Startseite A critical review of the multilayer sorption models and comparison with the sorption site occupancy (SSO) model for wood moisture sorption isotherm analysis
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A critical review of the multilayer sorption models and comparison with the sorption site occupancy (SSO) model for wood moisture sorption isotherm analysis

  • Wim Willems EMAIL logo
Veröffentlicht/Copyright: 7. Juni 2014
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Abstract

The wood moisture sorption (WMS) isotherm is generally considered to contain information on the water-cell wall interaction and the abundance of water sorption sites (SSs) in wood. The Hailwood-Horrobin (HH) model – as an example of the multilayer surface sorption models – is discussed for its suitability to analyze experimental WMS isotherms, to elaborate the fundamental sorption parameters. Based on multiple independent experimental and theoretical arguments, it was concluded that the basics of the surface multilayer-sorption models do not apply to wood. This is clearly illustrated by applying the analysis to the temperature-dependence of WMS isotherms, to the comparison of adsorption vs. desorption isotherms and to the quantification of SSs in wood. A sorption site occupancy (SSO) model is presented as an alternative for the HH model. It provides a comprehensive, thermodynamically consistent and quantitative basis for the analysis of WMS isotherms. The predicted SS densities are realistic and can be used to quantify sorption hysteresis and cell wall relaxation.


Corresponding author: Wim Willems, Wood Biology and Wood Products, Georg-August University Göttingen, Büsgenweg 4, 37077 Göttingen, Germany; and FirmoLin Technologies BV, Grote Bottel 7a, 5753 PE Deurne, the Netherlands, e-mail:

References

Araujo, C.D., Avramidis, S., MacKay, A.L. (1994) Behavior of solid wood and bound water as a function of moisture content – a proton magnetic resonance study. Holzforschung 48:69–74.10.1515/hfsg.1994.48.1.69Suche in Google Scholar

Back, E.L., Salmén, N.L. (1982) Glass transition of wood components hold implications for molding and pulping processes. Tappi J. 65:107–110.Suche in Google Scholar

Barkas, W.W. The Swelling of Wood Under Stress. HM Stationary Office, London, 1949.Suche in Google Scholar

Berthold, J., Rinaudo, M., Salmén, L. (1996) Association of water to polar groups–estimations by an adsorption model for ligno-cellulosic materials. Colloid Surf. A 112:117–129.Suche in Google Scholar

Brunauer, S., Emmett, P.H., Teller, E. (1938) Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60:309–319.Suche in Google Scholar

Caulfield, D.F., Weatherwax, R.C. (1978) Tensile modulus of paper wet-stiffened by crosslinking. In: Fiberwater Interactions in Papermaking: Transactions of The Symposium held at Oxford 1977, Vol 2, pp. 741–763.Suche in Google Scholar

Chirkova, J., Andersons, B., Andersone, I. (2009) Study of the structure of wood-related biopolymers by sorption methods. BioResources 4:1044–1057.Suche in Google Scholar

Engelund, E.T., Thygesen, L.G., Svensson, S., Hill, C.A.S. (2013) A critical discussion of the physics of wood-water interactions. J. Wood Sci. Technol. 47:141–161.Suche in Google Scholar

Freundlich, H.M.F. (1906) On the adsorption in solutions. Z. Phys. Chem. A57:385–470.Suche in Google Scholar

Glass, S.V., Zelinka, S.L. (2010) Moisture relations and physical properties of wood. In: Wood Handbook, Chapter 04: General Technical Report FPL-GTR-190. U.S. Department of Agriculture, Forest Service, Forest Products Laboratory, Madison, pp. 1–19.Suche in Google Scholar

González-Peña, M.M., Breese, M.C., Hale, M.D.C. (2005) Studies on the relaxation of heat-treated wood. In: Wood modification: processes properties and commercialization. Eds. Militz, H., Hill, C. Georg-August University Press, Göttingen. pp. 87–90.Suche in Google Scholar

Gröndahl, M., Eriksson, L., Gatenholm, P. (2004) Material Properties of Plasticized Hardwood Xylans for Potential Application as Oxygen Barrier Films. Biomacromolecules 5:1528–1535.10.1021/bm049925nSuche in Google Scholar PubMed

