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One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones

  • H. Tavakol EMAIL logo and S. Zakery
Published/Copyright: August 1, 2006
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Chemical Papers
From the journal Chemical Papers Volume 60 Issue 4

Abstract

Various imines and hydrazones were reduced to the corresponding amines and hydrazines using borane-tetrahydrofuran complex as a reducing agent in the solution of lithium perchlorate in diethyl ether. The initial imines or hydrazones have been prepared at the same conditions just before the reduction step. Both steps were carried out in one vessel with a good yield and insignificant formation of by-products.

Keywords: one-pot synthesis; secondary amines; trisubstituted hydrazines; reductive amination; ketones

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Published Online: 2006-8-1
Published in Print: 2006-8-1

© 2006 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

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  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
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  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
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https://doi.org/10.2478/s11696-006-0056-2
Keywords for this article
one-pot synthesis; secondary amines; trisubstituted hydrazines; reductive amination; ketones

Articles in the same Issue

  1. Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
  6. Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
  7. Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
  8. Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
  9. Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
  10. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
  14. Electrical conductivity of the molten KF—K2TaF7 system
  15. New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
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