Home Preparation and application of modified carboxymethyl cellulose Si/polyacrylate protective coating material for paper relics
Article
Licensed
Unlicensed Requires Authentication

Preparation and application of modified carboxymethyl cellulose Si/polyacrylate protective coating material for paper relics

  • Qian Chen , Wen-Ya Wen , Feng-Xian Qiu EMAIL logo , Ji-Cheng Xu , Han-Qiang Yu , Ming-Liang Chen and Dong-Ya Yang
Published/Copyright: April 21, 2016
Become an author with De Gruyter Brill

Abstract

There are large numbers of paper cultural relics in China, the country where paper making was invented. However, the paper relics have not been adequately protected so they are at risk of ageing, damage and disappearance. In order to better protect the paper relics, modified carboxymethyl cellulose/Si/polyacrylate protective materials were prepared with acrylicresin and modified carboxymethyl cellulose which has a good affinity with the paper and modified silica, improving the mechanical strength and ability to withstand weathering. The modified CMC/Si/polyacrylate protective material was analysed using infrared spectroscopy, transmission electron microscopy, differential scanning calorimetry and other performance-testing devices. The surface morphology of the paper samples was analysed using scanning electron microscopy. The protective material so prepared was evaluated by subjection to accelerated ageing (dry heat treatment). The results showed the protective material films to have good hydrophobicity, acid/alkali resistance and mechanical strength. When the content of SiO2 is 6 mass %, the protective material has an excellent comprehensive performance. The results of the ageing test reveal that the prepared material can effectively slow down the ageing rate. The prepared material is suited to the protection of paper cultural relics.

Acknowledgements

This project was supported by the Society Development Fund of Zhenjiang (SH2013020 and SH2014074), Project of Science and Technology of Suzhou (SG201338), Zhenjiang College Scientific Research Team (ZJCKYTD07) and sponsored by the Qing Lan Project (2012-2015).

References

Area, M. C., & Cheradame, H. (2011). Paper aging and degradation: Recent findings and research methods. Bioresources, 6, 5307–5337.Search in Google Scholar

Barberena-Fernández, A. M., Carmona-Quiroga, P. M., & Blanco-Varela, M. T. (2015). Interaction of TEOS with cementitious materials: Chemical and physical effects. Cement and Concrete Composites, 55, 145–152. DOI: 10.1016/j. cemconcomp.2014.09.010.10.1016/j. cemconcomp.2014.09.010Search in Google Scholar

Cocca, M., D’Arienzo, L., D’Orazio, L., Gentile, G., Mancarella, C., Martuscelli, E., & Polcaro, C. (2006). Water dispersed polymers for textile conservation: A molecular, thermal, structural, mechanical and optical characterization. Journal of Cultural Heritage, 7, 236–243. DOI: 10.1016/j.culher.2005.11.002.10.1016/j.culher.2005.11.002Search in Google Scholar

Fan, L. H., Zhang, Z. J., Yu, X. Y., Xue, Y. X., & Tan, T. W. (2012). Self-surface assembly of cellulosomes with two miniscaffoldins on Saccharomyces cerevisiae for cellulosic ethanol production. In Proceedings of the National Academy of Sciences of the United State of America, 109, 13260–13265. DOI: 10.1073/pnas.1209856109.10.1073/pnas.1209856109Search in Google Scholar PubMed PubMed Central

Guo, T. Y., Xi, C., Hao, G. J., Song, M. D., & Zhang, B. H. (2005). Preparation and properties of room temperature self-cros slinking poly (MMA-co-BA-co-St-co-VTES) latex film. Advances in Polymer Technology, 24, 288–295. DOI: 10.1002/adv.20051.10.1002/adv.20051Search in Google Scholar

Gutarowska, B., Skora, J., Zduniak, K., & Rembisz, D. (2012). Analysis of the sensitivity of microorganisms contaminating museums and archives to silver nanoparticles. International Biodeterioration & Biodegradation, 68, 7–17. DOI: 10.1016/j.ibiod.2011.12.002.10.1016/j.ibiod.2011.12.002Search in Google Scholar

