Abstract
Fluid catalytic cracking (FCC) is a dominant refining conversion process in China’s most refineries. After decades of development, China has already become one of the major FCC technology licensors in the world. In this review, the research and development (R&D) activities on FCC riser termination device (RTD) technologies in China are reviewed and discussed. Emphasis is put on the R&D of a series of advanced RTD technologies led by China University of Petroleum, Beijing, which initiated in the early 1990s when more and more China’s FCC units chose to process more residue feedstock. Followed by the guideline of three “quick”s and two “high”s, two early types of RTD systems with coupled zones for gas–solids centrifugal separation and pre-stripping were developed and applied successfully in commercial units. Significantly reduced yields of coke and dry gas due to restrained post-riser reactions and satisfactory particle recovery efficiency were achieved. These were the fender-stripper cyclone and vortex quick separator systems designed for external- and internal-riser FCC units, respectively. Later, further improvement efforts led to the development of another two RTD systems, i.e. the circulating-stripper cyclone system for external-riser units and super vortex quick separator system for internal-riser units. By now, nearly 50 applications were commissioned with a sum FCC capacity of 40.0 Mton/a, nearly one-third of China’s total FCC processing capacity. Besides, other research efforts, such as the geometry optimization efforts on LD2 type separator, the studies on RTD for down-flow riser FCC units, and the idea of non-disengager FCC unit are also discussed in this review. To accommodate to degraded feedstock, more stringent environmental regulations and new FCC process technologies, future R&D efforts on RTD technologies should be put on improvements to further satisfy the three-“quick”s and two-“high”s requirements with changing FCC operating conditions and different process requirements.
Acknowledgements
The authors acknowledge the financial supports by the Ministry of Science and Technology of China (2012CB215004 and 2012BAE05B02), the Ministry of Education of China by the Program for New Century Excellent Talents in University (NCET-11–0733) and the Science Foundation of China University of Petroleum, Beijing (KYJJ2012–03–11). The close cooperation and communication with the stuff from related engineering companies, refineries and equipment manufacturing companies during the applications of these RTD technologies are also acknowledged.
References
1. Letzsch WS. Fluid catalytic cracking. In: Jones DSJ, Pujadó PR, editors. Handbook of petroleum processing. Dordrecht, The Netherlands: Springer, 2006:253.Suche in Google Scholar
2. Wei Y, Yan H, Shi, M. Flow analysis of coking on the riser external wall of cyclone separator in the disengage of heavy oil catalytic cracker. Pet Process Petrochem 2000;31:33–6 (in Chinese).Suche in Google Scholar
3. Song J, Sun G, Chao Z, Wei, Y. Gas flow behavior in industrial FCC disengager vessels with different coupling configurations between two-stage separators. Powder Technol 2011;207:444–53.10.1016/j.powtec.2010.11.036Suche in Google Scholar
4. Kim SW, Lee JW, Koh JS, Kim GR, Choi S, Yoo IS. Formation and characterization of deposits in cyclone dipleg of a commercial residue fluid catalytic cracking reactor. Ind Eng Chem Res 2012:Article ASAP. doi:10.1021/ie301864x.10.1021/ie301864xSuche in Google Scholar
