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Preparation of Oxidized Starch Using Environment Friendly Chlorine Dioxide as Oxidant

  • Jintang Guo EMAIL logo , Yancui Huang , Jin Zhang and Junwei Yin
Published/Copyright: May 17, 2014

Abstract

In the present work, the oxidized corn starch was prepared by using chlorine dioxide as novel oxidant. It was characterized by X-ray diffraction, scanning electron microscope (SEM), and transmission electron microscope (TEM). The main factors that affect the oxidation process were studied, and the oxidation degree of oxidized starch was determined by the carboxyl content and viscosity of the product. The results show that carboxyl groups are introduced into the starch chains successfully, and the oxidation reaction mainly carries out at the amorphous area. Compared with native starch, the light transmittance and anti-retrogradation of oxidized starch increase, whereas the viscosity reduces. The best oxidized starch can be obtained at the sodium chlorate dosage of 3%, hydrochloric acid 4%, and sulfuric acid 3% (all based on the initial starch weight), while the oxidation reaction is conducted at 50°C for 5 h.

Acknowledgements

The work in this paper was supported by the Program of Introducing Talents Discipline to Universities (B06006), and we are thankful for that.

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Published Online: 2014-5-17
Published in Print: 2014-6-1

©2014 by Walter de Gruyter Berlin / Boston

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