of N-(3-chlorophenyl)-3-methyl-4-nitrobenzamide, C14H11ClN2O3
  59. Crystal structure of trichlorido-2-(4-pyridinium)bis(4-pyridyl)amine zinc(II), [Zn(C15H13N4)Cl3]
  60. Ethyl (E)- (4R,4aS,6aR,9S,11aR,11bS)-8-(propargyloxyimino)-4,9,11b-trimethyl-6a,9-methanocyclohepta[a]naphthalene-4-carboxylate, C25H37NO3
  61. The crystal structure of GaMn3B6O13(OH)
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