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Two new frameworks for biphenyl-3,3′,5,5′-tetracarboxylic acid and nitrogen-containing organics

  • Wen-Jie Zhao EMAIL logo , Jin-Ting Tan , Xia Li , Ying-Li Lu , Xing Feng and Xu-Wu Yang
Published/Copyright: June 24, 2014
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Chemical Papers
From the journal Chemical Papers Volume 68 Issue 10

Abstract

Two complexes, {Zn(bptc)0.5(bib)}n (I) and {Mn2(bptc)(pip)(H2O)}n (II) (H4bptc = biphenyl-3,3′,5,5′-tetracarboxylic acid; bib = 1,4-bis(2-methylimidazol-1-yl)butane; pip = 2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline) were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, TGA and solid fluorescence spectra. The results show that I and II both have 3D network architectures. I has porous architecture with a 162 topology structure. Effective porosity calculated by Platon is 5.5 %. Moreover, it has a two-fold interpenetrating structure allowed by a 70.73° torsion between the benzene rings of the bptc4− ligand and the flexibility of bib. II has a tetranuclear structure composed of binuclear architecture units with the torsion of 43.44° between the benzene rings of the bptc4− ligand. TGA shows that the skeletons of I and II are stable up to 372°C and 553°C, respectively. I exhibits fluorescence.

Keywords: biphenyl-3,3′,5,5′-tetracarboxylic acid; nitrogen-containing organics; parallel interpenetrating; polynuclear; solid fluorescence

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Published Online: 2014-6-24
Published in Print: 2014-10-1

© 2014 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.2478/s11696-014-0584-0
Keywords for this article
biphenyl-3,3′,5,5′-tetracarboxylic acid; nitrogen-containing organics; parallel interpenetrating; polynuclear; solid fluorescence

Articles in the same Issue

  1. Chemical preparation and applications of silver dendrites
  2. Evaluation of antioxidant activity and DNA cleavage protection effect of naphthyl hydroxamic acid derivatives through conventional and fluorescence microscopic methods
  3. Modelling of ORL1 receptor-ligand interactions
  4. Kinetics of enantioselective liquid-liquid extraction of phenylglycine enantiomers using a BINAP-copper complex as chiral selector
  5. Diffusive transport of Cu(II) ions through thin ion imprinted polymeric membranes
  6. Magnetic mixed matrix membranes in air separation
  7. The use of impregnated perlite as a heterogeneous catalyst for biodiesel production from marula oil
  8. Nitrobenzene degradation by micro-sized iron and electron efficiency evaluation
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  10. Residue analysis of fosthiazate in cucumber and soil by QuEChERS and GC-MS
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