Hashemi-Nasab, R., & Mirabedini, S. M. (2013). Effect of silica nanoparticles surface treatment on in situ polymerization of styrene–butyl acrylate latex. Progress in Organic Coatings, 76, 1016–1023. DOI: 10.1016/j.porgcoat.2013.02.016.10.1016/j.porgcoat.2013.02.016Search in Google Scholar

He, L., Liang, J. Y., Zhao, X. A., Li, W. D., & Luo, H. J. (2010). Preparation and comparative evaluation of well-defined fluorinated acrylic copolymer latex and solution for ancient stone protection. Progress in Organic Coatings, 69, 352–358. DOI: 10.1016/j.porgcoat.2010.07.008.10.1016/j.porgcoat.2010.07.008Search in Google Scholar

Karbowska-Berent, J., Górny, R. L., Strzelczyk, A. B., & Wlaz_lo, A. (2011). Airborne and dust borne microorganisms in selected Polish libraries and archives. Building and Enviroment, 46, 1872–1879. DOI: 10.1016/j.buildenv.2011.03.007.10.1016/j.buildenv.2011.03.007Search in Google Scholar

Li, Q. L., Xi, S. C., & Zhang, X. W. (2014). Conservation of paper relics by electrospun PVDF fiber membranes. Journal of Cultural Heritage, 15, 359–364. DOI: 10.1016/j.culher.2013.09.003.10.1016/j.culher.2013.09.003Search in Google Scholar

Liu, B. L., Zhang, B. T., Cao, S. S., Deng, X. B., Hou, X. H., & Chen, H. L. (2008). Preparation of the stable core–shell latex particles containing organic-siloxane in the shell. Progress in Organic Coatings, 61, 21–27. DOI: 10.1016/j.porgcoat.2007.08.008.10.1016/j.porgcoat.2007.08.008Search in Google Scholar

Michaelsen, A., Pinzari, F., Ripka, K., Lubitz, W., & Pi˜nar, G. (2006). Application of molecular techniques for identification of fungal communities colonising paper material. Inxiv Q. Chen et al./Chemical Papers ternational Biodeterioration & Biodegradation, 58, 133–141. DOI: 10.1016/j.ibiod.2006.06.019.10.1016/j.ibiod.2006.06.019Search in Google Scholar

Orelma, H., Filpponen, I., Johansson, L. S., Laine, J., & Rojas, O. J. (2011). Modification of cellulose films by adsorption of CMC and chitosan for controlled attachment of biomolecules. Biomacromolecules, 12, 4311–4318. DOI: 10.1021/bm201236a.10.1021/bm201236aSearch in Google Scholar

Princi, E., Vicini, S., Pedemonte, E., Arrighi, V., & McEwen, I. J. (2007). New polymeric materials for paper and textiles conservation. II. Grafting polymerization of ethyl acrylate/methyl methacrylate copolymers onto linen and cotton. Journal of Applied Polymer Science, 103, 90–99. DOI: 10.1002/app.24689.10.1002/app.24689Search in Google Scholar

Qi, H. S., Liebert, T., Meister, F., Zhang, L. N., & Heinze, T. (2010). Homogenous carboxymethylation of cellulose in the new alkaline solvent LiOH/urea aqueous solution. Macromolecular Symposia, 294, 125–132. DOI: 10.1002/masy. 200900166.10.1002/masy. 200900166Search in Google Scholar

Strzelczyk, A. B. (2004). Observations on aesthetic and structural changes induced in Polish historic objects by microorganisms. International Biodeterioration & Biodegradation, 53, 151–156. DOI: 10.1016/s0964-8305(03)00088-x.10.1016/s0964-8305(03)00088-xSearch in Google Scholar

