Startseite Crystal structure of tetramethyl-bis(μ2-2-(2-hydroxy-3-methoxybenzylidene)-1-(6-(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbonyl)picolinoyl)hydrazin-1-ido-κ4O,N,O′:O′)ditin(II) ─ ethanol (1/2), C54H62N10O14Sn2
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Crystal structure of tetramethyl-bis(μ2-2-(2-hydroxy-3-methoxybenzylidene)-1-(6-(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbonyl)picolinoyl)hydrazin-1-ido-κ4O,N,O′:O′)ditin(II) ─ ethanol (1/2), C54H62N10O14Sn2

  • Yan–Ling Qiao und Ji–Chun Cui ORCID logo EMAIL logo
Veröffentlicht/Copyright: 8. Januar 2025
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 240 Heft 2

Abstract

C54H62N10O14Sn2, triclinic, P1̄ (no. 2), a = 8.9238(14) Å, b = 10.6950(19) Å, c = 16.506(2) Å, α = 81.653(3)°, β = 75.444(2)°, γ = 70.354(2)°, V = 1432.8(4) Å3, Z = 1, Rgt(F) = 0.0309, wRref(F2) = 0.0824, T = 298(2) K.

CCDC no.: 2388162

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Orange block
Size: 0.25 × 0.23 × 0.20 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.94 mm−1
Diffractometer, scan mode: Bruker SMART-1000, φ and ω
θmax, completeness: 25.0°, 98 %
N(hkl)measured, N(hkl)unique, Rint: 7499, 4962, 0.015
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 4,270
N(param)refined: 361
Programs: Bruker, 1 SHELX, 2 , 3 Olex2 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Sn1 0.98421 (3) −0.06658 (2) 0.61595 (2) 0.03754 (9)
N1 0.8366 (4) −0.0739 (3) 0.95318 (17) 0.0425 (7)
N2 0.7774 (3) −0.0018 (3) 0.79732 (16) 0.0433 (7)
N3 0.7629 (3) 0.0286 (3) 0.71343 (16) 0.0394 (6)
N4 0.6198 (4) 0.0659 (3) 1.07658 (19) 0.0543 (8)
H4 0.604149 0.070235 1.026788 0.065*
N5 0.5174 (4) 0.1564 (3) 1.13210 (18) 0.0525 (8)
O1 1.0142 (3) −0.1618 (2) 0.74220 (14) 0.0490 (6)
O2 0.7629 (4) −0.0558 (3) 1.17305 (16) 0.0760 (9)
O3 0.8502 (3) 0.0971 (2) 0.53807 (13) 0.0403 (5)
O4 0.7484 (3) 0.2598 (2) 0.41272 (15) 0.0515 (6)
O5 0.4520 (3) 0.2935 (3) 1.26156 (16) 0.0592 (7)
H5 0.503371 0.233282 1.230169 0.089*
O6 0.2676 (4) 0.4965 (3) 1.34651 (18) 0.0698 (8)
O7 0.5548 (4) 0.1865 (3) 0.91001 (18) 0.0826 (10)
H7 0.623632 0.124410 0.884502 0.124*
C1 0.9122 (4) −0.0976 (3) 0.8031 (2) 0.0399 (8)
C2 0.9490 (4) −0.1343 (3) 0.8886 (2) 0.0408 (8)
C3 1.0961 (5) −0.2259 (4) 0.8980 (2) 0.0540 (9)
H3 1.171638 −0.266722 0.851887 0.065*
C4 1.1289 (5) −0.2559 (4) 0.9770 (3) 0.0624 (11)
H4A 1.227147 −0.317657 0.984957 0.075*
C5 1.0158 (5) −0.1942 (4) 1.0437 (2) 0.0577 (10)
H5A 1.036117 −0.212145 1.097486 0.069*
C6 0.8705 (5) −0.1044 (4) 1.0292 (2) 0.0466 (8)
C7 0.7471 (5) −0.0313 (4) 1.1008 (2) 0.0541 (10)
C8 0.6179 (4) 0.0918 (3) 0.7025 (2) 0.0423 (8)
H8 0.532996 0.100989 0.749589 0.051*
