Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
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Mohib Ullah
und
Noor Ul Amin
Abstract
This study pertains to theoretical aspect of membrane and surfactant supported ultrafiltration technique followed by experimental evaluation of rejection percentage (R%) and permeate flux (J). The organic dye malachite green (MG) was removed from water samples with help of micellar solution of sodium dodecyl sulfate (SDS) surfactant on account of effective surfactant-dye interaction. The MG removal from water was result of electrostatic force of attraction between Stern layer of SDS micelles and cationic MG in addition to hydrophobic-hydrophobic interaction. The regenerated cellulose membrane was used to retain enhanced MG-SDS micellar complex from polluted water in stirred ultrafiltration cell. R% of MG increases from 79.3%, 77%, 76% to 97.5%, 95%, 90% for 0.01, 0.1 and 0.2 mM concentrations, respectively. “J” decreases throughout the experiment on account of membrane plugging or concentration polarization. Hydrodynamic radius (Rh) of SDS surfactant was also determined at its post micellar concentrations by dynamic laser light scattering (DLLS) that shows high rejection percentage with increased Rh values.
Acknowledgements
The authors acknowledge Pakistan Science Foundation (PSF) for financial support.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
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Artikel in diesem Heft
- Frontmatter
- Study of Intermolecular Interactions of CTAB with Amino Acids at Different Temperatures: A Multi Technique Approach
- The Differential Spectroscopic Investigation of Partitioning of Reactive Dyes in Micellar Media of Cationic Surfactant, Cetyl Trimethylammonium Bromide (CTAB)
- Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
- Adsorption and Computational Studies for Evaluating the Behavior of Silicon Based Compounds as Novel Corrosion Inhibitors of Carbon Steel Surfaces in Acidic Media
- Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
- Solubility and Thermodynamics of 6-Phenyl-4,5-dihydropyridazin-3(2H)-one in Various (PEG 400+Water) Mixtures
- Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
- Experimental and Theoretical Study on the Interaction of P-Aminophenol Hydrochloride with H2O
