Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
-
Manish Kumar
,
Shashi Kant
Abstract
The present study aims for the structure-making and structure-breaking behavior of some electrolytes in aqueous citric acid solution. The density, viscosity and conductance of some alkali metal chlorides lithium chloride (LiCl), sodium chloride (NaCl) and potassium chloride (KCl) in 0.01 m aqueous citric acid have been measured in the concentration range 0.01–0.12 m at 303.15, 308.15, 313.15 and 318.15 K. From these measurements, molar volume, viscosity parameters and molar conductance have been deliberated. Debye Hückel limiting law is used for the assessment of the contributions of various types of solute–solvent interactions. Jones–Dole viscosity equation is used to calculate viscosity B-coefficient for these salts in aqueous citric acid, which is known to provide information concerning the solvation of ions and their effects on the structure of the solvent in the near environment of the solute particles. The free energies of activation of viscous flow per mole of solvent,
Acknowledgement
M. Kumar thanks CSIR New Delhi for his financial assistance.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Study of Intermolecular Interactions of CTAB with Amino Acids at Different Temperatures: A Multi Technique Approach
- The Differential Spectroscopic Investigation of Partitioning of Reactive Dyes in Micellar Media of Cationic Surfactant, Cetyl Trimethylammonium Bromide (CTAB)
- Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
- Adsorption and Computational Studies for Evaluating the Behavior of Silicon Based Compounds as Novel Corrosion Inhibitors of Carbon Steel Surfaces in Acidic Media
- Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
- Solubility and Thermodynamics of 6-Phenyl-4,5-dihydropyridazin-3(2H)-one in Various (PEG 400+Water) Mixtures
- Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
- Experimental and Theoretical Study on the Interaction of P-Aminophenol Hydrochloride with H2O
Artikel in diesem Heft
- Frontmatter
- Study of Intermolecular Interactions of CTAB with Amino Acids at Different Temperatures: A Multi Technique Approach
- The Differential Spectroscopic Investigation of Partitioning of Reactive Dyes in Micellar Media of Cationic Surfactant, Cetyl Trimethylammonium Bromide (CTAB)
- Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
- Adsorption and Computational Studies for Evaluating the Behavior of Silicon Based Compounds as Novel Corrosion Inhibitors of Carbon Steel Surfaces in Acidic Media
- Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
- Solubility and Thermodynamics of 6-Phenyl-4,5-dihydropyridazin-3(2H)-one in Various (PEG 400+Water) Mixtures
- Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
- Experimental and Theoretical Study on the Interaction of P-Aminophenol Hydrochloride with H2O
