Startseite Effect of Aspect Ratio of Whisker on the Fibrillation of Liquid Crystalline Polymer in Polysulfone Matrix
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Effect of Aspect Ratio of Whisker on the Fibrillation of Liquid Crystalline Polymer in Polysulfone Matrix

  • J. Chen , P. Chen , L. Wu , J. Zhang und J. He
Veröffentlicht/Copyright: 28. Februar 2022
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Abstract

The influence of content and aspect ratio of whiskers, calcium carbonate and aluminum borate, on the morphology evolution of liquid crystalline polymer (LCP) was investigated in polysulfone (PSF) matrix. The study showed that the deformation of LCP droplets was significantly promoted by adding whiskers into PSF/LCP blends, and the longer whisker produced a more pronounced fibrillation effect. The analysis of flow field and elasticity of system showed that the addition of longer whiskers increased the elasticity of materials more efficiently and enhanced the vortex in the converging flow area at the entry of capillary, which resulted in an increase of the elongational stress and promoted the formation of longer LCP fibrils in PSF/whisker system.


* Mail address: J. He, Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Engineering Plastics, Joint Laboratory of Polymer Science and Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China


Acknowledgements

This work was supported by the National Nature Science Foundation of China, Grant No. 50233010

References

1 Kiss, G.: Polym. Eng. Sci. 27, p. 410 (1987)10.1002/pen.760270606Suche in Google Scholar

2 Qin, Y. M.: Polym. Adv. Technol. 7, p. 151 (1996)10.1002/(SICI)1099-1581(199603)7:3<151::AID-PAT495>3.0.CO;2-OSuche in Google Scholar

3 Tjong, S. C.: Mater. Sci. Eng. 41, p. 1 (2003)10.1016/S0927-796X(03)00035-4Suche in Google Scholar

4 He, J., Zhang, H., Wang, Y.: Polymer 38, p. 4279 (1997)10.1016/S0032-3861(97)00113-4Suche in Google Scholar

5 He, J., Wang, Y., Zhang, H.: Compos. Sci. Technol. 60, p. 1919 (2000)10.1016/S0266-3538(00)00079-8Suche in Google Scholar

6 Tan, L. P., Yue, C. Y., Tam, K. C., Lam, Y. C., Hu, X., Nakayama, K.: J. Polym. Sci. Part B: Polym. Phys. 41, p. 2307 (2003)10.1002/polb.10522Suche in Google Scholar

7 Saikrasun, S., Bualek-Limcharoen, S., Kohjiya, S., Urayama, K.: J. Polym. Sci. Part B: Polym. Phys. 43, p. 135 (2005)10.1002/polb.20315Suche in Google Scholar

8 Chang, J.-H., Seo, B.-S., Kim, S. H.: J. Polym. Sci. Part B: Polym. Phys. 42, p. 3667 (2004)10.1002/polb.20232Suche in Google Scholar

9 Zhang, B., Ding, Y., Chen, P., Liu, C., Zhang, J., He, J., Hu, G. H.: Polymer 46, p. 5385 (2005)10.1016/j.polymer.2005.03.093Suche in Google Scholar

10 Wu, L., Chen, P., Zhang, J., He, J.: Polymer 47, p. 448 (2006)10.1016/j.polymer.2005.11.044Suche in Google Scholar

11 Chen, P., Wu, L., Ding, Y., Zhang, J., He, J.: Compos. Sci. Technol. 66, p. 1564 (2006)10.1016/j.compscitech.2005.11.019Suche in Google Scholar

12 Chen, P., Chen, J., Zhang, B., Zhang, J., He, J.: J. Polym. Sci. Part B: Polym. Phys. 44, p. 1020 (2006)10.1002/polb.20755Suche in Google Scholar

13 Chen, P., Zhang, J., He, J.: Polymer 46, p. 7652 (2005)10.1016/j.polymer.2005.05.123Suche in Google Scholar

14 Ding, Y., Zhang, J., Chen, P., Zhang, B., Yi, Z., He, J.: Polymer 45, p. 8051 (2004)10.1016/j.polymer.2004.09.035Suche in Google Scholar

15 Chen, J., Chen, P., Wu, L., Zhang, J., He, J.: Polymer 47, p. 5402 (2006)10.1016/j.polymer.2006.05.044Suche in Google Scholar

16 Zheng, X., Zhang, B., Zhang, J., Xue, Y., He, J.: Int. Polym. Process. 18, p. 3 (2003)10.3139/217.1716Suche in Google Scholar