C9 0.5759 (4) 0.1493 (3) 0.6236 (2) 0.0398 (7)
C10 0.6908 (4) 0.1573 (3) 0.5483 (2) 0.0371 (7)
C11 0.6293 (4) 0.2415 (3) 0.4815 (2) 0.0406 (8)
C12 0.4658 (4) 0.3004 (4) 0.4854 (2) 0.0506 (9)
H12 0.429742 0.350824 0.439104 0.061*
C13 0.3543 (4) 0.2848 (4) 0.5584 (2) 0.0570 (10)
H13 0.243178 0.323092 0.560736 0.068*
C14 0.4076 (4) 0.2132 (4) 0.6268 (2) 0.0518 (9)
H14 0.332238 0.206256 0.676317 0.062*
C15 0.7030 (5) 0.3751 (4) 0.3568 (2) 0.0567 (10)
H15A 0.795072 0.376677 0.312028 0.085*
H15B 0.615579 0.371887 0.333975 0.085*
H15C 0.668115 0.453828 0.386962 0.085*
C16 0.3891 (5) 0.2386 (4) 1.1096 (2) 0.0548 (10)
H16 0.365977 0.229319 1.059358 0.066*
C17 0.2812 (4) 0.3445 (4) 1.1611 (2) 0.0492 (9)
C18 0.3180 (4) 0.3702 (4) 1.2336 (2) 0.0468 (8)
C19 0.2149 (5) 0.4792 (4) 1.2793 (2) 0.0511 (9)
C20 0.0738 (5) 0.5584 (4) 1.2562 (3) 0.0592 (10)
H20 0.004516 0.629705 1.287326 0.071*
C21 0.0357 (5) 0.5306 (4) 1.1857 (3) 0.0668 (12)
H21 −0.060916 0.583034 1.170448 0.080*
C22 0.1365 (5) 0.4285 (4) 1.1385 (3) 0.0622 (11)
H22 0.109462 0.413876 1.090599 0.075*
C23 0.1738 (6) 0.6035 (5) 1.3955 (4) 0.0973 (18)
H23A 0.225183 0.603293 1.440102 0.146*
H23B 0.164538 0.685236 1.361279 0.146*
H23C 0.067181 0.595481 1.418715 0.146*
C24 1.1413 (4) 0.0377 (4) 0.6240 (2) 0.0481 (8)
H24A 1.079300 0.117518 0.652332 0.072*
H24B 1.220844 −0.017169 0.654827 0.072*
H24C 1.195465 0.060355 0.568599 0.072*
C25 0.8907 (5) −0.2091 (4) 0.5902 (2) 0.0497 (9)
H25A 0.774801 −0.182342 0.611244 0.075*
H25B 0.914628 −0.216207 0.530703 0.075*
H25C 0.940007 −0.293731 0.616931 0.075*
C26 0.5705 (6) 0.3027 (5) 0.8707 (4) 0.0960 (16)
H26A 0.631902 0.286870 0.813625 0.115*
H26B 0.632939 0.334194 0.898873 0.115*
C27 0.4083 (7) 0.4115 (7) 0.8683 (6) 0.190 (4)
H27A 0.428522 0.490939 0.839631 0.285*
H27B 0.346743 0.382289 0.839246 0.285*
H27C 0.347782 0.429660 0.924580 0.285*

1 Source of material

The 2, 6-bis[(3-methoxysalicylidene)hydrazinocarbonyl]pyridine (0.463 g, 1 mmol) and sodium ethoxide (0.136 g, 2 mmol) were dissolved in 20 mL of ethanol and stirred for 30 min in a round flask. Following this, dimethyltin dichloride (0.219 g, 1 mmol) was added to the solution, and the reaction mixture was stirred at room temperature for 2 h. The mixture was then filtered, and the solvent from the filtrate was gradually evaporated under vacuum, leading to the formation of a solid product. The solid was recrystallized from ethanol, yielding orange crystals with a 49 % yield.

2 Experimental details

The structure was solved by Direct Methods with the SHELXS program. Hydrogen atoms were positioned geometrically (C–H = 0.93–0.98 Å). Their Uiso values were set to 1.2Ueq or 1.5Ueq of the parent atoms.