Guo, J., Barbari, T.A. (2009) Unified dual mode description of small molecule sorption and desorption kinetics in a glassy polymer. Macromolecules 42:5700–5708.10.1021/ma9007576Suche in Google Scholar

Hailwood A.J., Horrobin, S. (1946) Absorption of water by polymers – analysis in terms of a simple model. Trans. Faraday Soc. 42B:84–102.10.1039/tf946420b084Suche in Google Scholar

Hill, C.A.S. Wood Modification – Chemical, Thermal and Other Processes. John Wiley & Sons, Chichester, 2006.10.1002/0470021748Suche in Google Scholar

Hill, C.A.S. (2008) The reduction in the fibre saturation point of wood due to chemical modification using anhydride reagents: a reappraisal. Holzforschung 62:423–428.10.1515/HF.2008.078Suche in Google Scholar

Hill, C.A.S., Norton, A., Newman, G. (2009) The water vapor sorption behavior of natural fibers. Appl. Polym. Sci. 112:1524–1537.Suche in Google Scholar

Hoffmeyer, P., Engelund, E.T., Thygesen, L.G. (2011) Equilibrium moisture content (EMC) in Norway spruce during the first and second desorptions. Holzforschung 65:875–882.10.1515/HF.2011.112Suche in Google Scholar

Jalaludin, Z. The water vapour sorption behaviour of wood. PhD thesis, Edinburgh Napier University, 2012.Suche in Google Scholar

Jalaludin, Z., Hill, C.A.S., Xie, Y., Samsi, H.W., Husain, H. Awang, K., Curling, S.F. (2010) Analysis of the water vapour sorption isotherms of thermally modified acacia and sesendok. Wood Mater. Sci. Eng. 5:194–203.Suche in Google Scholar

Kelly, M.W., Hart, C.A. (1970). Water vapor sorption rates by wood cell walls. Wood Fiber Sci. 1:270–282.Suche in Google Scholar

Lam, P.S. Steam explosion of biomass to produce durable wood pellets. PhD Thesis, Vancouver, University of British Columbia, 2011.Suche in Google Scholar

Lenth, C.A. Wood Material behavior in Severe environments. PhD Thesis, Virginia Polytechnic Institute, 1999.Suche in Google Scholar

Murata, K., Watanabe, Y., Nakano, T. (2013) Effect of thermal treatment on fracture properties and adsorption properties of spruce wood. Materials 6:4186–4197.10.3390/ma6094186Suche in Google Scholar PubMed PubMed Central

Nakano, T. (2006) Analysis of the temperature dependence of water sorption for wood on the basis of dual mode theory. J. Wood Sci. 52:490–495.10.1007/s10086-006-0807-2Suche in Google Scholar

Nissan, A.H., Batten, G.L. (1990) On the primacy of the hydrogen bond in paper mechanics. Tappi J. 73:159–16.Suche in Google Scholar

Olek, W., Majka, J., Czajkowski, Ł. (2013) Sorption isotherms of thermally modified wood. Holzforschung 67:183–191.10.1515/hf-2011-0260Suche in Google Scholar

Papadopoulos, A.N., Mantanis, G.I. (2012) Vapour sorption studies of Belmadur wood. Adv. Forestry Lett. 1:1-6.Suche in Google Scholar

Polanyi, M. (1916) Adsorption of gases (vapors) by a solid non-volatile adsorbent. Verh. Dtsch. Phys. Ges. 18:55–80.Suche in Google Scholar

Popescu, C.M., Hill, C.A.S. (2013) The water vapour adsorption–desorption behaviour of naturally aged Tilia cordata Mill. wood, Polym. Degrad. Stab. 98:1804–1813.10.1016/j.polymdegradstab.2013.05.021Suche in Google Scholar

Popper, R., Niemz, P., Croptier, S. (2009) Adsorption and desorption measurements on selected exotic wood species. Analysis with the Hailwood-Horrobin model to describe the sorption hysteresis. Wood Res. 54:43–56.Suche in Google Scholar

