Novel pathways of interaction of maleic anhydride derivatives with phosphorus(III) compounds: synthesis and characterisation of N,N,N′,N′ -tetraethyl-2,3-diphenylbut-2-enediamide and 3-dihydrofuranylidene-4-phosphorylidene–oxolane-2,5,5′-trione
-
Lenar I. Musin
,
Dmitry B. Krivolapov
Abstract
Maleic anhydride undergoes C-phosphorylation under the action of tris(diethylamino)phosphine to afford 3-dihydrofuranylidene-4-phosphorylidene-oxolane-2,5,5′-trione whereas 2,3-diphenylmaleic anhydride under the same conditions turns into N,N,N′,N′-tetraethyl-2,3-diphenylbut-2-enediamide. The latter reaction can serve as a novel approach for the synthesis of dicarboxylic acids diamides from corresponding cyclic anhydrides. Their structures were established by NMR and X-ray diffraction.
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© 2015 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Voltammetric determination of B1 and B6 vitamins using a pencil graphite electrode
- An electrochemical sensor for sensitive determination of nitrites based on Ag–Fe3O4–graphene oxide magnetic nanocomposites
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- Electrode and electrodeless impedance measurement for determination of orange juices parameters
- Evaluation of oxidative stability of vegetable oils enriched with herb extracts by EPR spectroscopy
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