3 Comment

Bis-hydrazone compounds are a class of organic compounds featuring two hydrazone (=N–NH2) functional groups, widely applied in organic synthesis, pharmaceutical chemistry, and materials science. Due to their unique molecular structure, bis-hydrazone compounds demonstrate significant potential in metal coordination chemistry, catalytic reactions, and biological activity studies. 5 , 6 , 7 , 8 In this work, we synthesized an organotin bis-hydrazone compound using 2, 6-bis[(3-methoxysalicylidene) hydrazinocarbonyl]pyridine and dimethyltin dichloride. The title compound features a classic ladder-like structure with a ditin core containing two ligands. The central tin atom exhibits a seven-coordinate pentagonal bipyramidal geometry. The Sn1–O1 bond length of 2.221(2) Å and Sn1–O3 bond length of 2.204(2) Å indicate a strong coordination bond between the Sn atom and the O atoms. The Sn1–N3 bond length is 2.248(3) Å. The bond angle of C24–Sn1–C25 at 163.37(14)∘ suggests a deviation from an ideal pentagonal bipyramidal geometry. These data are closely aligned with those reported in the literature for similar compounds. 9 , 10 , 11 , 12 , 13

Corresponding author: Ji–Chun Cui, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P.R. China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was supported by Shandong Provincial Natural Science Foundation under Grant ZR2020MB019.

  3. Conflict of interest: The authors declare no conflicts of interest regarding this article.

References

1. BRUKER. SAINT, APEX2 and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2009.Suche in Google Scholar

2. Sheldrick, G. M. A Short History of SHELX. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Suche in Google Scholar PubMed

3. Sheldrick, G. M. Crystal Structure Refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

4. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: a Complete Structure Solution, Refinement and Analysis Program. J. Appl. Cryst. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Suche in Google Scholar

5. Zhang, L.; Duan, P.; Liu, Y.; Sun, J.; Zhao, D.; Du, C. Anion-directed Assembly of Lanthanide Coordination Polymers with SMMs Properties Based on a Dihydrazone Ligand. Z. Kristallogr. Cryst. Mater. 2018, 233, 2017–2076; https://doi.org/10.1515/zkri-2017-2076.Suche in Google Scholar

6. Wu, D.–Q.; Shao, D.; Wei, X.–Q.; Shen, F.–X.; Shi, L.; Zhang, Y.–Q.; Wang, X.–Y. Single-ion Magnetism in Seven-Coordinate YbIII Complexes with Distorted D5h Coordination Geometry. Dalton Trans. 2017, 46, 12884–12892; https://doi.org/10.1039/c7dt02461d.Suche in Google Scholar PubMed

7. Vadavi, R. S.; Shenoy, R. V.; Badiger, D. S.; Gudasi, K. B.; Devi, L. G.; Nethaji, M. Crystal Structure of Nonadentate Tricompartmental Ligand Derived from Pyridine-2,6-Dicarboxylic Acid: Spectroscopic, Electrochemical and Thermal Investigations of its Transition Metal(II) Complexes. Spectrochim. Acta, Part A 2011, 79, 348–355; https://doi.org/10.1016/j.saa.2011.03.011.Suche in Google Scholar PubMed

8. Li, Z.–F.; Wang, P.; Zhang, Q.; Chen, Z.–M.; Wang, C.–X. 2,6–Bis[(2-hydroxy-3-methoxybenzylidene)hydrazinocarbonyl]Pyridine Monohydrate. Acta Crystallogr. 2007, c63, o369–o370; https://doi.org/10.1107/s0108270107021920.Suche in Google Scholar PubMed

9. Bondi, A. van der Waals Volumes and Radii. J. Phys. Chem. 1964, 68, 441–451; https://doi.org/10.1021/j100785a001.Suche in Google Scholar

10. Tan, Y.; Zhang, Z.; Tan, Y.; Kuang, D.; Yu, J.; Zhu, X.; Jiang, W. Syntheses Crystal Structures and Biological Activity of the Dialkytin Complexes Based on 2-Oxo-3-Phenylpropionic Acid Salicyloylhydrazone. J. Coord. Chem. 2017, 70, 2606–2624; https://doi.org/10.1080/00958972.2017.1355460.Suche in Google Scholar