17 Zheng, X., Zhang, J., He, J.: J. Polym. Sci. Part B: Polym. Phys. 42, p. 1619 (2004)10.1002/polb.20034Suche in Google Scholar

18 Xu, H.-S., Li, Z.-M., Pan, J.-L., Yang, M.-B., Huang, R.: Macromol. Mater. Eng. 289, p. 1087 (2004)10.1002/mame.200400197Suche in Google Scholar

19 Tol, R. T., Groeninckx, G., Vinckier, I., Moldenaers, P., Mewis, J.: Polymer 45, p. 2587 (2004)10.1016/j.polymer.2003.12.072Suche in Google Scholar

20 Saengsuwan, S., Bualek-Limcharoen, S., Mitchell, G. R., Olley, R. H.: Polymer 44, p. 3407 (2003)10.1016/S0032-3861(03)00244-1Suche in Google Scholar

21 Wang, H., Tao, X., Newton, E., Chung, T. S.: Polym. J. 34, p. 575 (2002)10.1295/polymj.34.575Suche in Google Scholar

22 He, J., Bu, W., Zhang, H.: Polym. Eng. Sci. 35, p. 1695 (1995)10.1002/pen.760352106Suche in Google Scholar

23 Sukhadia, A. M., Done, D., Baird, D. G.: Polym. Eng. Sci. 30, p. 519 (1990)10.1002/pen.760300904Suche in Google Scholar

24 Berry, D., Kenig, S., Siegmann, A.: Polym. Eng. Sci. 31, p. 451 (1991)10.1002/pen.760310612Suche in Google Scholar

25 Berry, D., Kenig, S., Siegmann, A.: Polym, Eng. Sci. 31, p. 459 (1991)10.1002/pen.760310613Suche in Google Scholar

26 Lee, M. W., Hu, X., Yue, C .Y., Li, L., Tam, K. C., Nakayama, K.: J. Appl. Polym. Sci. 86, p. 2070 (2002)10.1002/app.11157Suche in Google Scholar

27 Jansen, K. M. B., Agterof, W. G. M., Mellema, J.: J. Rheol. 45, p. 227 (2001)10.1122/1.1333001Suche in Google Scholar

28 He, J., Bu, W.: Polymer 35, p. 5061 (1994)10.1016/0032-3861(94)90665-3Suche in Google Scholar

29 Cogswell, F. N.: Polym. Eng. Sci. 12, p. 64 (1972)10.1002/pen.760120111Suche in Google Scholar

30 Binding, D. M.: J. Non-Newtonian Fluid Mech. 27, p. 173 (1988)10.1016/0377-0257(88)85012-2Suche in Google Scholar

31 White, S. A., Baird, D. G.: J. Non-Newtonian Fluid Mech. 20, p. 93 (1986)10.1016/0377-0257(86)80016-7Suche in Google Scholar

32 White, J. L., Kondo, A.: J. Non-Newtonian Fluid Mech. 3, p. 41 (1977/1978)10.1016/0377-0257(77)80011-6Suche in Google Scholar

33 Boger, D. V.: Ann. Rev. Fluid Mech. 19, p. 157 (1987)10.1146/annurev.fl.19.010187.001105Suche in Google Scholar

34 White, J. L.: Appl. Polym. Sympo. 20, p. 155 (1973)10.1070/SM1973v020n01ABEH002937Suche in Google Scholar

35 Azaiez, J., Guenette, R., Ait-Kadi, A.: J. Non-Newtonian Fluid Mech. 73, p. 289 (1997)10.1016/S0377-0257(97)00047-5Suche in Google Scholar

36 Bulters, M. J. H., Meijer, H. E. H..: J. Non-Newtonian Fluid Mech. 38, p. 43 (1990)10.1016/0377-0257(90)85032-TSuche in Google Scholar

37 White, S. A., Gotsis, A. D., Baird, D. G.: J. Non-Newtonian Fluid Mech. 24, p. 121 (1987)10.1016/0377-0257(87)85007-3Suche in Google Scholar

38 Debbaut, B., Crochet, M. J.: J. Non-Newtonian Fluid Mech. 30, p. 169 (1988)10.1016/0377-0257(88)85023-7Suche in Google Scholar

Received: 2006-07-04
Accepted: 2006-10-06
Published Online: 2022-02-28
Published in Print: 2022-02-28

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