Startseite The Effect of TiO2 Contained within a Titanium Silicalite (TS-1) Catalyst and on the Selective Oxidation of Ammonia
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The Effect of TiO2 Contained within a Titanium Silicalite (TS-1) Catalyst and on the Selective Oxidation of Ammonia

  • Celal Utku Deniz , Solmaz Akmaz und Muzaffer Yasar EMAIL logo
Veröffentlicht/Copyright: 28. September 2013
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International Journal of Chemical Reactor Engineering
Aus der Zeitschrift International Journal of Chemical Reactor Engineering Band 11 Heft 1

Abstract

The selective oxidation of ammonia to hydroxylamine using titanium silicalite-1 as a catalyst with an increasing content range of 1–2.5 wt% TiO2 was systematically investigated in a batch reactor. The hydroxylamine yielded 33, 43, 52 and 62% at reaction temperatures of 50, 60, 70 and 80°C, respectively, for 8 min using a TS-1a catalyst, which contained 2.5% TiO2. The molar ratio of 15 NH3/H2O2 was kept during these reactions. Experiments were also conducted with different amounts of NH3/H2O2 in molar ratios, which were between 7 and 60 to investigate the effect of NH3/H2O2 molar ratio on the reactions. Reactions with higher ratios of NH3/H2O2 were seen to have a higher yield at the end of the reaction performance time.

Keywords: selective oxidation; ammonia; gas chromatography; hydroxylamine; TS-1 catalyst

Acknowledgment

This work was supported by Scientific Research Projects Coordination Unit of Istanbul University, Project Number 3314 and UDP-25184.

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Published Online: 2013-09-28

©2013 by Walter de Gruyter Berlin / Boston

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https://doi.org/10.1515/ijcre-2013-0086
Schlagwörter für diesen Artikel
selective oxidation; ammonia; gas chromatography; hydroxylamine; TS-1 catalyst

Artikel in diesem Heft

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  2. Masthead
  4. Efficient Synthesis of 1-Acetylpyrene Using [Bmim]Cl–FeCl3 Ionic Liquid as Dual Catalyst and Solvent
  5. Ethanol Steam Reforming for Hydrogen Production in Microchannel Reactors: Experimental Design and Optimization
  6. Modeling NOx Adsorption onto Fe/ZSM-5 Catalysts in a Fixed Bed Reactor
  7. Multistep Optimization and Residue Disposal Study for Electrochemical Treatment of Textile Wastewater Using Aluminum Electrode
  8. Effect of Vibrating Sparger on Mass Transfer, Gas Holdup, and Bubble Size in a Bubble Column Reactor
  9. Production of Silicon from SiH4 in a Fluidized Bed, Operation and Results
  10. Reforming of Glycerol into Bio-Crude: A Parametric Study
  11. Hydrodynamic and Mass Transfer Characteristics in a Large-Scale Slurry Bubble Column Reactor for Gas Mixtures in Actual Fischer–Tropsch Cuts
  12. Optimization of l-Asparaginase Production by Isolated Aspergillus niger C4 from Sesame (black) Oil Cake under SSF using Box–Behnken Design in Column Bioreactor
  13. Simplified Kinetic Model for Thermal Combustion of Lean Methane–Air Mixtures in a Wide Range of Temperatures
  14. Identification and Optimization of Recombinant E. coli Fed-Batch Fermentation Producing γ-Interferon Protein
  15. A Comparison of Monomeric Phenols Produced from Lignin by Fast Pyrolysis and Hydrothermal Conversions
  16. Design and Optimization of a Fixed Bed Reactor for Direct Dimethyl Ether Production from Syngas Using Differential Evolution Algorithm
  17. Conversion Enhancement of Fixed-Bed Reactors Using Two-Dimensional Hollow Cylindrical Catalyst Pellet
  18. Bubble Columns with Internals: A Review
  19. A Historic Review on R&D of China’s FCC Riser Termination Device Technologies
  20. Recent Advances of Spout-Fluid Bed: A Review of Fundamentals and Applications
  21. Ethanol Catalytic Oxidation on Ordered Mesoporous CuO/KIT-6 Catalyst
  22. A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor
  23. Implementation of Homotopy Perturbation Method to Solve a Population Balance Model in Fluidized Bed
  24. Experimental Research on Utilization of Steel Rolling Sludge in Sintering Process
  25. Application of Honey-Bee Mating Optimization to Naphtha Reforming Reactor
  26. Modeling and Simulation of a Fischer–Tropsch Slurry Bubble Column Reactor Using Different Kinetic Rate Expressions for Iron and Cobalt Catalysts
  27. Solids Suspension Study in a Side-Entering Stirred Tank Through CFD Modeling
  28. Triphase Catalysis Using Silica Gel as Support
  29. Enhanced Trichloroethylene CatalyticOxidation on Modified Lanthanum Manganite ano-Perovskites
  30. A Novel Reactor for Microwave Hydrothermal Scale-up Nanopowder Synthesis
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  37. Applications of Feed-Forward Neural Network to Study Irregular-Shape Particle Effects on Hydrodynamics Behavior in a Liquid–Solid Circulating Fluidized Bed Riser
  38. Experimental Investigation on the Translational and Rotational Motion of Biomass Particle in a Spout-Fluid Bed
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  40. Study of Co-pyrolysis Characteristics of Lignite and Rice Husk in a TGA and a Fixed-Bed Reactor
  41. Exergy Analysis of Oxidative Steam Reforming of Methanol for Hydrogen Producton: Modeling Study
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