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Crystal structures of isomorphous triaquatris(3-aminobenzoato-O, O)yttrium(III) trihydrate and triaquatris(3-aminobenzoato-0,0)lanthanide(III) trihydrate
Published/Copyright:
August 25, 2010
Abstract
The space group and unit cell parameters of yttrium(III) and lanthanide(III) 3-aminobenzoate hexahydrate crystals have been determined. All compounds have the formula [M(C7H6NO2)3 · 3H2O] · 3H20 and their crystals are isomorphous in the non-centrosymmetric trigonal space group R3c. Crystal structures of three of these salts have been determined: Y(III), Er(III) and Lu(III). The structures consist of the metal cation coordinated by water molecules, bidentate chelating 3-aminobenzoate anions, and crystallization water. The metal coordination polyhedron, with crystallographically imposed threefold symmetry axis, is formed by nine oxygen atoms: six of carboxylate groups and three of water molecules. The crystal structure is stabilized by interligand hydrogen bonding between water molecules and either carboxylate or amino groups.
Published Online: 2010-08-25
Published in Print: 1992
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Articles in the same Issue
- Crystal structure of a cholesterogen – cholesteryl methyl carbonate (CMC)
- An X-ray search for anharmonicity in indium phosphide
- Crystal structure and spectra of bis[p-chloro-benzoyl-di-(2-pyridyl)ketonohydrazono]uranyl
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- Crystal structure of calcium hydroxide nitrate hydrate and its superstructure in relation to cadmium hydroxide nitrate hydrate
- Structural phase transition in GaMo4Se8 and AlMo4S8 by X-ray powder diffraction
- The crystal structure of Ce4Ru3
- Allowance for Debye scattering in Wilson-plot least-squares procedures
- The (1:1) adducts of (2,4-dichlorophenoxy)acetic acid with 4-aminobenzoic acid and triphenylphosphine oxide *
- Molecular and crystal structure of a terminally-blocked Aib homotetrapeptide *
- Molecular and crystal structure of Nα-benzyloxycarbonyl-l-proline amide *
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