Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
P4/n and P4nc long-range ordering in low-temperature vesuvianites
-
Thomas Armbruster
und
Edwin Gnos
Veröffentlicht/Copyright:
26. März 2015
Abstract
Low-temperature vesuvianites crystallize in the two space groups P4/n or P4nc due to different arrangements of Ca-dodecahedra and M2+,3+ square pyramids that form strings along the fourfold axes. Long-range ordered vesuvianites of acentric P4nc symmetry may have the same diffraction symmetry as centrosymmetric disordered P4/nnc vesuvianites. In contrast, P4/n long-range ordered vesuvianites exhibit glide plane violating reflections and can easily be identified. We report the first successful Xray single-crystal structure refinement of a P4nc vesuvianite, a = 15.487(2), c = 11.764(2) Å from the N’chwaning II mine of the Kalahari manganese fields (RSA). This untwinned crystal has Cu2+ and Mn2+, Mn3+ forming the square pyramid and exhibits an acentric ordering pattern with 85% string A and 15% string B. This is compared to a reinvestigation of the structure of a P4/n vesuvianite from Asbestos Quebec (Canada), a = 15.531(2), c = 11.817(2) Å. The crystal is composed of a merohedral (110) twin with a close to 1:1 twin ratio and has mainly Fe3+ in square pyramidal coordination. In this centric structure, string A is 84% and string B is 16% occupied. Criteria to determine the symmetry of low-temperature vesuvianites, studied by diffraction experiments, are discussed.
Received: 1999-4-26
Accepted: 1999-10-20
Published Online: 2015-3-26
Published in Print: 2000-4-1
© 2015 by Walter de Gruyter Berlin/Boston
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Iron concentration and the physical processes of dynamic oxidation in an alkaline earth aluminosilicate glass
- A crystal chemical re-evaluation of amphibole/melt and amphibole/clinopyroxene DTi values in petrogenetic studies
- Mineralogy of mafic xenoliths and their reaction zones in the olivine lamproite from Prairie Creek Arkansas and the paragenesis of haggertyite, Ba [Fe6Ti5Mg]O19
- Magmatic anhydrite in granitic rocks: First occurrence and potential petrologic consequences
- Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites
- Spectroscopic and structural properties of synthetic micas on the annite-siderophyllite binary: Synthesis, crystal structure refinement, Mössbauer, and infrared spectroscopy
- Thermodynamic properties of tremolite: A correction and some comments
- Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes
- Hydrogen in diopside: Diffusion profiles
- Diffusion of C and O in calcite at 100 MPa
- Solubility and stability of zeolites in aqueous solution: II. Calcic clinoptilolite and mordenite
- TEM and SFM of exsolution and twinning in an alkali feldspar
- Equation of state of magnetite and its high-pressure modification: Thermodynamics of the Fe-O system at high pressure
- Optimization of site occupancies in minerals using quadratic programming
- Leverage analysis and structure refinement of minerals
- The absolute energy positions of conduction and valence bands of selected semiconducting minerals
- Antiferroelectric phase transition in titanite: Excess entropy and short range order
- P4/n and P4nc long-range ordering in low-temperature vesuvianites
- Tetrahedral vacancies and cation ordering in low-temperature Mn-bearing vesuvianites: Indication of a hydrogarnet-like substitution
- Sodic-ferripedrizite, a new monoclinic amphibole bridging the magnesium-iron-manganese-lithium and the sodium-calcium groups
- The crystal structure of peprossiite-(Ce), an anhydrous REE and Al mica-like borate with square-pyramidal coordination for Al
- Crystal chemistry of the new mineral brandholzite, Mg(H2O)6[Sb(OH)6]2, and of the synthetic analogues M2+(H2O)6[Sb(OH)6]2 (M2+ = Mg, Co)
- Letters. In-situ Raman spectra of dissolved silica species in aqueous fluids to 900 °C and 14 kbar
- Quetzalcoatlite: A new octahedral-tetrahedral structure from a 2 × 2 × 40 μm3 crystal at the Advanced Photon Source-GSE-CARS Facility
- Bonding and dynamics of Mg in pyrope: a theoretical investigation
- Structure of a new Al-rich phase, [K, Na]0.9[Mg, Fe]2[Mg, Fe, Al, Si]6O12, synthesized at 24 GPa
- Core level electron binding energies of realgar (As4S4)
- Oxidation of {100} and {111} surfaces of pyrite: Effects of preparation method
Artikel in diesem Heft
- Iron concentration and the physical processes of dynamic oxidation in an alkaline earth aluminosilicate glass
- A crystal chemical re-evaluation of amphibole/melt and amphibole/clinopyroxene DTi values in petrogenetic studies
- Mineralogy of mafic xenoliths and their reaction zones in the olivine lamproite from Prairie Creek Arkansas and the paragenesis of haggertyite, Ba [Fe6Ti5Mg]O19
- Magmatic anhydrite in granitic rocks: First occurrence and potential petrologic consequences
- Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites
- Spectroscopic and structural properties of synthetic micas on the annite-siderophyllite binary: Synthesis, crystal structure refinement, Mössbauer, and infrared spectroscopy
- Thermodynamic properties of tremolite: A correction and some comments
- Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes
- Hydrogen in diopside: Diffusion profiles
- Diffusion of C and O in calcite at 100 MPa
- Solubility and stability of zeolites in aqueous solution: II. Calcic clinoptilolite and mordenite
- TEM and SFM of exsolution and twinning in an alkali feldspar
- Equation of state of magnetite and its high-pressure modification: Thermodynamics of the Fe-O system at high pressure
- Optimization of site occupancies in minerals using quadratic programming
- Leverage analysis and structure refinement of minerals
- The absolute energy positions of conduction and valence bands of selected semiconducting minerals
- Antiferroelectric phase transition in titanite: Excess entropy and short range order
- P4/n and P4nc long-range ordering in low-temperature vesuvianites
- Tetrahedral vacancies and cation ordering in low-temperature Mn-bearing vesuvianites: Indication of a hydrogarnet-like substitution
- Sodic-ferripedrizite, a new monoclinic amphibole bridging the magnesium-iron-manganese-lithium and the sodium-calcium groups
- The crystal structure of peprossiite-(Ce), an anhydrous REE and Al mica-like borate with square-pyramidal coordination for Al
- Crystal chemistry of the new mineral brandholzite, Mg(H2O)6[Sb(OH)6]2, and of the synthetic analogues M2+(H2O)6[Sb(OH)6]2 (M2+ = Mg, Co)
- Letters. In-situ Raman spectra of dissolved silica species in aqueous fluids to 900 °C and 14 kbar
- Quetzalcoatlite: A new octahedral-tetrahedral structure from a 2 × 2 × 40 μm3 crystal at the Advanced Photon Source-GSE-CARS Facility
- Bonding and dynamics of Mg in pyrope: a theoretical investigation
- Structure of a new Al-rich phase, [K, Na]0.9[Mg, Fe]2[Mg, Fe, Al, Si]6O12, synthesized at 24 GPa
- Core level electron binding energies of realgar (As4S4)
- Oxidation of {100} and {111} surfaces of pyrite: Effects of preparation method