5. Kelly WA, Hunt L, Zhao, X. FCC unit short contact time observations. NPRA Annual Meeting, San Antonio, TX, AM-96–26, 1996.Suche in Google Scholar
6. Avidan AA, Krambeck FJ, Owen H, Schipper PH. FCC closed-cyclone system. Oil Gas J 1990;88:56–63.Suche in Google Scholar
7. Chen Y-M. Recent advances in FCC technology. Powder Technol 2006;163:2–8.10.1016/j.powtec.2006.01.001Suche in Google Scholar
8. Couch KA, Seibert KD, Van Opdorp, P. Controlling FCC yields and emissions: UOP technology for a changing environment. NPRA Annual Meeting, San Antonio, TX, AM-04–45, 2004.Suche in Google Scholar
9. Niccum PK, Santner CR. KBR fluid catalytic cracking process. In: Meyers RA, editor. Handbook of petroleum refining processes (3ED). New York: McGraw-Hill Professional, 2003.Suche in Google Scholar
10. Letzsch WS. Stone & Webster–Institut Francis du pétrole fluid RFCC process. In: Meyers RA, editor. Handbook of petroleum refining processes (3ED). New York: McGraw-Hill Professional, 2003.Suche in Google Scholar
11. Gauthier T, Andreux R, Verstraete J, Roux R, Ross, J. Industrial development and operation of an efficient riser separation system for FCC units. Int J Chem Reactor Eng 2005;3(1); ISSN (Online) 1542–6580, Doi: 10.2202/1542-6580.1247.10.2202/1542-6580.1247Suche in Google Scholar
12. Andreux R, Ferschneider G, Hémati M, Simonin, O. Experimental study of a fast gas-particle separator. Chem Eng Res Des 2007;85:808–14.10.1205/cherd06154Suche in Google Scholar
13. Xie C. Recent advance of fluid catalytic cracking technologies. Report of RIPP on FCC technologies. SINOPEC, Beijing, China, 2010 (in Chinese).Suche in Google Scholar
14. Zhang D. Preface. Proceeding of the 11th FCC Annual Meeting of China, Jiujiang, Jiangxi Province, China, 2007 (in Chinese).Suche in Google Scholar
15. Wang X, Xie C, Li Z, Zhu G. Catalytic processes for light olefin production. In: Hsu GS, Robinson PR, editors. Practical advances in petroleum processing, Vol. 1. New York: Springer, 2006:149–68.Suche in Google Scholar
16. Song J, Sun G, Chao Z, Wei Y, Shi, M. Gas flow behavior and residence time distribution in a FCC disengager vessel with different coupling configurations between two-stage separators. Powder Technol 2010;201:258–65.10.1016/j.powtec.2010.04.008Suche in Google Scholar
17. Lu C, Cao Z, Shi M. Experimental study and industrial application of a novel riser termination system: Fender-Stripping Cyclone (FSC). Proceeding of the Seventh FCC Annual Meeting of China, Shanghai, China, 2000 (in Chinese).Suche in Google Scholar
18. Cao Z, Lu C, Shi M. Study of a new rough cyclone with a stripper attached. Pet Process Petrochem 1997;28:47–51 (in Chinese).Suche in Google Scholar
19. Liu W, Bian X, Wei S. Commercial application of shed stripping cyclone. Pet Process Petrochem 2000;30:45–7 (in Chinese).Suche in Google Scholar
20. Lu C, Xu G, Lu S, Shi M. Study and industry application of a pre-stripping separation system for riser termination of FCCU. Pet Process Petrochem 2002;33:33–7 (in Chinese).Suche in Google Scholar
21. Xu K. Revamping of FCC unit with CSC rapid-separation technology. Pet Refinery Eng 2005;35:11–13 (in Chinese).Suche in Google Scholar
22. Cao Z, Shi M. Study of a vortex rough cut separation system for FCC riser outlet. Pet Process Petrochem 1996;27:10–13 (in Chinese).Suche in Google Scholar
23. Cao Z, Lu C, Shi M. Vortex type fast separation system at FCCU riser outlet. Pet Refinery Eng 1999;29:14–8 (in Chinese).Suche in Google Scholar
24. Hu Y, Lu C, Shi M. Performance comparison of two newly developed disengager arms in vortex quick separator for FCC disengager. J Chem Ind Eng (China) 2008;59:2478–84 (in Chinese).Suche in Google Scholar
