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Magnetic mixed matrix membranes in air separation

  • Aleksandra Rybak EMAIL logo , Gabriela Dudek , Monika Krasowska , Anna Strzelewicz , Zbigniew Grzywna und Petr Sysel
Veröffentlicht/Copyright: 24. Juni 2014
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 68 Heft 10

Abstract

Ethylcellulose (EC) or linear polyimide (LPI) and magnetic neodymium powder particles MQP-14-12 were used for the preparation of inorganic-organic hybrid membranes. For all the membranes, N2, O2 and air permeability were examined. Mass transport coefficients were determined using the Time Lag System based on dynamic experiments in a constant pressure system. The results showed that the membrane permeation properties were improved by the addition of magnetic neodymium particles to the polymer matrix. The magnetic ethylcellulose and polyimide membranes exhibited higher gas permeability and diffusivity, while their permeability selectivity and solubility were either unchanged or slightly increased. Polyimide mixed matrix membranes were characterised by a higher thermal and mechanical stability, larger filler loading, better magnetic properties and reasonable selectivity in the air separation.

Keywords: magnetic mixed matrix membranes; air enrichment; permeation; ethyl cellulose; linear polyimide

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Published Online: 2014-6-24
Published in Print: 2014-10-1

© 2014 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.2478/s11696-014-0587-x
Schlagwörter für diesen Artikel
magnetic mixed matrix membranes; air enrichment; permeation; ethyl cellulose; linear polyimide

Artikel in diesem Heft

  1. Chemical preparation and applications of silver dendrites
  2. Evaluation of antioxidant activity and DNA cleavage protection effect of naphthyl hydroxamic acid derivatives through conventional and fluorescence microscopic methods
  3. Modelling of ORL1 receptor-ligand interactions
  4. Kinetics of enantioselective liquid-liquid extraction of phenylglycine enantiomers using a BINAP-copper complex as chiral selector
  5. Diffusive transport of Cu(II) ions through thin ion imprinted polymeric membranes
  6. Magnetic mixed matrix membranes in air separation
  7. The use of impregnated perlite as a heterogeneous catalyst for biodiesel production from marula oil
  8. Nitrobenzene degradation by micro-sized iron and electron efficiency evaluation
  9. RP-HPLC-UV-ESI-MS phytochemical analysis of fruits of Conocarpus erectus L.
  10. Residue analysis of fosthiazate in cucumber and soil by QuEChERS and GC-MS
  11. Degradation of polylactide using basic ionic liquid imidazolium acetates
  12. Ring-opening polymerisation of ɛ-caprolactone catalysed by Brønsted acids
  13. Click synthesis by Diels-Alder reaction and characterisation of hydroxypropyl methylcellulose-based hydrogels
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  18. Dithiols as more effective than monothiols in protecting biomacromolecules from free-radical-mediated damage: in vitro oxidative degradation of high-molar-mass hyaluronan
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