Startseite Effect of in-situ formation of AlP on solidification of hypereutectic Al–Si alloy
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Effect of in-situ formation of AlP on solidification of hypereutectic Al–Si alloy

  • Shuying Chen , Lei Zhang , Xudong Yue und Guowei Chang
Veröffentlicht/Copyright: 23. Oktober 2019
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

The effects of in-situ AlP formation on the solidification process of an Al-20 %Si alloy were studied by examining the change law of the solidification microstructures after the addition of Cu–P alloy to the melt and stirring. During the early stage of stirring, the eutectic Si was clearly refined and Si mainly existed in a point-like shape. During the middle stage of stirring, the typical eutectic microstructure disappeared, and the microstructure consisted of fine primary Si uniformly distributed in the α matrix. Many AlP precipitates with sizes near the critical nucleation radius of primary Si were formed after the Cu–P alloy was dissolved in the Al-20 %Si alloy and stirred. These AlP precipitates became the nuclei of the primary and eutectic Si. The Si-poor layers around the primary Si provided the conditions necessary for the precipitation of the primary α phases when the primary Si grew. For finer primary Si, the distance between the primary Si was reduced, and lower temperature facilitated the formation of a complete α loop or continuous α phases around the primary Si. During the eutectic reaction, the ultrafine AlP caused the eutectic Si phases to nucleate alone and grow; the eutectic α phases grew based on the primary α phases, which resulted in the formation of divorced eutectic microstructures.


Correspondence address, Professor Shuying Chen, School of Materials Science and Engineering, Liaoning University of Technology, Shiying Street, Jinzhou, 121001, P. R. China, Tel: +86-0416-4199650, Fax: +86-0416-4198809, E-mail:

References

[1] M.Zuo, X.F.Liu: J. Inorg. Organomet. Polym.22 (2012) 64. 10.1007/s10904-011-9516-4Suche in Google Scholar

[2] Q.L.Wang, H.R.Geng, M.Zuo, F.Long, X.Peng: Sci. Technol.29 (2013) 1233. 10.1179/1743284713Y.0000000267Suche in Google Scholar

[3] A.Q.Wang, L.J.Zhang, J.P.Xie: J. Rare Earths31 (2013) 522. 10.1016/S1002-0721(12)60313-5Suche in Google Scholar

[4] W.W.Ding, T.D.Xia, W.J.Zhao: Materials.7 (2014) 1188. 28788509 10.3390/ma7021188Suche in Google Scholar PubMed PubMed Central

[5] T.H.Ludwig, P.L.Schaffer, L.Arnberg: Metall. Mater. Trans.A 44 (2013) 5796. 10.1007/s11661-013-1945-ySuche in Google Scholar

[6] F.R.Hemandez, J.Sokolowski: Adv. Eng. Mater.7 (2010) 1037. 10.1002/adem.200500137Suche in Google Scholar

[7] T.H.Ludwig, E. SchonhovdDaehlen, P.L.Schaffer, L.Arnberg: J. Alloy. Compd.586 (2014) 180. 10.1016/j.jallcom.2013.09.127Suche in Google Scholar

[8] S.J.Hong, T.S.Jeong, H.J.Ko, T.H.Lee: Curr. Nanosci.10 (2014) 146. 10.2174/1573413709666131109004559Suche in Google Scholar

[9] C.L.Xu, H.Y.Wang, Y.F.Yang, Q.C.Jiang: Mater. Sci. Eng.A 452 (2007) 341. 10.1016/j.msea.2006.10.114Suche in Google Scholar

[10] Y.J.Sun, Q.L.Wang, H.R.Geng: J. Mater. Sci.47 (2012) 2104. 10.1007/s10853-011-6010-xSuche in Google Scholar

[11] J.Sun, X.B.Zhang, Y.J.Zhang, N.H.Ma, H.W.Wang: J. Mater. Sci.50 (2015) 1237. 10.1007/s10853-014-8680-7Suche in Google Scholar

[12] E.S.Lee: Int. J. Adv. Manuf. Tech.16 (2000) 700. 10.1007/s001700070021Suche in Google Scholar

[13] P.Kapranos, D.H.Kirkwood, H.V.Atkinson, P.Kapranos, J.T.Rheinlander, J.J.Bentzen, P.T.Toft, C.P.Debel, G.Laslaz, L.Maenner, S.Blais, J.M.Rodriguez-lbabe, L.Lasa, P.Giordano, G.Chiarmetta, A.Giese: J. Mater. Process. Technol.135 (2003) 271. 10.1016/s0924-0136(02)00857-9Suche in Google Scholar