11. Wang, F.; Yin, H.; Cui, J.; Zhang, Y.; Geng, H.; Hong, M. Synthesis, Structural Characterization, In Vitro Cytotoxicities, DNA-Binding and BSA Interaction of Diorganotin (IV) Complexes Derived from Hydrazone Schiff Base. Organometallics 2014, 759, 83–91; https://doi.org/10.1016/j.jorganchem.2013.12.037.Suche in Google Scholar

12. Lee, S. M.; Sim, K. S.; Lo, K. M. Synthesis, Characterization and Biological Studies of Diorganotin(IV) Complexes with Tris[(Hydroxymethyl)Aminomethane] Schiff Bases. Inorg. Chim. Acta 2015, 429, 195–208; https://doi.org/10.1016/j.ica.2015.01.017.Suche in Google Scholar

13. Hussain, N.; Bhardwaj, V. K. The Influence of Different Coordination Environments on One-Dimensional Cu(II) Coordination Polymers for the Photo-Degradation of Organic Dyes. Dalton Trans. 2016, 45, 7697–7707; https://doi.org/10.1039/c6dt00612d.Suche in Google Scholar PubMed

Received: 2024-10-01
Accepted: 2024-11-29
Published Online: 2025-01-08
Published in Print: 2025-04-28

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of N-(3-bromo-4-fluorophenyl)-N′-hydroxy-4-{[2-(4-methylphenyl)ethyl]amino}-1,2,5-oxadiazole-3-carboximidamide, C18H17BrFN5O2
  4. Synthesis and crystal structure of ethyl (2S,4aS,6aS,6bR,8aR,12aS,12bR,14bR,E)-10-(((3,4-dichlorobenzyl)oxy)imino)-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydropicene-2-carboxylate
  5. The crystal structure of pyrazole nitrate
  6. Crystal structure of tetramethyl-bis(μ2-2-(2-hydroxy-3-methoxybenzylidene)-1-(6-(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbonyl)picolinoyl)hydrazin-1-ido-κ4O,N,O′:O′)ditin(II) ─ ethanol (1/2), C54H62N10O14Sn2
  7. Crystal structure of catena-poly[μ3-iodido-(4-bromopyridine-κ1N)copper(I)], C5H4BrNCuI
  8. The crystal structure of cyclopentadienyl Co–P–C complexes by benzylideneacetone addition, C38H38CoO2P
  9. Synthesis and crystal structure of-(3S,10S,13S,17S)-N-(2-methoxyphenyl)-10,13-dimethyl-17-((R)-1-(phenylamino)ethyl)hexadecahydro-1H-cyclopenta[α]phenanthren-3-amine, C34H48N2O
  10. The crystal structure of (E)-3-((E)-3-(4-ethoxy-3-methoxyphenyl)-1-hydroxyallylidene) chroman-2,4-dione, C21H18O6
  11. The crystal structure of trans–L/D-[bis-(2-methyl-8-hydroxyquinoline-κ2 N,O) bis-(1,3,5-triaza-7-phosphaadamantane-κ2 P)cobalt(III)] tetrafluoroborate
  12. Crystal structure of 9-chloro-2,3,4,4a,5,6-hexahydro-1H-pyrido [1′,2′:1,6]pyrazino[2,3-b]quinoxaline, C14H15ClN4
  13. Crystal structure of 7-(diethylamino)-3-(benzoyl)-2 H -chromen-2-one, C20H19NO3
  14. The crystal structure of 4–bromo-3,5-dinitropyrazole
  15. Crystal structure of 8-hydroxy-3,5,8a-trimethyl-7,8,8a,9-tetrahydronaphtho[2,3-b]furan-4,6-dione, C15H16O4
  16. Crystal structure of 5-hydroxy-3,5,8a-trimethyl-4a,5,6,7,8a,9-hexahydronaphtho[2,3-b]furan-4,8-dione, C15H18O4
  17. Synthesis and crystal structure of-(3S,10S,13S,17S)-N-(2-methoxyphenyl)-10,13-dimethyl-17-((R)-1-(p-tolylamino)ethyl)hexadecahydro-1H-cyclopenta[α]phenanthren-3-amine, C35H50N2O
