Startseite Preparation and Characterization of PES and PA Composite Membranes for Air Separation at Low Pressures
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Preparation and Characterization of PES and PA Composite Membranes for Air Separation at Low Pressures

  • S. S. Madaeni , M. Esmaeili , S. Attar Nosrati und J. Barzin
Veröffentlicht/Copyright: 9. September 2013
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In this study poly(ether sulphone) (PES) asymmetric membranes and Polyamide (PA) composite membranes were used for gas separation at low pressures. The effect of PES concentration, contact time of sebacoyldichloride, addition of 1,6-hexaethylene diamine solution and PA active layer on the structures of PES support layer were studied. Changing the structure of PES membrane from channel-like to sponge form increased the selectivity in the gas separation process. However, this structural variation caused a considerable decline in gas permeability. The characteristics of top layer depend on the porosity and compactness of sub-layers structure. Active layer formation on the surface of support structure at PES concentrations of more than 25 %wt improved the oxygen selectivity considerably. The optimum conditions for preparation of PA active layer through interfacial polymerization process were elucidated in this paper. The PA composite membrane prepared at the PES concentration of 25 wt% and monomer concentration of 1 wt% provided the highest selectivity for oxygen enrichment process.


4 Mail address: Sayed S. Madaeni, Membrane Research Center, Chemical Engineering Department, Razi University, Kermanshah, Iran. E-mail:

References

BakerR. W.: Membrane Technology and Applications, John Wiley, New York (2004)10.1002/0470020393Suche in Google Scholar

BarzinJ., MadaeniS. S., MirzadehH., MehrabzadehM., “Effect of Polyvinylpyrrolidone on Morphology and Performance of Hemodialyssis Membranes Prepared from Polyethersulfone”, J. Appl. Polym. Sci., 92, 38043813(2004a)10.1002/app.20395Suche in Google Scholar

BarzinJ., FengC., KhulbeK. C., MatsuuraT., MadaeniS. S., MirzadehH., “Characterization of Polyethersulfone Hemodialysis Membrane by Ultrafiltration and Atomic Force Microscopy”, J. Membr. Sci., 237, 7785 (2004b)10.1016/j.memsci.2004.02.029Suche in Google Scholar

BarzinJ., MadaeniS.S., MirzadehH., “Effect of Preparation Conditions on Morphology and Performance of Hemodialysis Membranes Prepared from Polyethersulfone (PES) and Polyvinylpyrrolidone (PVP)”, I. P. J., 14, 353360 (2005)Suche in Google Scholar

BelferS., PurinsonY., FainshteinR., RadchenkoY., KedemO., “Surface Modification of Commercial Composite Polyamide Reverse Osmosis Membranes”, J. Membr. Sci., 139, 175181 (1998)10.1016/S0376-7388(97)00248-2Suche in Google Scholar

BequetS., AbenozaT., AptelP., EspenanJ. M., RemigyJ. C., RicardA., “New Composite Membrane for Water Softening”, J. Desal., 131, 299305 (2000)Suche in Google Scholar

BoussuK., VandecasteeleC., Van Der BruggenB., “Study of the Characteristics and the Performance of Self-made Nonporous Polyethersulfone Membranes”, Polym. J., 47, 34643476 (2006)10.1016/j.polymer.2006.03.048Suche in Google Scholar

ChungT. S., TeohS. K., HuX., “Formation of Ultrathin High-performance Polyethersulfone Hollow-fiber Membranes, J. Membr. Sci., 133, 161175 (1997)10.1016/S0376-7388(97)00101-4Suche in Google Scholar

ChungT. S., ShiehaJ. J., LauW. W. Y., SrinivasanaM. P., PaulD. R., “Fabrication of Multi-layer Composite Hollow Fiber Membranes for Gas Separation”, J. Membr. Sci., 152, 211225 (1999a)10.1016/S0376-7388(98)00225-7Suche in Google Scholar

