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Review on nanostructures from catalytic pyrolysis of gas and liquid carbon sources

  • Eldar B. Zeynalov , Joerg F. Friedrich , Dilgam B. Tagiyev , Asgar B. Huseynov , Matanat Ya. Magerramova und Narmin A. Abdurehmanova
Veröffentlicht/Copyright: 13. Juli 2018
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Abstract

Numerous scientific reports devoted to the synthesis of carbon nanostructures (CNS) are published as a way of searching for industrially feasible processes. Researchers try to find efficient and at the same time cheap, affordable and easy-to-use sources of carbon, catalysts and methods of carbon nanotubes production. The present review article highlights research on the synthesis of CNS from gas and liquid feedstock which appears to be the most amenable for large-scale production. Carbon sources, types of catalysts used as well as methods for production of various carbon nanostructures are sequentially described.

Kurzfassung

Zahlreiche wissenschaftliche Publikationen sind der Synthese von Kohlenstoff-Nanostrukturen (CNS) unter dem Aspekt industrieller Herstellung gewidmet. Ausschau wurde nach Wegen zur effizienten katalytischen Produktion von Kohlenstoff-Nanoröhren gehalten, deren Synthese billige und leicht zugängliche Kohlenwasserstoffquellen und Katalysatorsysteme nutzt. Dieser Übersichtsartikel beschreibt einige Verfahren der CNS-Synthese, die flüssige und gasförmige Kohlenwasserstoffquellen nutzen und gleichzeitig zur Hochskalierung in industrielle Maßstäbe geeignet sind. Insbesondere die Kohlenwasserstoffquellen, die Katalysatorsysteme und die damit erhaltenen Kohlenstoff-Nanostrukturen werden im Einzelnen beschrieben.


*Correspondence Address, Prof. Dr. Joerg Friedrich, Polymer Technique/Polymer Physics, Technical University Berlin, Straße des 17. Juni, Berlin, Germany, E-mail:

Prof. Dr. sc. nat. Eldar B. Zeynalov studied chemistry at the Azerbaijan State University, Baku from 1966 to 1971. From 1971 to 1976 he was a PhD student at the Institute of Chemical Physics of the USSR Academy of Sciences, Moscow. Between 1976 and 1989, he was research officer, senior staff scientist, assistant professor and associate professor and finally received a DSc scientific degree in Chemical Sciences in 1989. In 2010 he became full professor. Since 1991 to the present, he has been head of scientific departments and laboratories at different Institutes of the Azerbaijan National Academy of Sciences (ANAS), Baku. In 2017 he was elected as corresponding member of the ANAS.

Prof. Dr. habil. rer. nat. Joerg F. Friedrich studied chemistry at the Humboldt University, Berlin, Germany. In 1975 he received a Dr. rer. nat. (PhD) in Polymer Chemistry from the Academy of Sciences of GDR, Institute of Macromolecular Sciences, Berlin, as well as a Promotion B (Habilitation). 1982, he became Dr. sc. nat. in polymer and plasma chemistry. Ordinary habilitation (Dr. rer. nat. habil.) followed in 1991 from the TH Merseburg, Germany. From 1996–2014 he was Director and Professor at the Federal Institute for Materials Research and Testing. Presently he is Professor at the Technical University Berlin

Academician Dilgam B. Tagiyev studied chemistry at Baku State University, Baku in Azerbaijan/USSR from 1966 to 1971. In 1975 and 1984 he successfully defended his Ph.D and doctoral theses in Moscow at the Scientific Council of the Institute of Organic Chemistry of the AS of the USSR and was granted a title of professor in 1990. From 1974 on, he worked in the positions of an engineer, junior and senior research scientist, head of group and laboratory at the Institute of Inorganic and Physical Chemistry of the AS of Azerbaijan. From 1986 to 1991 he was a deputy director on scientific works at this institute. In 1991, he was elected professor at General Chemistry and chair at Azerbaijan Medical University. From 1999 he also headed the laboratory “Heterogeneous catalysis” at the invitation of the directorate of the Institute of Petrochemical Processes of ANAS. In 2007 he was elected corresponding member of the ANAS. In 2013, according to the resolution of the common meeting of the NAS of Azerbaijan, he was appointed academician-secretary at Department of Chemical Sciences and member of the Presidium of the ANAS. In 2014 he was elected director of the Institute of Catalysis and Inorganic Chemistry (IC&ICh) and academician for the ANAS with a speciality in “Chemical kinetics and catalysis”.

Huseynov Asgar Beyuk-Aga, born in 1953, received his MSc degree in chemistry from Baku State University and PhD degree in chemistry from the Azerbaijan Academy of Sciences (AAS) in 1979 and 1985, respectively. From 1976 to 2004, he worked at the AAS Institute Petrochemical Processes. Currently he is head of the department “Nanochemistry and nanosorbents” at the Research and Development Center for High Technologies in Baku, Azerbaijan. His major research interests include the development of processes for the synthesis of carbon nanostructures and various composites based on them, as well as the use of the obtained nanomaterials in new types of sensors, solving environmental problems and creating new efficient catalysts for the oxidation of hydrocarbons

Matanat Ya. Magerramova studied chemistry at the Azerbaijan State Oil and Chemistry Institute, Baku from 1981 to 1986. Between 1983 and 2001 she was an engineer and laboratory assistant at the Institute of Polymer Materials of the ANAS, Sumgayit. From 2001 to 2014, she was senior researcher at the Sumgayit State University. She received her PhD scientific degree in Macromolecular Chemistry in 2006 at the ANAS Institute of Theoretical Problems of Chemical Technology. Since 2014 to the present, she has had the positions of senior researcher and associate professor at the Institute of Catalysis and Inorganic Chemistry, ANAS.

Narmin A. Abdurahmanova studied chemistry and biology at Qafqaz University, Baku, Azerbaijan from 2011 to 2015. From 2015 to 2017 she was a Master's student and laboratory assistant at the Institute of Catalysis and Inorganic Chemistry (IC&ICh), ANAS. Currently, she is a junior research fellow at the IC&ICh.


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Published Online: 2018-07-13
Published in Print: 2018-07-16

© 2018, Carl Hanser Verlag, München

Artikel in diesem Heft

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