  18. The crystal structure of catena-poly((μ2-1,3,5-tri(1H- imidazol-1-yl)benzene κ2N:N′)-bis(4-hydroxbenzoato-κ1O)-zinc(II) monohydrate), C29H24N6O7Zn
  19. Crystal structure of 2-(benzo[d]oxazol-2-yl)acetonitrile, C9H6N2O
  20. Crystal structure of 1,3-dihydroxy-6,8-dimethoxy-2-(6-methyltetrahydro-2Hpyran-2-yl)-4a,9a-dihydroanthracene-9,10-dione, C22H22O7
  21. The crystal structure of the double salt potassium 1-methylpiperazine-1,4-di-ium trinitrate, C5H14KN5O9
  22. Crystal structure of 5′-hydroxy-6′-methoxy-1′-methyl-2′,3′,8′,8a′-tetrahydro-1′H-spiro[cyclohexane-1,7′-cyclopenta[ij]isoquinoline]-2,5-dien-4-one, C18H19NO3
  23. The crystal structure of 1,1′-(2,3,5,6-tetramethylpyrazine-1,4-diyl)bis(ethan-1-one), C12H18N2O2
  24. Crystal structure of [μ2-piperazine-1,4-bis(2-hydroxypropanesulfonato-κ2O:O′)] bis(μ2-4,4′-trimethylenedipyridyl-κ2N:N′)disilver(I), C18H24AgN3O4S
  25. Crystal structure of bis ((1-((E)-((4-methoxyphenyl)imino)methyl)naphthalen-2-yl)oxy) copper(II), C36H28CuN2O4
  26. Synthesis and crystal structure of 6,6′-((1E,11E)-5,8-dioxa-2,11-diazadodeca-1,11-diene-1,12-diyl) bis(2,4-di-tert-butylphenol), C36H56N2O4
  27. The crystal structure of barium hexahydroxidoiridate(IV) dihydroxide, Ba2[Ir(OH)6](OH)2
  28. Crystal structure of cinnamoyl ferrocene, C19H16FeO
  29. Crystal structure of (E)-3-(4-butoxyphenyl)acryloylferrocene, C23H24FeO2
  30. Crystal structure of 7-(dimethylamino)-2-hydroxy-2-(trifluoromethyl)-2H-chromene-3-ethyl carboxylate, C15H16F3NO4
  31. The crystal structure of 1-phenylethan-1-aminium 4-hydroxy-3,5-dimethoxybenzoate C17H21NO5
  32. The crystal structure of 1,3,5-trichloro-2-nitrobenzene
  33. The crystal structure of tris(μ2-bromido)-bis(η6-p-cymene)-diosmium(II) tetrafluoroborate, C20H28BBr3F4Os2
  34. Crystal structure of new barium lithium manganese fluorides: Ba14Li1.87Mn14.13F68 with a Jarlite–related structure
  35. Crystal structure of (4-fluorobenzyl)triphenylphosphonium chloride, C25H21ClFP
  36. The crystal structure of calcitriol–chloroform (1/1), C27H44O3⋅CHCl3
  37. The crystal structure of (E)-1-((3)-nitrophenyl)pyren-3-(pyren-1-yl)prop-2-en-1-one, C25H15NO3
  38. Crystal structure of (E)-2-hydroxy-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H16N2O3
  39. Crystal structure of (E)-(3-(thiophen-2-yl)acryloyl)ferrocene, C17H14FeOS
  40. Crystal structure of (E)-(3-(furan-2-yl)acryloyl)ferrocene, C17H14FeO2
  41. Synthesis and crystal structure poly[diaqua(μ3-3-(((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl) methyl)ammonio)propanoate-κ3 O:O′:O″) sodium(I)] monohydrate, C20H24NNaO12S
  42. Crystal structure of 9-methoxy-4-(2-methoxypyridin-3-yl)-5,6-dihydrobenzo[h]quinazolin-2-amine C19H18N4O2
  43. Synthesis and crystal structure of 4-(difluoromethyl)-1-methyl-N-(pyridin-3-yl)-1H-pyrazole-3-carboxamide hydrate, C11H12F2N4O2
  44. The crystal structure of caesalfurfuric acid B, C22H32O4
  45. The crystal structure of 2-bromo-2-(5-bromo-2-methyl-4-nitro-1H-imidazol-1-yl)-1-phenylethanone, C12H9Br2N3O3