25. Lu C, Cai Z, Shi M. Experimental study and industry application of a new vortex quick separation system at FCCU riser outlet. Acta Petrolei Sinica (Pet Process Sect) 2004;20:24–9 (in Chinese).Suche in Google Scholar
26. Zhou S, Lu C, Shi M. Study on the flow field of gas–solid vortex quick separator with different structure. Pet Process Petrochem 2004;34:12–17 (in Chinese).Suche in Google Scholar
27. Sun F, Lu C, Shi M. Modification of the 3-dimension gas flow field in the vortex quick separation system of FCC disengager. Pet Process Petrochem 2004;35:51–5 (in Chinese).Suche in Google Scholar
28. Sun F, Lu C, Shi M. Numerical simulation and analysis of gas flow field in vortex quick separation system of FCC disengager. J Chem Ind Eng (China) 2005;56:16–23 (in Chinese).Suche in Google Scholar
29. Sun F, Lu C, Shi M. Numerical simulation of gas-particles flow field in new vortex quick separation system for FCC disengager. J Chem Ind Eng (China) 2005;56:2280–7 (in Chinese).Suche in Google Scholar
30. Hu Y, Wang Y, Lu C, Shi M. Improvement of the isolate cylinder in vortex quick separation system at FCC riser outlet. Acta Petrolei Sinica (Pet Process Sect) 2008;24:177–83 (in Chinese).Suche in Google Scholar
31. Liu X, Lu C, Shi M. Structural optimization of a novel gas-solid separator incorporating inertial and centrifugal separation. Chin J Process Eng 2005;5:504–8 (in Chinese).Suche in Google Scholar
32. Liu X, Lu C, Zhang X, Shi M. Performance examination of a novel gas-solid separator used at outlet of post coke-burning riser in large scale cold model experimental setup. Chem React Eng Technol 2005;21:309–14 (in Chinese).Suche in Google Scholar
33. Yan C, Lu C, Liu X, Shi M. Numerical simulation of flow field in a novel gas-solids separator. J Chem Eng Chin Univ 2007;21:392–7 (in Chinese).Suche in Google Scholar
34. Liu X, Lu C, Shi M. Experimental research of the flow field in a novel gas-solids separator. J Chem Eng Chin Univ 2006;20:875–81 (in Chinese).Suche in Google Scholar
35. Liu X, Lu C, Yan C, Shi M. Structural optimization of a novel gas-solid separator. Chem React Eng Technol 2006;22:120–4 (in Chinese).Suche in Google Scholar
36. Lu C, Liu X, Shi M. A gas-solids separator with central gas outlet pipe. Chinese Patent, ZL 200510077578.8, 2007 (in Chinese).Suche in Google Scholar
37. Gai X, Tian Y, Xia D, Qiao Y. Structural optimization of a novel up-run gas-solid separator. Chin Pet Process Petrochem Technol 2011;13:36–42 (in Chinese).Suche in Google Scholar
38. Yang Y, Qian Z, Yu H, Wei F, Jin Y. A novel gas-solid separator used in concurrent down-flow reactor. Pet Process Petrochem 2000;31:24–7 (in Chinese).Suche in Google Scholar
39. Zhang L, Yan B, Wu C, Cheng Y. Numerical simulation of gas-solids fast separator in ultra-short contact reactor. J Chem Ind Eng (China) 2010;61:623–8 (in Chinese).Suche in Google Scholar
40. Wei Y, Song J, Chen J, Shi M. A fluid catalytic cracking process without disengager. Pet Refinery Eng 2008;38:9–12 (in Chinese).Suche in Google Scholar
41. Song J, Wei Y, Chen J, Shi M. Analysis of necessity and feasibility of fluidized catalytic cracking unit without a disengager. Modern Chem Ind 2009;29:69–75 (in Chinese).Suche in Google Scholar
42. Lu C, Xu W, Wei Y, Zhang Y, Shi M. Experimental studies of a novel compact FCC disengager. Acta Petrolei Sinica (Pet Process Sect) 2007;23:6–12 (in Chinese).Suche in Google Scholar
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