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Schwingungsspektroskopische Untersuchungen an SiO2-Clathraten
Veröffentlicht/Copyright:
25. August 2010
Abstract
Infrared and Raman spectroscopy were used to establish the presence and interactions of guest molecules enclosed in the SiO2-clathrasil compound Dodecasil 3C. X-ray powder diagrams showed an expansion of the crystal lattice that varied with the size of the guest molecule. Reactions of the guest molecules on heating the clathrate were demonstrated by means of vibrational spectroscopy. Larger quantities of substances were synthesized in autoclaves. The occupation of the silica framework with guest molecules was quantitatively determined in one substance.
Published Online: 2010-08-25
Published in Print: 1992
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Artikel in diesem Heft
- Crystal structure of a cholesterogen – cholesteryl methyl carbonate (CMC)
- An X-ray search for anharmonicity in indium phosphide
- Crystal structure and spectra of bis[p-chloro-benzoyl-di-(2-pyridyl)ketonohydrazono]uranyl
- Crystal structures of isomorphous triaquatris(3-aminobenzoato-O, O)yttrium(III) trihydrate and triaquatris(3-aminobenzoato-0,0)lanthanide(III) trihydrate
- Crystal structure of calcium hydroxide nitrate hydrate and its superstructure in relation to cadmium hydroxide nitrate hydrate
- Structural phase transition in GaMo4Se8 and AlMo4S8 by X-ray powder diffraction
- The crystal structure of Ce4Ru3
- Allowance for Debye scattering in Wilson-plot least-squares procedures
- The (1:1) adducts of (2,4-dichlorophenoxy)acetic acid with 4-aminobenzoic acid and triphenylphosphine oxide *
- Molecular and crystal structure of a terminally-blocked Aib homotetrapeptide *
- Molecular and crystal structure of Nα-benzyloxycarbonyl-l-proline amide *
- Schwingungsspektroskopische Untersuchungen an SiO2-Clathraten
- Liebauite, Ca3Cu5Si9O26: A new silicate mineral with 14er single chain
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