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Enthalpies of mixing in ternary Ce–Cu–Sb liquid alloys

  • Michael Ivanov , Natalia Usenko , Natalia Kotova and Natalia Golovataya
Published/Copyright: October 23, 2019
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 110 Issue 11

Abstract

The enthalpies of mixing in liquid alloys of the ternary Ce–Cu–Sb system were determined over a wide range of compositions by means of isoperibolic calorimetry at temperature 1300 K. Measurements were performed along five sections (xCu/xSb = 0.20/0.80; 0.40/0.60 and 0.60/0.40 for xCe changed from 0 up to 0.35 and xCu/xCe = 0.20/0.80 and 0.60/0.40 for xSb changed from 0 up to 0.25). The enthalpies of mixing in the ternary system were found to be exothermic and steadily increasing in absolute values from the binary constituent systems Ce–Cu and Cu–Sb towards the Ce–Sb boundary, reaching the minimum value of approximately –120 kJ · mol–1 in the vicinity of the phase CeSb.

Keywords: Copper; Cerium; Antimony; Calorimetry; Enthalpy of mixing
∗Correspondence address, Dr. Natalia Usenko, Department of Chemistry, Taras Shevchenko National University, 64, Volodymirska St., 01601 Kyiv, Ukraine, Tel.: +380442393370, E-mail:

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Received: 2019-03-12
Accepted: 2019-05-24
Published Online: 2019-10-23
Published in Print: 2019-11-12

© 2019, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.111833
Keywords for this article
Copper; Cerium; Antimony; Calorimetry; Enthalpy of mixing

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Note from the Editor-in-Chief
  5. Original Contributions
  6. The softening factor cb of commercial titanium alloy wires
  7. A comparative assessment of cyclic deformation behavior of SA333 Gr-6 steel at ambient and elevated temperatures
  8. Effects of Ni and Al on the Cu-precipitation in ferritic Fe–Cu–M (M = Ni or Al) alloy
  9. Effect of manganese on the microstructure and mechanical properties of magnesium alloys
  10. Effect of heat treatment and extrusion on wear properties of AZ91-Pr alloy
  11. Effect of anodization treatment on the mechanical properties and fatigue behavior of AA2017-T4 aluminum alloy Al–Cu–Mg1
  12. Microstructural and tribological characterization of molybdenum–molybdenum carbide structures produced by spark plasma sintering
  13. Investigation of indentation and dry sliding wear behaviour of Al-12.6 wt.% Si-10 wt.% TiB2 composites produced by sequential milling and pressureless sintering
  14. Enthalpies of mixing in ternary Ce–Cu–Sb liquid alloys
  15. Effect of in-situ formation of AlP on solidification of hypereutectic Al–Si alloy
  16. Complex-shaped high speed steel with high mechanical performance fabricated by gelcasting sintering
  17. Internal electromagnetic stirring method for preparing a large-sized aluminum alloy billet
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