The Role of Fatty Acids Functional Group in Morinda citrifolia L. on Surface Tension and Diffusion Performance into Ink Particles
-
Trismawati Trismawati
, I. N. G. Wardana , Nurkholis Hamidi and Mega Nur Sasongko
Abstract
The interaction of fatty acid of Morinda citrifolia L. (FAMC) with ink was studied using Hele Shaw Cells. The interaction is compared to that of fatty acid derivates of synthetic surfactant. These interactions are modeled and explained through micro diffusion and its viscous fingering character. The results show that the molecule structure and the number of double bonds have a special effect on the surface tension and the micro diffusion character. FAMC at six-hour extraction has the highest speed of interaction and highest perimeter of diffusion among synthetic surfactants and other fatty acids in Morinda citrifolia L.
Kurzfassung
Die Wechselwirkung von Fettsäure des Morinda citrifolia L. (FAMC) mit Tinte wurde in Hele-Shaw-Zellen untersucht. Die Wechselwirkung wird mit der des Fettsäurederivates des synthetischen Tensids verglichen. Diese Wechselwirkungen werden entwickelt und mit Mikrodiffusion und dessen „viscous fingering“-Charakter erklärt. Die Ergebnisse zeigen, dass die Molekülstruktur und die Anzahl der Doppelbindungen einen besonderen Effekt auf die Oberflächenspannung und den Mikrodiffusionscharakter haben. FAMC nach sechsstündiger Extraktion hat die höchste Geschwindigkeit der Wechselwirkung und den größten Diffusionsbereich unter den synthetischen Tensiden und anderen Fettsäuren in Morinda citrifolia L.
References
1. Khalek, M. A.: Performance of different surfactants in deinking flotation process. Elixir Appl. Chem.46 (2012) 8147–8151.Search in Google Scholar
2. Mayeli, N. and Talaeipour, M.: Effect of difference HLB value and enzymatic treatmenton the properties of old newspaper deinked pulp. Bioresources5 (4) (2010) 2520–2534. 10.15376/biores.5.4.2520-2534Search in Google Scholar
3. Paria, S. and Khilar, K. C.: A review on experimental studies of surfactant adsorption atthe hydrophilic solid-water interface. Advances Colloid and Interface Science, 110 (3) (2004) 75–95. 10.1016/j.cis.2004.03.001Search in Google Scholar PubMed
4. Theander, K.: Studies of Surfactant Behavior and Model Surfaces Relevant to Flotation Deinking. Doctoral Thesis, Royal Institute of Technology, Stockholm, 2006.Search in Google Scholar
5. Hannuksela, T. and Rosencrance, S.: Deinking Chemistry, Scientific Reports of Working Group Meetings, Kemira Germany GmbH and Kemira Chemicals Inc., unpublished (2008).Search in Google Scholar
6. Oftring, A., Kahmen, M., Ott, C., Oetter, G. and Baur, R.: Fatty acid derivatives and their use as surfactants in detergents and cleaners. Patent US 6204238 B1, 2001, assigned to BASF Aktiengesellschaft.Search in Google Scholar
7. Collins, J. H. and Murch, B. P.: Nonionic surfactant systems containing polyhydroxyfatty acid amides and one or more additional nonionic surfactants. Patent US, WO 1992006160 A1, 1992, assigned to The Procter and Gambler Company.Search in Google Scholar
8. Ophardt: Polarity of Organic Compound.VirtualChembook, Elmhurst College (2013).Search in Google Scholar
9. Saffman, P. G.: Viscous fingering in Hele-Shaw cells. J. Fluid Mech.173 (1986) 73–94. 10.1017/S0022112086001088Search in Google Scholar
10. Mullol, J. I. and Maher, J. V.: Experiments on Anisotropic radial viscous fingering. Physical Review E53 (4) (1996) 3788–3893. 10.1103/PhysRevE.53.3788Search in Google Scholar PubMed
11. Nagatsu, Y., Bae, S. K., Kato, Y. and Tada, Y.: Miscible viscous fingering with achemical reaction involving precipitation. Physical Review E.77 (6) (2008) 067302. PMid:18643403; 10.1103/PhysRevE.77.067302Search in Google Scholar PubMed
12. Nagatsu, Y., Iguchi, C., Matsuda, K., Kato, Y. and Tada, Y.: Miscible viscous fingeringinvolving viscosity changes of the displacing fluid by chemical reaction. Physics of Fluids22 (2010) 024101. 10.1063/1.3301244Search in Google Scholar
13. Azaiez, J. and Alhumade, H.: Reversible reactive flow displacements in homogeneousporous media. Proceedings of The World Congress on Engineering, 2010, 3,.1–6.Search in Google Scholar
14. Shahnazari, M. R., Eslami, F. and Rezazadeh, Sh.: Instability analysis of miscibledisplacements in homogeneous porous media.Iranian Journal of Chemical Engineering9 (4) (2012) 25–32.Search in Google Scholar
15. Maes, R., Rousseaux, G., Scheid, B., Mishra, M., Colinet, P. and De Wit, A.: Experimental study of dispersion and miscible viscous fingering of initially circular sample in Hele Shaw Cells. Physics of Fluids22 (12) (2010) 123104-1–123104-12. 10.1063/1.3528039Search in Google Scholar
