Startseite Effect of Compatibilizer Distribution on Thermal and Rheological Properties of Gelatinized Starch/Biodegradable Polyesters Blends
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Effect of Compatibilizer Distribution on Thermal and Rheological Properties of Gelatinized Starch/Biodegradable Polyesters Blends

  • F. Xie , L. Yu , H. Liu und K. Dean
Veröffentlicht/Copyright: 26. März 2013
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 21 Heft 4

Abstract

Thermal and rheological properties of various blends of gelatinized starch and biodegradable polyester, polycaprolactone (PCL) or poly(butylene succinate adipate) (PBSA), were studied by DSC, TGA and rheometry. Methylenediphenyl diisocyanate (MDI) was used as a compatibilizer and was distributed in different phases through controlled processing. The addition of MDI showed a stronger effect on thermal and rheological properties when it was mainly distributed in the polyester phase prior to blending. Starch was shown to increase the shear viscosity of both types of polyesters. The two blends, starch/PCL and starch/PBSA, showed a similar pattern of a power law dependence of viscosity on shear rate. MDI was shown to enhance the effect of starch on the melting and decomposition temperatures, especially when distributed in the polyester phase.

∗ Mail address: L. Yu, Commonwealth Scientific and Industrial Research Organization, CMIT, Gate 4, Normanby Rd, Clayton, Melbourne, Australia. E-mail:

References

1Koenig, M. F., Huang, S. J.: Polym. Mater. Sci. Eng. 67, p. 290 (1992)Suche in Google Scholar

2Koenig, M. F., Huang, S. J.: Polym. Mater. Sci. Eng. 36, p. 1877 (1995)Suche in Google Scholar

3Huang, S. J., Koening, M., Huang, M., in: Ching, C. et al. (Eds.), Biodegradable Polymers and Packaging, Technomic, Basel (1993)10.1016/0306-3747(93)90255-CSuche in Google Scholar

4Narayan, R., Krishnan, M.: Polym. Mater. Sci. Eng. 72, p. 186 (1995)Suche in Google Scholar

5Bastioli, C., Cerrutti, A., Guanella, I., Romano, G. C., Tosin, M.: J. Env. Polym. Deg. 3, p. 81 (1995)10.1007/BF02067484Suche in Google Scholar

6Pranamuda, H., Tokiwa, Y., Tanaka, H.: J. Env. Polym. Deg. 4, p. 1 (1996)10.1007/BF02083877Suche in Google Scholar

7Shin, B. Y., Lee, S., Shin, Y. S., Balakrishnan, S., Narayan, R.: Polym. Eng. Sci. 44, p. 1429 (2004)10.1002/pen.20139Suche in Google Scholar

8Iwamoto, A., Tokiwa, Y.: Polym. Degrad. Stabil. 45, p. 205 (1994)10.1016/0141-3910(94)90138-4Suche in Google Scholar

9Averous, L., Moro, L., Dole, P., Fringant, C.: Polymer41, p. 4157 (2000)10.1016/S0032-3861(99)00636-9Suche in Google Scholar

10Ke, T., Sun, X.: J. Appl. Polym. Sci. 81, p. 3069 (2001)10.1002/app.1758Suche in Google Scholar

11Ke, T., Sun, X.: J. Appl. Polym. Sci. 89, p. 1203 (2003)10.1002/app.12162Suche in Google Scholar

12Ke, T., Sun, X.: J. Appl. Polym. Sci. 89, p. 3639 (2003)10.1002/app.12617Suche in Google Scholar

13Park, J. W., Im, S. S.: Polym Eng Sci. 40, p. 2539 (2000)10.1002/pen.11384Suche in Google Scholar

14Martin, O., Averous, L.: Polymer42, p. 6209 (2001)10.1016/S0032-3861(01)00086-6Suche in Google Scholar

15Willett, J. L., Shogren, R. L.: Polymer43, p. 5935 (2002)10.1016/S0032-3861(02)00497-4Suche in Google Scholar

16Zhang, L., Den, X., Zhao, S., Huang, Z.: Polymer Int. 44, p. 104 (1997)10.1002/(SICI)1097-0126(199709)44:1<104::AID-PI812>3.0.CO;2-#Suche in Google Scholar

17Willett, J. L, Kotnis, M. A., O'Brien, G. S., Fanta, G. F., Gordon, S. H.: J. Appl. Polym. Sci. 70, p. 1121 (1988)10.1002/(SICI)1097-4628(19981107)70:6<1121::AID-APP8>3.0.CO;2-QSuche in Google Scholar

