Effect of Some Vitamins of Group B (B1, B6, B12) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions

Lusine R. Harutyunyan; Martina L. Lachinyan; Romik S. Harutyunyan

doi:10.3139/113.110513

Artikel

Effect of Some Vitamins of Group B (B₁, B₆, B₁₂) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions

Lusine R. Harutyunyan , Martina L. Lachinyan und Romik S. Harutyunyan

Veröffentlicht/Copyright: 6. September 2017

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Aus der Zeitschrift Tenside Surfactants Detergents Band 54 Heft 5

Abstract

The influence of vitamins B₁ (thiamine hydrochloride), B₆ (pyridoxine) and B₁₂ (cyanocobalamine) on the micellization, surface activity and viscometric behavior of anionic surfactant sodium dodecylsulfate, cationic surfactant cetylpyridinium bromide and nonionic surfactant hexadecylpoly[oxyethylene(20)] alcohol at different temperatures was studied. The critical micelle concentration, the micellization thermodynamics, the maximum adsorption density, the standard free energy of adsorption and the other micellar parameters of surfactants in the presence of vitamins B₁, B₆ and B₁₂ were obtained. On the basis of dependence of the relative viscosities on concentration, the viscosity B-coefficients of the Jones-Dole semiempirical equation were calculated for both premicellar and postmicellar regions. The results of our study allowed the conclusion that vitamins B₁, B₆ and B₁₂ are solubilized in micelles.

Kurzfassung

Der Einfluss der Vitamine B₁ (Thiaminhydrochlorid), B₆ (Pyridoxin) und B₁₂ (Cyanocobalamin) auf die Mizellenbildung, die Oberflächenaktivität und das viskose Verhalten des anionischen Tensids Natriumdodecylsulfat, des kationischen Tensids Cetylpyridiniumbromid und des nichtionischen Tensids Hexadecylpoly(oxyethylen (20))alkohol wurde bei verschiedenen Temperaturen untersucht. Die kritische Mizellenbildungskonzentration, die Thermodynamik der Mizellenbildung, die maximale Adsorptionsdichte, die freie Gibbs-Adsorptionsenergie und die anderen mizellaren Parameter von Tensiden wurden in Gegenwart der Vitamine B₁, B₆ und B₁₂ erhalten. Auf der Grundlage der Abhängigkeit der relativen Viskositäten von der Konzentration wurden die Viskositätskoeffizienten der semiempirischen Jones-Dole- Gleichung sowohl für den prämmizellaren als auch für den postmizellaren Bereich berechnet. Die Ergebnisse unserer Studie erlaubten den Schluss, dass die Vitamine B₁, B₆ und B₁₂ in Micellen solubilisiert sind.

Key words: Vitamins of group B; surfactant; micellization; surface activity; Jones-Dole equation

Stichwörter: Vitamine der B-Gruppe; Tenside; Mizellenbildung; Oberflächenaktivität; Jones-Dole-Gleichung

*Correspondence address, Mrs. Dr. Lusine R. Harutyunyan, Department of Chemistry, Yerevan State University, Manukyan 1, 0025 Yerevan, Armenia, Tel.: (+374)93519144, E-Mail: lusinehar@ysu.am

Lusine R. Harutyunyan earned her M. Sc. and Ph. D. degree from Yerevan State University, Armenia. Now she is an Associate Professor in the Chair of Inorganic and Analytical Chemistry, Faculty of Pharmacy and Chemistry, Yerevan State University, Armenia. Her research fields are colloid chemistry, chemistry of surfactant solutions, and purification of water from surfactants.

Martina L. Lachinyan earned her M. Sc. and Ph. D. degree from Yerevan State University, Armenia. She is researcher in Department of Chemistry in Yerevan State University.

Prof. Romik S. Harutyunyan is Head of Chair of Inorganic and Analytical Chemistry, Faculty of Pharmacy and Chemistry, Yerevan State University, Armenia. His main areas of research include the physico-chemical properties of surfactant solutions, micellar catalysis, synthesis and properties of surfactant-modified sorbents.

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Received: 2017-01-27

Accepted: 2017-04-17

Published Online: 2017-09-06

Published in Print: 2017-09-15

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Artikel in diesem Heft

https://doi.org/10.3139/113.110513

Schlagwörter für diesen Artikel

Vitamins of group B; surfactant; micellization; surface activity; Jones-Dole equation