  46. The crystal structure of bis{chlorido-[μ2-(1-oxidopyridin-2-yl)(pyridin-2-yl)amido-κ3 O,N, N′]copper(II)}, C20H16Cl2Cu2N6O2
  47. The crystal structure of 3-amino-2-formyl-1-phenyl-9,10-dihydrophenanthrene-4-carbonitrile, C22H16N2O
  48. The crystal structure of 1,1′-(2,5-dimethylpyrazine-1,4-diyl)bis(ethan-1-one), C10H14N2O2
  49. Crystal structure of 5′-(9-phenyl-9H-carbazol-3-yl)-[2,2′-bithiophene]-5-carbaldehyde, C27H17NOS2
  50. The crystal structure of the double salt dipyridin-1-ium bromide tribromide
  51. Crystal structure of (E)-(3-(3-methylthiophen-2-yl)acryloyl)ferrocene, C18H16FeOS
  52. Crystal structure of (E)-(3-(4-phenoxyphenyl)acryloyl)ferrocene, C25H20FeO2
  53. Crystal structure of (E)-(3-(3,4-dimethylphenyl)acryloyl)ferrocene, C21H20FeO
  54. Crystal structure of [(1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N‴)tetracyanidodiplatinum(II)] dimethyl sulfoxide solvate, C18H36N8O2Pt2S2
  55. Crystal structure of (4-ethoxybenzyl)triphenylphosphonium bromide ethanol solvate, C29H32BrO2P
  56. Crystal structure of (1-naphthalen-1-yl-methyl)triphenylphosphonium chloride ethanol solvate, C31H30ClOP
  57. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)platinum(II) bis[tribromido(dimethyl sulfoxide-κS)platinate(II)], C14H36Br6N4O2Pt3S2
  58. Crystal structure of (2-methylbenzyl)triphenylphosphonium chloride ethanol solvate, C28H30ClOP
  59. Crystal structure of bis(η2, σ1-8-methoxycyclooct-4-enyl)(μ2-1,4,8,11-tetraazacyclotetradecane-κ4 N, N′, N″, N‴)diplatinum(II) dibromide, C28H54Br2N4O2Pt2
  60. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) tetrabromidopalladate(II), C10H24Br4N4Pd2
  61. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) bis[trichlorido(dimethyl sulfoxide-κS)platinate(II)], C14H36Cl6N4O2PdPt2S2
  62. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) tetraiodidopalladate(II), C10H24I4N4Pd2
https://doi.org/10.1515/ncrs-2024-0386
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of N-(3-bromo-4-fluorophenyl)-N′-hydroxy-4-{[2-(4-methylphenyl)ethyl]amino}-1,2,5-oxadiazole-3-carboximidamide, C18H17BrFN5O2
  4. Synthesis and crystal structure of ethyl (2S,4aS,6aS,6bR,8aR,12aS,12bR,14bR,E)-10-(((3,4-dichlorobenzyl)oxy)imino)-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydropicene-2-carboxylate
  5. The crystal structure of pyrazole nitrate
  6. Crystal structure of tetramethyl-bis(μ2-2-(2-hydroxy-3-methoxybenzylidene)-1-(6-(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbonyl)picolinoyl)hydrazin-1-ido-κ4O,N,O′:O′)ditin(II) ─ ethanol (1/2), C54H62N10O14Sn2
  7. Crystal structure of catena-poly[μ3-iodido-(4-bromopyridine-κ1N)copper(I)], C5H4BrNCuI
  8. The crystal structure of cyclopentadienyl Co–P–C complexes by benzylideneacetone addition, C38H38CoO2P
  9. Synthesis and crystal structure of-(3S,10S,13S,17S)-N-(2-methoxyphenyl)-10,13-dimethyl-17-((R)-1-(phenylamino)ethyl)hexadecahydro-1H-cyclopenta[α]phenanthren-3-amine, C34H48N2O