16. Homsy, G. M.: Viscous fingering in porous media. Annual review of Fluid Mechanics, 19 (1987) 271–311. 10.1146/annurev.fl.19.010187.001415Search in Google Scholar
17. Davies, J. T.: A Quantitative Kinetics Theory of Emulsion Type I – Physical Chemistry of The Emulsifying Agent. Proceedings of 2nd. International Congress on Surface Activity, 1957, Butterworth London Academic, 426.Search in Google Scholar
18. Kovalchuk, N. M, Trybala, A., Starov, V., Matar, O. and Ivanova, N.: Fluoro- vs hydrocarbon surfactants: Why do they differ in wetting performance?, Advances in Colloid and Interface Science210 (2014), 65–71. PMid:24814169; 10.1016/j.cis.2014.04.003Search in Google Scholar PubMed
19. Karlkvist, T., Patra, A., Bordes, R., Holmberg, K. and Hanumantha, R. K.: Flotation Selectivity of Novel Alkyl Dicarboxylate Reagents for Calcite-Fluorite Separation, Tenside Surfactants Detergents53 (6) (2016) 516–523. 10.1021/la010625qSearch in Google Scholar
20. Kanicky, J. R., Paniatowski, A. F., Mehta, N. R. and Shah, D. O.: Cooperativity among Molecules at Interfaces in Relation to Various Technological Processes: Effect of Chain Length on the pKa of Fatty Acid Salts Solutions, Langmuir16 (1) (2000) 172–177. 10.1021/la990719o.Search in Google Scholar
21. Saffman, P. G. and Taylor, G.: The penetration of a fluid into a porous medium or Hele-Shawcell containing a more viscous liquid, Proc. R. Soc. London. A245 (1958) 312–329. 10.1098/rspa.1958.0085Search in Google Scholar
22. Mclean, J. W. and Saffman, P. G.: The effect of surface tension on the shapeof fingers in a Hele Shaw cell, J. Fluid Mech102 (1981) 466–469. 10.1017/S0022112081002735Search in Google Scholar
23. Szymezyk, K.: The properties of binary mixture of ethoxylated octhyl phenol with ethoxylated fluorinated alkanols at the water – air interface, Journal Surfactants and Detergents vol.14 (3) (2011) 415–423. 10.1007/s11743-011-1246-7Search in Google Scholar
© 2017, Carl Hanser Publisher, Munich
Articles in the same Issue
- Contents/Inhalt
- Contents
- Detergents/Cleaning
- Application of Glycerin in Liquid Laundry Detergents as an Example of Innovation in the Household Chemicals Industry
- Application
- Characterization of Pyrene Solubilization in Selective Micellar Media of Novel Bio-degradable Natural Surfactant Saponin (Extracted from Soap Nut) and Conventional Surfactant SDBS in Presence and Absence of Common Salt NaCl
- The Effect of pH on the Properties of a Cationic Bitumen Emulsifier
- The Role of Fatty Acids Functional Group in Morinda citrifolia L. on Surface Tension and Diffusion Performance into Ink Particles
- Physical Chemistry
- Effect of Some Vitamins of Group B (B1, B6, B12) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions
- Phase Behavior and Solubilization of Microemulsions Containing C16mimBr with Different Oil-Water Ratios
- Thermodynamics of Micellization, Interfacial Behavior and Wettability Alteration of Aqueous Solution of Nonionic Surfactants
- Novel Surfactants
- Synthesis and Properties of a Novel Gemini Surfactant with Bis-piperidinium
- Surface Activities and Quantum Chemical Calculations for Different Synthesized Cationic Gemini Surfactants
- Effect of Novel Surfactant on the Growth Kinetics of Cobalt Nanoparticles
Articles in the same Issue
- Contents/Inhalt
- Contents
- Detergents/Cleaning
- Application of Glycerin in Liquid Laundry Detergents as an Example of Innovation in the Household Chemicals Industry
- Application
- Characterization of Pyrene Solubilization in Selective Micellar Media of Novel Bio-degradable Natural Surfactant Saponin (Extracted from Soap Nut) and Conventional Surfactant SDBS in Presence and Absence of Common Salt NaCl
- The Effect of pH on the Properties of a Cationic Bitumen Emulsifier
- The Role of Fatty Acids Functional Group in Morinda citrifolia L. on Surface Tension and Diffusion Performance into Ink Particles
- Physical Chemistry
- Effect of Some Vitamins of Group B (B1, B6, B12) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions
- Phase Behavior and Solubilization of Microemulsions Containing C16mimBr with Different Oil-Water Ratios
- Thermodynamics of Micellization, Interfacial Behavior and Wettability Alteration of Aqueous Solution of Nonionic Surfactants
- Novel Surfactants
- Synthesis and Properties of a Novel Gemini Surfactant with Bis-piperidinium
- Surface Activities and Quantum Chemical Calculations for Different Synthesized Cationic Gemini Surfactants
- Effect of Novel Surfactant on the Growth Kinetics of Cobalt Nanoparticles