Rautkari, L., Hill, C.A.S., Curling, S., Jalaludin, Z., Ormondroyd, G. (2013) What is the role of the accessibility of wood hydroxyl groups in controlling moisture content? J. Mater. Sci. 48: 6352–6356.Suche in Google Scholar

Shirota, H., Horie, K. (1999) Deuterium isotope effect on swelling process in aqueous polymer gels. Chem. Phys. 242:115–121.Suche in Google Scholar

Siau, J.F. Transport Processes in Wood. Springer, Berlin, 1984.10.1007/978-3-642-69213-0Suche in Google Scholar

Skaar, C. Wood-Water Relations. Springer Verlag, Berlin, 1988.10.1007/978-3-642-73683-4Suche in Google Scholar

Thygesen, L.G., Engelund, E.T., Hoffmeyer, P. (2010) Water sorption in wood and modified wood at high values of relative humidity – Part 1: results for untreated, acetylated, and furfurylated Norway spruce. Holzforschung 64:315–323.10.1515/hf.2010.044Suche in Google Scholar

Vrentas, J.S., Vrentas C.M. (1991) Sorption in glassy polymers. Macromolecules 24:2404–2412.10.1021/ma00009a043Suche in Google Scholar

Weichert, L. (1963) Investigations on sorption and swelling of spruce, beech and compressed beech wood at temperatures between 20° and 100°C. Holz. Roh. Werkst. 21:290–300.10.1007/BF02610962Suche in Google Scholar

Willems, W. (2014a) The water vapor sorption mechanism and its hysteresis in wood: the water/void mixture postulate. J. Wood Sci. Technol. 48:499–518.10.1007/s00226-014-0617-4Suche in Google Scholar

Willems, W. (2014b) The hydrostatic pressure and temperature dependence of wood moisture sorption isotherms. J. Wood Sci. Technol. 48:483–498.10.1007/s00226-014-0616-5Suche in Google Scholar

Zaihan, J., Hill, C.A.S., Curling, S., Hashim, W.S., Hamdan, H. (2009) Moisture adsorption isotherms of Acacia mangium and Endospermum malaccense using dynamic vapour sorption. J. Trop. For. Sci. 21:277–285.Suche in Google Scholar

Zauscher, S., Caulfield, D.F., Nissan, A.H. (1996) The influence of water on the elastic modulus of paper Part 1: extension of the H-bond theory. Tappi J. 79:178–182.Suche in Google Scholar

Received: 2014-3-7
Accepted: 2014-5-9
Published Online: 2014-6-7
Published in Print: 2015-1-1

©2015 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Original Articles
  3. Influence of spruce xylan characteristics on tensile strength of spruce kraft pulp
  4. Evidence for a very slow disaggregation of lignosulfonates
  5. Slow relaxation mode of sodium lignosulfonate in saline solutions
  6. Influence of carboxylic group content on the solution behavior of carboxymethylated lignin (CML) in water
  7. Chemithermomechanical and kraft pulping of Pinus radiata wood chips after the hydrothermal extraction of hemicelluloses
  8. In-plane shear strength of paper measured by asymmetric four-point bending test
  9. Strain distribution and load transfer in the polymer-wood particle bond in wood plastic composites
  10. Structural changes in spruce wood during different steps of steam explosion pretreatment
  11. A critical review of the multilayer sorption models and comparison with the sorption site occupancy (SSO) model for wood moisture sorption isotherm analysis
  12. Hygric properties of Norway spruce and sycamore after incubation with two white rot fungi
  13. On-line monitoring of hygroscopicity and dimensional changes of wood during thermal modification by means of neutron imaging methods
  14. Influence of blue stain on density and dimensional stability of Pinus radiata timber from northern Galicia (Spain)
  15. Bacterial and abiotic decay in waterlogged archaeological Picea abies (L.) Karst studied by confocal Raman imaging and ATR-FTIR spectroscopy
  16. Effects of vitamin E combined with antioxidants on wood flour/polypropylene composites during accelerated weathering
  17. Short Note
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  19. Lignin masks the presence of fibrillar network structure in the cell corner middle lamella (CCML)
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