Su, T., Wang, G. Y., Wang, S. L., & Hu, C. P. (2010). Fluorinated siloxane-containing waterborne polyurethaneureas with excellent hemocompatibility, waterproof and mechanical properties. European Polymer Journal, 46, 472–483. DOI: 10.1016/j.eurpolymj.2009.12.009.10.1016/j.eurpolymj.2009.12.009Search in Google Scholar

The Chinese National Standards (2008a). Chinese standard: Paper and board-sampling for testing and identification of machine and cross direction, wire side and felt side. GB/T 450-2008. Beijing, China: The Chinese National Standards.Search in Google Scholar

The Chinese National Standards (2008b). Chinese standard: Accelerated aging (dry heat treatment) of paper and board. GB 464-2008. Beijing, China: The Chinese National Standards.Search in Google Scholar

Totolin, M. I., & Neamtu, I. (2011). Positive findings for plasma polymer (meth)acrylate thin films in heritage protective applications. Journal of Cultural Heritage, 12, 392–398. DOI: 10.1016/j.culher.2011.03.005.10.1016/j.culher.2011.03.005Search in Google Scholar

Wang, Y. J., Fang, Y. X., Tan, W., & Liu, C. Y. (2013). Preservation of aged paper using borax in alcohols and the supercritical carbon dioxide system. Journal of Cultural Heritage, 14, 16–22. DOI: 10.1016/j.culher.2012.02.010.10.1016/j.culher.2012.02.010Search in Google Scholar

Yang, H. N., Park, J. S., Jeon, S. Y., & Park, K. H. (2015). Carboxymethylcellulose (CMC) formed nanogels with branched poly(ethyleneimine) (bPEI) for inhibition of cytotoxicity in human MSCs as a gene delivery vehicles. Carbohydrate Polymers, 122, 265–275. DOI: 10.1016/j.carbpol.2014.12.073.10.1016/j.carbpol.2014.12.073Search in Google Scholar PubMed

Received: 2015-7-29
Revised: 2015-12-8
Accepted: 2015-12-9
Published Online: 2016-4-21
Published in Print: 2016-7-1

© 2016 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

  1. Original Paper
  2. Oxygen transfer rate and pH as major operating parameters of citric acid production from glycerol by Yarrowia lipolytica W29 and CBS 2073
  3. Original Paper
  4. Repetitive inductions of bioluminescence of Pseudomonas putida TVA8 immobilised by adsorption on optical fibre
  5. Original Paper
  6. Novel catalytic system: N-hydroxyphthalimide/hydrotalcite-like compounds catalysing allylic carbonylation of cyclic olefins
  7. Original Paper
  8. Total oxidation of ethanol and toluene over ceria—zirconia supported platinum catalysts
  9. Original Paper
  10. ZnO-nanorods as economical catalyst for synthesis of 4-amino-2-iminodithiole derivatives using tetramethyl thiourea in water
  11. Original Paper
  12. Cr(VI) ion removal from artificial waste water using supported liquid membrane
  13. Original Paper
  14. Waste poly (vinyl chloride) pyrolysis with hydrogen chloride abatement by steelmaking dust
  15. Original Paper
  16. Effect of titanium source on structural properties and acidity of Ti-pillared bentonite
  17. Original Paper
  18. Preparation and application of modified carboxymethyl cellulose Si/polyacrylate protective coating material for paper relics
  19. Original Paper
  20. Role of polydimethylsiloxane in properties of ternary materials based on polyimides containing zeolite Y
  21. Original Paper
  22. Synthesis of 1-fluoro-substituted codeine derivatives
  23. Original Paper
  24. Synthesis and biological activities of novel quinazolinone derivatives containing a 1,2,4-triazolylthioether moiety
  25. Original Paper
  26. Importance of inter-residue interactions in ligand—receptor binding
Downloaded on 27.11.2025 from https://www.degruyterbrill.com/document/doi/10.1515/chempap-2016-0029/html
Scroll to top button