ChungT. S., TeohS. K., “The Ageing Phenomenon of Polyethersulphone Hollow Fiber Membranes for Gas Separation and Their Characteristics”, J. Membr. Sci., 152, 175188 (1999b)10.1016/S0376-7388(98)00224-5Suche in Google Scholar

ClausiD. T., MckelveyS. A., KorosW. J., “Characterization of Substructure Resistance in Asymmetric Gas Separation Membranes”, J. Membr. Sci., 160, 5164 (1999)10.1016/S0376-7388(99)00078-2Suche in Google Scholar

FengX., IvoryJ., RajanV. S. V., “Air Separation by Integrally Asymmetric Hollow-fiber Membranes”, AIChE J., 45, 21422152 (1999)10.1002/aic.690451013Suche in Google Scholar

FengX., ShaoP., HuangR. Y. M., JiangG., XuR. X., “A Study of Silicone Rubber/Polysulfone Composite Membranes: Correlating H2/N2 and O2/N2 Permselectivities”, J. Sep. Pur. Tech. Technol., 27, 211223 (2002)10.1016/S1383-5866(01)00196-4Suche in Google Scholar

FuertesA. B., “Adsorption-selective Carbon Membrane for Gas Separation”, J. Membr. Sci., 177, 916 (2000)10.1016/S0376-7388(00)00458-0Suche in Google Scholar

HamzaA., ChowdhuryG., MatsuuraT., SourirajanS., “Sulphonated Poly(2, 6-dimethyl-1,4-phenylene oxide)-Polyethersulphone Composite Membranes. Effects of Composition of Solvent System, Used for Preparing Casting Solution, on Membrane-surface Structure and Reverse-osmosis Performance”, J. Membr. Sci., 129, 5564 (1997)10.1016/S0376-7388(96)00331-6Suche in Google Scholar

HeT., MulderM. H. V., StrathmannH., WesslingM., “Preparation of Composite Hollow Fiber Membranes: Co-Extrusion of Hydrophilic Coatings onto Porous Hydrophobic Support Structures”, J. Membr. Sci., 207, 143156 (2002)10.1016/S0376-7388(02)00118-7Suche in Google Scholar

HongJ. J., YangJ. K., HanJ. R., U.S. Patent 6732020 (2002)Suche in Google Scholar

HuC. C., ChangC. S., RuaanR. C., LaiJ. Y., “Effect of Free Volume and Sorption on Membrane Gas Transport”, J. Membr. Sci., 226, 5156 (2003)10.1016/j.memsci.2003.07.010Suche in Google Scholar

IsmailA. F., DavidL. I. B., “A Review on the Latest Development of Carbon Membranes for Gas Separation”, J. Membr. Sci., 193, 118 (2001)10.1016/S0376-7388(01)00510-5Suche in Google Scholar

JiangL., ChungT. S., LiD. F., CaoC., KulprathipanjaS., “Fabrication of Matrimid/Polyethersulfone Dual-layer Hollow Fiber Membranes for Gas Separation”, J. Membr. Sci., 240, 91103 (2004)10.1016/j.memsci.2004.04.015Suche in Google Scholar

KawataI., OkamotoT., AkasuH., KomatsuK., U. S. Patent 5340480 (1994)Suche in Google Scholar

KimH. J., Tabe-MohammadiA., KumarA., FoudaA. E., “Asymmetric Membranes by A Two-stage Gelation Technique for Gas Separation: Formation and Characterization”, J. Membr. Sci., 161, 229238 (1999)10.1016/S0376-7388(99)00115-5Suche in Google Scholar

LiY., CaoC., ChungT. S., PramodaK. P., “Fabrication of Dual-layer Polyethersulfone (PES) Hollow Fiber Membranes with An Ultra Thin Dense-selective Layer For Gas Separation”, J. Membr. Sci., 245, 5360 (2004)10.1016/j.memsci.2004.08.002Suche in Google Scholar