  10. The crystal structure of (E)-3-((E)-3-(4-ethoxy-3-methoxyphenyl)-1-hydroxyallylidene) chroman-2,4-dione, C21H18O6
  11. The crystal structure of trans–L/D-[bis-(2-methyl-8-hydroxyquinoline-κ2 N,O) bis-(1,3,5-triaza-7-phosphaadamantane-κ2 P)cobalt(III)] tetrafluoroborate
  12. Crystal structure of 9-chloro-2,3,4,4a,5,6-hexahydro-1H-pyrido [1′,2′:1,6]pyrazino[2,3-b]quinoxaline, C14H15ClN4
  13. Crystal structure of 7-(diethylamino)-3-(benzoyl)-2 H -chromen-2-one, C20H19NO3
  14. The crystal structure of 4–bromo-3,5-dinitropyrazole
  15. Crystal structure of 8-hydroxy-3,5,8a-trimethyl-7,8,8a,9-tetrahydronaphtho[2,3-b]furan-4,6-dione, C15H16O4
  16. Crystal structure of 5-hydroxy-3,5,8a-trimethyl-4a,5,6,7,8a,9-hexahydronaphtho[2,3-b]furan-4,8-dione, C15H18O4
  17. Synthesis and crystal structure of-(3S,10S,13S,17S)-N-(2-methoxyphenyl)-10,13-dimethyl-17-((R)-1-(p-tolylamino)ethyl)hexadecahydro-1H-cyclopenta[α]phenanthren-3-amine, C35H50N2O
  18. The crystal structure of catena-poly((μ2-1,3,5-tri(1H- imidazol-1-yl)benzene κ2N:N′)-bis(4-hydroxbenzoato-κ1O)-zinc(II) monohydrate), C29H24N6O7Zn
  19. Crystal structure of 2-(benzo[d]oxazol-2-yl)acetonitrile, C9H6N2O
  20. Crystal structure of 1,3-dihydroxy-6,8-dimethoxy-2-(6-methyltetrahydro-2Hpyran-2-yl)-4a,9a-dihydroanthracene-9,10-dione, C22H22O7
  21. The crystal structure of the double salt potassium 1-methylpiperazine-1,4-di-ium trinitrate, C5H14KN5O9
  22. Crystal structure of 5′-hydroxy-6′-methoxy-1′-methyl-2′,3′,8′,8a′-tetrahydro-1′H-spiro[cyclohexane-1,7′-cyclopenta[ij]isoquinoline]-2,5-dien-4-one, C18H19NO3
  23. The crystal structure of 1,1′-(2,3,5,6-tetramethylpyrazine-1,4-diyl)bis(ethan-1-one), C12H18N2O2
  24. Crystal structure of [μ2-piperazine-1,4-bis(2-hydroxypropanesulfonato-κ2O:O′)] bis(μ2-4,4′-trimethylenedipyridyl-κ2N:N′)disilver(I), C18H24AgN3O4S
  25. Crystal structure of bis ((1-((E)-((4-methoxyphenyl)imino)methyl)naphthalen-2-yl)oxy) copper(II), C36H28CuN2O4
  26. Synthesis and crystal structure of 6,6′-((1E,11E)-5,8-dioxa-2,11-diazadodeca-1,11-diene-1,12-diyl) bis(2,4-di-tert-butylphenol), C36H56N2O4
  27. The crystal structure of barium hexahydroxidoiridate(IV) dihydroxide, Ba2[Ir(OH)6](OH)2
  28. Crystal structure of cinnamoyl ferrocene, C19H16FeO
  29. Crystal structure of (E)-3-(4-butoxyphenyl)acryloylferrocene, C23H24FeO2
  30. Crystal structure of 7-(dimethylamino)-2-hydroxy-2-(trifluoromethyl)-2H-chromene-3-ethyl carboxylate, C15H16F3NO4
  31. The crystal structure of 1-phenylethan-1-aminium 4-hydroxy-3,5-dimethoxybenzoate C17H21NO5
  32. The crystal structure of 1,3,5-trichloro-2-nitrobenzene
  33. The crystal structure of tris(μ2-bromido)-bis(η6-p-cymene)-diosmium(II) tetrafluoroborate, C20H28BBr3F4Os2
  34. Crystal structure of new barium lithium manganese fluorides: Ba14Li1.87Mn14.13F68 with a Jarlite–related structure
  35. Crystal structure of (4-fluorobenzyl)triphenylphosphonium chloride, C25H21ClFP
  36. The crystal structure of calcitriol–chloroform (1/1), C27H44O3⋅CHCl3
  37. The crystal structure of (E)-1-((3)-nitrophenyl)pyren-3-(pyren-1-yl)prop-2-en-1-one, C25H15NO3
