Startseite On the high-temperature oxidation of MCrAlY coatings
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On the high-temperature oxidation of MCrAlY coatings

  • W. G. Sloof und T. J. Nijdam
Veröffentlicht/Copyright: 11. Juni 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 100 Heft 10

Abstract

In this review, recent progress in understanding the short- and long-term oxidation behaviour of MCrAlY coatings and the instruments that can be employed to influence the oxidation behaviour of the MCrAlY's are discussed. Particular attention is given on the transient oxidation behaviour, the initial distribution of the Y in the oxide scale and how these initial oxide products influence the long-term oxide growth rate and adhesion of the oxide scale. It is shown that the growth kinetics and adhesion of the oxide scale are to a large extent determined by the amount and distribution of Y-oxide inclusions in the scale. Oxide scales with a regularly distributed and larger amount of small Y-oxide inclusions are faster growing, but perform better in thermal cycle tests. Transient oxide products like metastable aluminas (γ- or θ-Al2O3) and spinels do not have a large influence on long-term oxidation behaviour except when the oxide scale is virtually free of Y-oxide inclusions due to Y depletion. Then, the nucleation of metastable aluminas at the onset of oxidation may be beneficial due to a slower-growing alumina scale with a larger grain size after transformation into α-Al2O3. Spinel oxides are considered detrimental for long-term oxidation performance, but their amount is usually limited on most types of MCrAlY coatings due to the rapid supply of Al along the numerous grain and phase boundaries in the fine-grained coatings. The key instruments that can be employed to manipulate the oxidation behaviour of MCrAlY coatings are: (i) the composition and size of the main phases in the coating (γ-Ni and β-NiAl), (ii) the initial distribution, chemical state (metallic or oxidized) and reservoir of the Y in the coating, (iii) the composition and roughness at the coating surface, and (iv) the oxidation conditions during post-deposition heat treatment (temperature, time, partial oxygen pressure).

Keywords: MCrAlY; Oxidation; Alumina; Yttrium; Lifetime
* Correspondence address, Dr. Ir. W.G. Sloof Department of Materials Science and Engineering Delft University of Technology Mekelweg 2, 2628 CD Delft, The Netherlands Tel.: +31 15 2 784 924 Fax: +31 15 2 786 730 Email:

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Received: 2009-6-16
Accepted: 2009-7-25
Published Online: 2013-06-11
Published in Print: 2009-10-01

© 2009, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Introduction
  4. Introduction
  5. G. Petzow: Laudation for Peter Paul Schepp
  6. Dr. Schepp's retirement after 20 years of service was celebrated
  7. Preface to Feature Articles
  8. “SURFACE and INTERFACE ENGINEERING”
  9. Feature
  10. Thermodynamics of reactions and phase transformations at interfaces and surfaces
  11. Oxidation of palladium: from single crystal surfaces towards nanoparticles
  12. On the high-temperature oxidation of MCrAlY coatings
  13. Conducting polymers for corrosion protection: a review
  14. Fundamental and applied aspects of laser surface engineering
  15. Low-temperature gaseous surface hardening of stainless steel: the current status
  16. Foreword
  17. Foreword
  18. Editorial
  19. The scientific work of Charles Crussard (1916–2008)
  20. Review
  21. Charles Crussard's early contributions: Recrystallization in situ and a Grain Boundary study with J. Friedel and B. Cullity
  22. Magnetohydrodynamics applied to materials processing
  23. Charles Crussard's contribution to sheet metal forming and participation in IDDRG
  24. Glide of dislocations in non-octahedral planes of fcc metals: a review
  25. The deformation stage II of face-centered cubic crystals: Fifty years of investigations
  26. Nucleation and growth during primary recrystallization of certain metals and alloys with a face-centered cubic structure: Formation of the cube texture
  27. Basic
  28. Andrade creep revisited
  29. Application of cluster dynamics modeling to the precipitation in aluminum alloys
  30. On the effect of pre-recovery on subsequent recrystallization
  31. The interplay between grain boundaries and disclinations in condensed matter physics
  32. Plasticity of nanocrystalline materials: a critical viewpoint
  33. Thermoelectric power applied to metallurgy: principle and recent applications
  34. Notifications
  35. People
https://doi.org/10.3139/146.110201
Schlagwörter für diesen Artikel
MCrAlY; Oxidation; Alumina; Yttrium; Lifetime

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Introduction
  4. Introduction
  5. G. Petzow: Laudation for Peter Paul Schepp
  6. Dr. Schepp's retirement after 20 years of service was celebrated
  7. Preface to Feature Articles
  8. “SURFACE and INTERFACE ENGINEERING”
  9. Feature
  10. Thermodynamics of reactions and phase transformations at interfaces and surfaces
  11. Oxidation of palladium: from single crystal surfaces towards nanoparticles
  12. On the high-temperature oxidation of MCrAlY coatings
  13. Conducting polymers for corrosion protection: a review
  14. Fundamental and applied aspects of laser surface engineering
  15. Low-temperature gaseous surface hardening of stainless steel: the current status
  16. Foreword
  17. Foreword
  18. Editorial
  19. The scientific work of Charles Crussard (1916–2008)
  20. Review
  21. Charles Crussard's early contributions: Recrystallization in situ and a Grain Boundary study with J. Friedel and B. Cullity
  22. Magnetohydrodynamics applied to materials processing
  23. Charles Crussard's contribution to sheet metal forming and participation in IDDRG
  24. Glide of dislocations in non-octahedral planes of fcc metals: a review
  25. The deformation stage II of face-centered cubic crystals: Fifty years of investigations
  26. Nucleation and growth during primary recrystallization of certain metals and alloys with a face-centered cubic structure: Formation of the cube texture
  27. Basic
  28. Andrade creep revisited
  29. Application of cluster dynamics modeling to the precipitation in aluminum alloys
  30. On the effect of pre-recovery on subsequent recrystallization
  31. The interplay between grain boundaries and disclinations in condensed matter physics
  32. Plasticity of nanocrystalline materials: a critical viewpoint
  33. Thermoelectric power applied to metallurgy: principle and recent applications
  34. Notifications
  35. People
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