Home Enthalpic analysis of the CaTiSiO5 system
Article
Licensed
Unlicensed Requires Authentication

Enthalpic analysis of the CaTiSiO5 system

  • I. Nerád EMAIL logo , L. Kosa , E. Mikšíková and K. Adamkovičová
Published/Copyright: August 1, 2006
Become an author with De Gruyter Brill
Author Information
Chemical Papers
From the journal Chemical Papers Volume 60 Issue 4

Abstract

The relative enthalpy of titanite and enthalpy of CaTiSiO5 melt have been measured using drop calorimetry between 823 K and 1843 K. Enthalpies of solution of titanite and CaTiSiO5 glass have been measured by the use of hydrofluoric acid solution calorimetry at 298 K. Enthalpy of vitrification at 298 K, δvitr H(298 K) = (80.7 ± 3.4) kJ mol−1, and enthalpy of fusion at the temperature of fusion 1656 K, δfus H(1656 K) = (139 ± 3) kJ mol−1, of titanite have been determined from experimental data. The obtained enthalpy of fusion is considerably higher than up to the present published values of this quantity.

[1] Speer, J. A. and Gibbs, G. V., Am. Mineral. 61, 238 (1976). Search in Google Scholar

[2] Kroeker, S., Rice, D., and Stebbins, J. F., Am. Mineral. 87, 572 (2002). Search in Google Scholar

[3] Mysen, B. O., Ryerson, E. J., and Virgo, D., Am. Mineral. 65, 1150 (1980). Search in Google Scholar

[4] Dingwell, D. B., Geochim. Cosmochim. Acta 56, 3403 (1992). http://dx.doi.org/10.1016/0016-7037(92)90387-X10.1016/0016-7037(92)90387-XSearch in Google Scholar

[5] Dingwell, D. B., Am. Mineral. 77, 270 (1992). Search in Google Scholar

[6] Webb, S. L. and Dingwell, D. B., Contrib. Mineral. Petrol. 118, 157 (1994). http://dx.doi.org/10.1007/BF0105286610.1007/BF01052866Search in Google Scholar

[7] Farges, F., Brown, E. G., Navrotsky, A., Gan, H., and Rehr, J. R., Geochim. Cosmochim. Acta 60, 3055 (1996). http://dx.doi.org/10.1016/0016-7037(96)00146-910.1016/0016-7037(96)00146-9Search in Google Scholar

[8] Bouhifd, M. A., Sipp, A., and Richet, P., Geochim. Cosmochim. Acta 63, 2429 (1999). http://dx.doi.org/10.1016/S0016-7037(99)00145-310.1016/S0016-7037(99)00145-3Search in Google Scholar

[9] Vance, E. R. and Agraval, D. K., Nucl. Chem. Waste Man. 3, 229 (1982). http://dx.doi.org/10.1016/0191-815X(82)90004-310.1016/0191-815X(82)90004-3Search in Google Scholar

[10] Donald, I. W., Metcalfe, B. L., and Taylor, R. N. J., J. Mater. Sci. 32, 5851 (1997). http://dx.doi.org/10.1023/A:101864650743810.1023/A:1018646507438Search in Google Scholar

[11] King, E. G., Orr, R. L., and Bonnickson, K. R., J. Am. Chem. Soc. 76, 4320 (1954). http://dx.doi.org/10.1021/ja01646a02110.1021/ja01646a021Search in Google Scholar

[12] Berman, R. G., J. Petrol. 29, 445 (1988). Search in Google Scholar

[13] Holland, T. J. B. and Powell, R., J. Metamorph. Geol. 8, 89 (1990). http://dx.doi.org/10.1111/j.1525-1314.1990.tb00458.x10.1111/j.1525-1314.1990.tb00458.xSearch in Google Scholar

[14] Robie, R. A. and Hemmingway, B. S., Geol. Soc. Bull. 1995, 2131. Search in Google Scholar

[15] Xirouchakis, D., Fritsch, S., Putnam, R. L., Navrotsky, A., and Lindsley, D. H., Am. Mineral. 82, 754 (1997). Search in Google Scholar

[16] Xirouchakis, D. and Lindsley, D. H., Am. Mineral. 83, 712 (1998). Search in Google Scholar

[17] Tangeman, J. and Xirouchakis, D., Phys. Chem. Miner. 28, 167 (2001). http://dx.doi.org/10.1007/s00269000012410.1007/s002690000124Search in Google Scholar

[18] Thiéblot, L., Téqui, C., and Richet, P., Am. Mineral. 84, 848 (1999). Search in Google Scholar

[19] Proks, I., Eliášová, M., Zlatovský, I., and Záuška, J., Silikáty 21, 253 (1977). Search in Google Scholar

[20] Zlatovský, I., Silikáty 21, 71 (1977). 10.1016/0083-6656(77)90004-6Search in Google Scholar

[21] Xirouchakis, D., Kunz, M., Parise, J. B., and Lindsley, D. H., Am. Mineral. 82, 748 (1997). Search in Google Scholar

Published Online: 2006-8-1
Published in Print: 2006-8-1

© 2006 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

  1. Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
  6. Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
  7. Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
  8. Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
  9. Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
  10. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
  14. Electrical conductivity of the molten KF—K2TaF7 system
  15. New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
https://doi.org/10.2478/s11696-006-0047-3

Articles in the same Issue

  1. Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
  6. Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
  7. Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
  8. Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
  9. Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
  10. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
  14. Electrical conductivity of the molten KF—K2TaF7 system
  15. New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 27.11.2025 from https://www.degruyterbrill.com/document/doi/10.2478/s11696-006-0047-3/html
Scroll to top button