18Wang, H., Sun, X., Seib, P.: J. Appl. Polym. Sci. 82, p. 1761 (2001)10.1002/app.2018Suche in Google Scholar

19Wang, H., Sun, X., Seib, P.: J. Appl. Polym. Sci. 84, p. 1257 (2002)10.1002/app.10457Suche in Google Scholar

20Wang, H., Sun, X., Seib, P.: J. Polym. Enviro10, p. 133 (2002)10.1023/A:1021139903549Suche in Google Scholar

21Wang, H., Sun, X., Seib, P.: J. Appl. Polym. Sci. 90, p. 3683 (2003)10.1002/app.13001Suche in Google Scholar

22Kweon, D., Cha, D., Park, H., Lim, S.: J. Appl. Polym. Sci. 78, p. 986 (2000)10.1002/1097-4628(20001031)78:5<986::AID-APP70>3.0.CO;2-TSuche in Google Scholar

23Yu, L., Dean, K., Yuang, Q., Xie, F., Liu, H.: Effect of Compatibilizer Distribution on the Mechanical Properties of Starch/Biodegradable Polyesters Blends, to be publishedSuche in Google Scholar

24Grigat, E., in: Oertel, G. (Ed.), Polyurethane Handbook, Hanser, Munich, New York (1985)Suche in Google Scholar

25Hizykuri, S., in: Eliasson, A. (Ed.), Carbohydrates in Food, Marcel Dekker, New York (1996)Suche in Google Scholar

26Yokota, Y., Ishioka, R., Moteki, Y., Watanbe, N.: Biodegradable Plastics and Polymer, p. 577 (1994)10.1016/B978-0-444-81708-2.50068-3Suche in Google Scholar

Received: 2005-9-26
Accepted: 2006-3-14
Published Online: 2013-03-26
Published in Print: 2006-09-01

© 2006, Hanser Publishers, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. A Study of Integration of LIGA and M-EDM Technology on the Micro Injection Molding of Super Thin Plates with Micro Through Holes
  5. Carbon Black Filled Polyester as Electrically Conductive Master Batch for Fibers
  6. Tip-clearance Effect on Mixing Performance of Twin Screw Extruders
  7. Structure Development in Melt Spinning and Cold Drawing of Poly(ethylene-co-octene) Copolymer
  8. Effect of Distributor Geometry on Crimp Contraction of PET Side-by-side Bicomponent Fibers
  9. Effect of Compatibilizer Distribution on Thermal and Rheological Properties of Gelatinized Starch/Biodegradable Polyesters Blends
  10. Numerical Simulation of the Effect of Processing Parameters on the Flow Behavior and Break-through Phenomenon in Co-Injection Molding
  11. Study of Shrinkage and Warpage in Microcellular Co-Injection Molding
  12. Melting Temperature Characteristics for Polyethylenes from Crystal Size Distribution
  13. Experimental/Numerical Analysis of Chaotic Advection in a Three-dimensional Cavity Flow
  14. A Numerical Investigation on the Cure Cycle of Composite Brake Blocks
  15. PPS News
  16. PPS News
  17. Seikei-Kakou Abstracts
  18. Seikei-Kakou Abstracts
https://doi.org/10.3139/217.0119

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. A Study of Integration of LIGA and M-EDM Technology on the Micro Injection Molding of Super Thin Plates with Micro Through Holes
  5. Carbon Black Filled Polyester as Electrically Conductive Master Batch for Fibers
  6. Tip-clearance Effect on Mixing Performance of Twin Screw Extruders
  7. Structure Development in Melt Spinning and Cold Drawing of Poly(ethylene-co-octene) Copolymer
  8. Effect of Distributor Geometry on Crimp Contraction of PET Side-by-side Bicomponent Fibers
  9. Effect of Compatibilizer Distribution on Thermal and Rheological Properties of Gelatinized Starch/Biodegradable Polyesters Blends
  10. Numerical Simulation of the Effect of Processing Parameters on the Flow Behavior and Break-through Phenomenon in Co-Injection Molding
  11. Study of Shrinkage and Warpage in Microcellular Co-Injection Molding
  12. Melting Temperature Characteristics for Polyethylenes from Crystal Size Distribution
  13. Experimental/Numerical Analysis of Chaotic Advection in a Three-dimensional Cavity Flow
  14. A Numerical Investigation on the Cure Cycle of Composite Brake Blocks
  15. PPS News
  16. PPS News
  17. Seikei-Kakou Abstracts
  18. Seikei-Kakou Abstracts
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 31.10.2025 von https://www.degruyterbrill.com/document/doi/10.3139/217.0119/html
Button zum nach oben scrollen