[14] A.A.Luo, A.K.Sachdev, B.R.Powell: China Foundry7 (2010) 463. 10.3724/SP.J.1077.2011.00225Suche in Google Scholar

[15] V.Vijeesh, P.K.Narayan: Trans. Indian. Inst. Met.67 (2014) 1. 10.1007/s12666-013-0327-xSuche in Google Scholar

[16] S.E.Vaziri Yeganeh, A.Razaghian, M.Emamy: Mater. Sci. Eng.A 566 (2013) 1. 10.1016/j.msea.2012.12.078Suche in Google Scholar

[17] G.Zhong, Z.B.Wu, C.Qiu, Y.F.Li: Mater. Sci. Forum.794 (2014) 112. 10.4028/www.scientific.net/MSF.794-796.112Suche in Google Scholar

[18] M.Zou, X.F.Liu, Q.Q.Sun: J. Mater. Sci.44 (2009) 1952. 10.1007/s10853-009-3287-0Suche in Google Scholar

[19] M.Zou, K.Jiang, X.F.Liu: J. Alloy. Compd.503 (2010) L26. 10.1016/j.jallcom.2010.05.017Suche in Google Scholar

[20] J.Guo, Y.Liu, P.X.Fan, H.X.Qu, T.Quan: J. Alloy. Compd.495 (2010) 45. 10.1016/j.jallcom.2010.02.012Suche in Google Scholar

[21] M.Zuo, D.G.Zhao, T.Y.Teng, H.R.Geng, Z.S.Zhang: Mater. Des.47 (2013) 857. 10.1016/j.matdes.2012.12.054Suche in Google Scholar

[22] D.K.Li, M.Zuo, Q.Zhang, X.F.Liu: J. Alloys Compd.502 (2010) 304. 10.1016/j.jallcom.2010.04.165Suche in Google Scholar

[23] H.Qiao, X.Z.Zhu, T.Gao, Y.Y.Wu, X.F.Liu: J. Mater. Sci. Technol.31 (2015) 391. 10.1016/j.jmst.2014.09.010Suche in Google Scholar

[24] H. QiaoH, T.Gao, X.Z.Zhu, Y.Y.Wu, Z.Qian, X.F.Liu: J. Alloy. Compd.622 (2015) 622. 10.1016/j.jallcom.2014.10.048Suche in Google Scholar

[25] A.V.Pozdniakov, M.V.Glavatskikh, S.V.Makhov, V.I.Napalkov: Mater. Lett.128 (2014) 325. 10.1016/j.matlet.2014.04.068Suche in Google Scholar

[26] G.J.Bao, D.K.Li, J.F.Nie, X.F.Liu: J. Alloy. Compd.528 (2012) 45. 10.1016/j.jallcom.2012.03.025Suche in Google Scholar

[27] T.H.Ludwig, P.L.Schaffer, L. ArnbergL: Metall. Mater. Trans.A 44 (2013) 5796. 10.1007/s11661-013-1945-ySuche in Google Scholar

[28] K.Nogita, D. McDonaldStuart, K.Tsujimoto, K.Yasuda, A.Dahle: J. Electron. Microsc.53 (2004) 361. 15585468 10.1093/jmicro/dfh048Suche in Google Scholar PubMed

[29] T.Ohmi, K.Matsuura, M.Kudoh, Y.Iton: Light Metals47 (1997) 71. 10.2464/JILM.47.71Suche in Google Scholar

[30] W.Kasprzak, D.Sediako, M.Walker, M.Sahoo, I.Swainson: Metall. Mater. Trans.A 42 (2011) 1854. 10.1007/s11661-011-0666-3Suche in Google Scholar

[31] R.H.Mathiesen, L.Arnberg, Y.Li, V.Meier, P.L.Schaffer, I.Snigireva, A.Snigirev, A.K.Dahle: Metall. Mater. Trans.A 42 (2011) 170. 10.1007/s11661-010-0443-8Suche in Google Scholar

Received: 2018-04-27
Accepted: 2019-05-14
Published Online: 2019-10-23
Published in Print: 2019-11-12

© 2019, Carl Hanser Verlag, München

Heruntergeladen am 17.11.2025 von https://www.degruyterbrill.com/document/doi/10.3139/146.111831/pdf
Button zum nach oben scrollen