Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
Isolation and identification of residual chromophores from aged bleached pulp samples
-
Thomas Rosenau
Veröffentlicht/Copyright:
1. November 2007
Abstract
Three bleached and subsequently aged cellulosic pulps have been analysed for their chromophore content according to the chromophore release and identification (CRI) method. Several chromophores have been unambiguously identified, despite their very low content (ppb range). This is the first report on defined chromophoric structures isolated from bleached pulps. It is also the first application of the CRI method to cellulose I substrates, rather than to cellulose II substrates (fibres) and cellulose derivatives as hitherto performed. A common feature of the chromophores is the 2-hydroxy-[1,4]benzoquinone moiety, which is strongly stabilized by resonance or tautomerism. The structure of the chromophores indicates that oxidised carbohydrate structures act as precursor moieties, which condense upon ageing to the chromophore structures identified.
Received: 2007-2-7
Accepted: 2007-6-12
Published Online: 2007-11-01
Published in Print: 2007-11-01
©2007 by Walter de Gruyter Berlin New York
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Acknowledgement
- Subject index
- Contents Volume 61 (2007)
- Author index
- Species index (scientific names)
- Meetings
- Improvement of Pinus pinaster Ait elite trees selection by combining near infrared spectroscopy and genetic tools
- Direct method for the determination of phenolic hydroxyl groups in pulp
- Comparative effect of ozone, chlorine dioxide, and hydrogen peroxide on lignin: Reactions affecting pulp colour in the final bleaching stage
- Structural modification of eucalypt pulp lignin in a totally chlorine-free bleaching sequence including a laccase-mediator stage
- Analysis of wood tissues by time-of-flight secondary ion mass spectrometry
- Isolation and identification of residual chromophores from aged bleached pulp samples
- Studies on oxidative modifications of cellulose in the periodate system: Molecular weight distribution and carbonyl group profiles
- Lignin-carbohydrate network in wood and pulps: A determinant for reactivity
- Cross polarisation/magic angle spinning 13C-NMR spectroscopic studies of cellulose structural changes in hardwood dissolving pulp process
- Fungal decay of spruce and beech wood assessed by near-infrared spectroscopy in combination with uni- and multivariate data analysis
- Paper mill sludge as a component of wood adhesive formulation
- Implementation of sorption hysteresis in multi-Fickian moisture transport
- Time/temperature equivalence in the dry wood creep response
- Neural network prediction of bending strength and stiffness in western hemlock (Tsuga heterophylla Raf.)
- Bending properties of particleboard and MDF layers
- Gold as an X-ray CT scanning contrast agent: Effect on the mechanical properties of wood plastic composites
- Lignin modification in the initial phase of softwood kraft pulp delignification with polyoxometalates (POMs)
Schlagwörter für diesen Artikel
aging;
bleached pulp;
bleaching;
cellulose;
chromophores;
CRI method;
hydroxyquinones
Artikel in diesem Heft
- Acknowledgement
- Subject index
- Contents Volume 61 (2007)
- Author index
- Species index (scientific names)
- Meetings
- Improvement of Pinus pinaster Ait elite trees selection by combining near infrared spectroscopy and genetic tools
- Direct method for the determination of phenolic hydroxyl groups in pulp
- Comparative effect of ozone, chlorine dioxide, and hydrogen peroxide on lignin: Reactions affecting pulp colour in the final bleaching stage
- Structural modification of eucalypt pulp lignin in a totally chlorine-free bleaching sequence including a laccase-mediator stage
- Analysis of wood tissues by time-of-flight secondary ion mass spectrometry
- Isolation and identification of residual chromophores from aged bleached pulp samples
- Studies on oxidative modifications of cellulose in the periodate system: Molecular weight distribution and carbonyl group profiles
- Lignin-carbohydrate network in wood and pulps: A determinant for reactivity
- Cross polarisation/magic angle spinning 13C-NMR spectroscopic studies of cellulose structural changes in hardwood dissolving pulp process
- Fungal decay of spruce and beech wood assessed by near-infrared spectroscopy in combination with uni- and multivariate data analysis
- Paper mill sludge as a component of wood adhesive formulation
- Implementation of sorption hysteresis in multi-Fickian moisture transport
- Time/temperature equivalence in the dry wood creep response
- Neural network prediction of bending strength and stiffness in western hemlock (Tsuga heterophylla Raf.)
- Bending properties of particleboard and MDF layers
- Gold as an X-ray CT scanning contrast agent: Effect on the mechanical properties of wood plastic composites
- Lignin modification in the initial phase of softwood kraft pulp delignification with polyoxometalates (POMs)
