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Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡

  • Masahiro Mikuriya EMAIL logo , Mayu Hamagawa , Natsuki Tomioka , Rika Fujimori , Daisuke Yoshioka , Shoichi Hori , Taro Kuriyama , Hiroshi Sakiyama , Makoto Handa und Ryoji Mitsuhashi
Veröffentlicht/Copyright: 22. Januar 2016
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 70 Heft 1

A nickel(II) complex, [Ni(taetacn)](ClO4)2 · H2O, where taetacn = 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane was synthesized. The crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. The complex crystallizes in the orthorhombic space groupPna21 with a = 16.004(2) Å, b = 10.186(1) Å, c = 13.937(2) Å, V = 2271.9(5) Å3, Dx = 1.56 g cm−3, Dm = 1.59 g cm−3 (floatation method), and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0636 and 0.1672, respectively, for all 4845 independent reflections. The compound is composed of octahedral nickel(II) cation with three 2-aminoethyl pendant groups of taetacn, tetrahedral ClO4− anion, and a water molecule of crystallization. Electronic spectra are consistent with the octahedral geometry. Temperature dependence of the magnetic susceptibility (4.5–300 K) can be interpreted considering the zero-field splitting of the nickel(II) ion (g = 2.14, D = 3.72 cm−1, and Nα = 300 × 10−6 cm3 mol−1). Cyclic voltammetry in DMF showed quasi-reversible and irreversible oxidation waves (Epa = 0.54 V, Epc = 0.45 V; Epa = 1.16 V, Epc = 0.71 V vs. Ag/Ag+).

Keywords: nickel(II) complex; triazacyclononane ligand; crystal structure; magnetic property; electronic spectra

‡ Presented at the XXV. International Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, 31 May–5 June 2015

Acknowledgements.

The present work was partially supported by Grants-in-Aid for Scientific Research Nos. 26410080 from the Ministry of Education, Culture, Sports, Science and Technology and the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2010-2014.

Supplementary data

Crystallographic data for complex I reported in this paper have been deposited with the Cambridge Crystallographic Data Centre, CCDC no. 1035536. Copies of the information may be obtained free of charge from: The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: +441223-336033; e-mail: or via http://www.ccdc.cam.ac.uk/datarequest/cif).

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Received: 2015-3-15
Revised: 2015-5-29
Accepted: 2015-6-10
Published Online: 2016-1-22
Published in Print: 2016-1-1

© 2015 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0165
Schlagwörter für diesen Artikel
nickel(II) complex; triazacyclononane ligand; crystal structure; magnetic property; electronic spectra

Artikel in diesem Heft

  1. Original Paper
  2. Mononuclear and heterodinuclear phenanthrolinedione complexes of d- and f-block elements‡
  3. Original Paper
  4. New heteroscorpionate lanthanide complexes for ring-opening polymerisation of ɛ-caprolactone and rac-lactide‡
  5. Original Paper
  6. EPR on bis(1,2-dithiosquarato)cuprate(II) in the bis(1,2-dithiosquarato)nickelate(II) host lattice – structure and spectroscopy‡
  7. Review
  8. Electric fields in zeolites: fundamental features and environmental implications‡
  9. Short Communication
  10. Mononuclear cobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine and N-salicylidene-2-hydroxy-5-chlorobenzylamine‡
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  12. Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane‡
  13. Original Paper
  14. SOD mimetic activity of salicylatocopper complexes‡
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  17. Review
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  19. Original Paper
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