  38. Crystal structure of (E)-2-hydroxy-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H16N2O3
  39. Crystal structure of (E)-(3-(thiophen-2-yl)acryloyl)ferrocene, C17H14FeOS
  40. Crystal structure of (E)-(3-(furan-2-yl)acryloyl)ferrocene, C17H14FeO2
  41. Synthesis and crystal structure poly[diaqua(μ3-3-(((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl) methyl)ammonio)propanoate-κ3 O:O′:O″) sodium(I)] monohydrate, C20H24NNaO12S
  42. Crystal structure of 9-methoxy-4-(2-methoxypyridin-3-yl)-5,6-dihydrobenzo[h]quinazolin-2-amine C19H18N4O2
  43. Synthesis and crystal structure of 4-(difluoromethyl)-1-methyl-N-(pyridin-3-yl)-1H-pyrazole-3-carboxamide hydrate, C11H12F2N4O2
  44. The crystal structure of caesalfurfuric acid B, C22H32O4
  45. The crystal structure of 2-bromo-2-(5-bromo-2-methyl-4-nitro-1H-imidazol-1-yl)-1-phenylethanone, C12H9Br2N3O3
  46. The crystal structure of bis{chlorido-[μ2-(1-oxidopyridin-2-yl)(pyridin-2-yl)amido-κ3 O,N, N′]copper(II)}, C20H16Cl2Cu2N6O2
  47. The crystal structure of 3-amino-2-formyl-1-phenyl-9,10-dihydrophenanthrene-4-carbonitrile, C22H16N2O
  48. The crystal structure of 1,1′-(2,5-dimethylpyrazine-1,4-diyl)bis(ethan-1-one), C10H14N2O2
  49. Crystal structure of 5′-(9-phenyl-9H-carbazol-3-yl)-[2,2′-bithiophene]-5-carbaldehyde, C27H17NOS2
  50. The crystal structure of the double salt dipyridin-1-ium bromide tribromide
  51. Crystal structure of (E)-(3-(3-methylthiophen-2-yl)acryloyl)ferrocene, C18H16FeOS
  52. Crystal structure of (E)-(3-(4-phenoxyphenyl)acryloyl)ferrocene, C25H20FeO2
  53. Crystal structure of (E)-(3-(3,4-dimethylphenyl)acryloyl)ferrocene, C21H20FeO
  54. Crystal structure of [(1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N‴)tetracyanidodiplatinum(II)] dimethyl sulfoxide solvate, C18H36N8O2Pt2S2
  55. Crystal structure of (4-ethoxybenzyl)triphenylphosphonium bromide ethanol solvate, C29H32BrO2P
  56. Crystal structure of (1-naphthalen-1-yl-methyl)triphenylphosphonium chloride ethanol solvate, C31H30ClOP
  57. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)platinum(II) bis[tribromido(dimethyl sulfoxide-κS)platinate(II)], C14H36Br6N4O2Pt3S2
  58. Crystal structure of (2-methylbenzyl)triphenylphosphonium chloride ethanol solvate, C28H30ClOP
  59. Crystal structure of bis(η2, σ1-8-methoxycyclooct-4-enyl)(μ2-1,4,8,11-tetraazacyclotetradecane-κ4 N, N′, N″, N‴)diplatinum(II) dibromide, C28H54Br2N4O2Pt2
  60. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) tetrabromidopalladate(II), C10H24Br4N4Pd2
  61. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) bis[trichlorido(dimethyl sulfoxide-κS)platinate(II)], C14H36Cl6N4O2PdPt2S2
  62. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)palladium(II) tetraiodidopalladate(II), C10H24I4N4Pd2
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Heruntergeladen am 16.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0386/html
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