MadaeniS. S., RahimpourA., BarzinJ., “Preparation of Polysulfone Ultrafiltration Membranes For Milk Concentration: Effect of Additives on Morphology and Performance”, I. P. J., 14, 421428 (2005)Suche in Google Scholar

MadaeniS. S., EsmaeiliM., BarzinJ., “Preparation and Optimization of Polyethersulfone-based Composite Membranes for Air Separation at Low Pressures”, J. Poly & Poly Comp., 15, 579589 (2007)Suche in Google Scholar

RichardsonJ. F., HarkerJ. H., BackhurstJ. R.: Coulson and Richardson’s Chemical Engineering, Butterworth-Heinemann, Volume 2, Oxford (2002)12643157Suche in Google Scholar

Ruiz-TrevinoF. A., PaulD. R., “Modification of Polysulfone Gas Separation Membranes by Additives”, J. Appl. Polym. Sci., 66, 19251941 (1997)10.1002/(SICI)1097-4628(19971205)66:10<1925::AID-APP9>3.0.CO;2-PSuche in Google Scholar

ScottK.: Handbook of Industrial Membranes, Part 4Elsevier Advanced, New York (1995)Suche in Google Scholar

Singh-GhosalA., KorosW. J., “Air Separation Properties of Flat Sheet Homogeneous Pyrolytic Carbon Membranes”, J. Membr. Sci., 174, 177188 (2000)10.1016/S0376-7388(00)00392-6 Suche in Google Scholar

SinghP. S., JoshiS. V., TrivediJ. J., DevmurariC. V., Prakash RaoA., GhoshP. K., “Probing the Structural Variations of Thin Film Composite RO Membranes Obtained by Coating Polyamide over Polysulfone Membranes of Different Pore Dimensions”, J. Membr. Sci., 278, 1925 (2005)10.1016/j.memsci.2005.10.039Suche in Google Scholar

ToshimaN.: Polymers for Gas Separation, VCH Publication, New York (1992)Suche in Google Scholar

TsuchidaE., NishidaH., KawakamiH., SesameY., U.S. Patent 5411580 (1995)Suche in Google Scholar

TsujitaY., “Gas Sorption and Permeation of Glassy Polymers with Microvoids”, J. Prog. Polym. Sci., 28, 13771401 (2003)10.1016/S0079-6700(03)00048-0Suche in Google Scholar

WeiJ., JianX., WuC., ZhangS., YanC., “Influence of Polymer Structure on Thermal Stability of Composite Membranes”, J. Membr. Sci., 256, 116121 (2005)Suche in Google Scholar

WangD., TeoW. K., LiK., “Preparation and Characterization of High-Flux Polysulfone Hollow Fiber Gas Separation Membranes”, J. Membr. Sci., 204, 247256 (2002)10.1016/S0376-7388(02)00047-9Suche in Google Scholar

WinstonW. S., SirkarK.: Membrane Handbook, Part 2, Chapman and Hall, London (1999)Suche in Google Scholar

YongZ., SanchuanY., MeihongL., CongjieG., “Polyamide Thin Film Composite Membrane Prepared from m-Phenylenediamine and m-Phenylenediamine-5-Sulfonic Acid”, J. Membr. Sci., 270, 162168 (2005)10.1016/j.memsci.2005.06.053Suche in Google Scholar

ZhangR. X., VannesteJ., PoelmansL., SottoA., WangX. L., Van Der BruggenB., “Effect of the Manufacturing Conditions on the Structure and Performance of Thin-film Composite Membranes”, J. Appl. Polym. Sci., 125, 37553769 (2012)10.1002/app.36542Suche in Google Scholar

Received: 2012-11-8
Accepted: 2013-12-2
Published Online: 2013-09-09
Published in Print: 2013-07-01

© 2013, Carl Hanser Verlag, Munich

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