Polylactic acid effectively reinforced with reduced graphitic oxide
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Alejandra De La Cruz Natera
, Adriana Cordero García , Juan Restrepo Betancourt , Mary Judith Arias Tapia und Oscar Vargas Ceballos
Abstract
The present study was developed to reinforce a thermoplastic matrix with carbonaceous material to improve its thermal and mechanical properties. Composite materials formed from the homogenization of polylactic acid (PLA) and reduced graphitic oxide (RGO) were synthesized and characterized, reinforcement of the polymer’s thermomechanical properties and the adequate homogeneity ratio in the dispersion of the composite material were studied. Graphitic oxide (GO) was synthesized by the modified Hummers method, followed by thermal exfoliation. The chemical composition and the structure of RGO were studied by infrared (FT-IR) and Raman spectroscopies, respectively. PLA composites with different RGO contents (2 and 3% by weight) were prepared and compared in terms of distribution of RGO in the matrix and morphology, using scanning electron microscopy. The thermal stability of the composites was determined through thermogravimetric analysis. Torque of the different composites was measured, which increased at 21%; the tensile test showed an improvement in the mechanical parameters of the composites because the RGO favors the rigidity of the composite. In addition, the oxygenated functional groups present in the RGO allowed a more significant interaction with the PLA matrix, which results in an effective reinforcement of the mechanical properties of the composite material.
Funding source: Universidad del Atlántico
Award Identifier / Grant number: ING36-TGI2018
Funding source: Universidad Industrial de Santander
Award Identifier / Grant number: 2502
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Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The authors acknowledge the different dependencies of the Universidad del Atlántico and the financial support from Universidad Industrial de Santander through the internal project 2502.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Tsuji, H., Echizen, Y., Nishimura, Y. Photodegradation of biodegradable polyesters: a comprehensive study on poly(l-lactide) and poly(ɛ-caprolactone). Polym. Degrad. Stabil. 2006, 91, 1128–1137; https://doi.org/10.1016/j.polymdegradstab.2005.07.007.Suche in Google Scholar
2. Auras, R., Lim, L.-T., Selke, S. E. M., Tsuji, H. Poly(lactic Acid): Synthesis, Structures, Properties and Applications; John Wiley & Sons: New Jersey, 2010.10.1002/9780470649848Suche in Google Scholar
3. Oksman, K., Skrifvars, M., Selin, J.-F. Natural fibres as reinforcement in polylactic acid (PLA) composites. Compos. Sci. Technol. 2003, 61, 1317–1324; https://doi.org/10.1016/s0266-3538(03)00103-9.Suche in Google Scholar
4. Liu, H., Zhang, J. Research progress in toughening modification of poly(lactic acid). J. Polym. Sci. B Polym. Phys. 2011, 49, 1051–1083; https://doi.org/10.1002/polb.22283.Suche in Google Scholar
5. Ho, M., Lau, K., Wang, H., Hui, D. Improvement on the properties of polylactic acid (PLA) using bamboo charcoal particles. Compos. B Eng. 2015, 81, 14–25; https://doi.org/10.1016/j.compositesb.2015.05.048.Suche in Google Scholar
6. Domínguez-Robles, J., Martin, N. K., Fong, M. L., Stewart, S. A., Irwin, N. J., Rial-Hermida, M. I., Donnelly, R. F., Larrañeta, E. Antioxidant PLA composites containing lignin for 3D printing applications: a potential material for healthcare applications. Pharmaceutics 2019, 11, 5–7; https://doi.org/10.3390/pharmaceutics11040165.Suche in Google Scholar PubMed PubMed Central
7. Potts, J. R., Dreyer, D. R., Bielawski, C. W., Ruoff, R. S. Graphene-based polymer nanocomposites. Polymer 2011, 52, 5–25; https://doi.org/10.1016/j.polymer.2010.11.042.Suche in Google Scholar
8. Vargas, O. A., Caballero, Á., Morales, J. Can the performance of graphenenanosheets for lithium storage in Li-ion batteries be predicted? Nanoscale 2012, 4, 2083–2092; https://doi.org/10.1039/c2nr11936f.Suche in Google Scholar PubMed
9. International, C. A. Standard Practice for Injection Molding Test Specimens of Thermoplastic Molding and Extrusion Materials. USA, 2021.Suche in Google Scholar
10. C. A. International. Standard Test Method for Tensile Properties of Plastics. USA, 2015.Suche in Google Scholar
11. Vorrada, L., Krit, T., Passakorn, E., Wanchai, B., Achanai, B. Preparation and characterization of reduced graphene oxide sheets via water-based exfoliation and reduction methods. Adv. Mater. Sci. Eng. 2013, 2013, 1–5; https://doi.org/10.1155/2013/923403.Suche in Google Scholar
12. Ferrari, A. C. Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B 2000, 61, 14095; https://doi.org/10.1103/physrevb.61.14095.Suche in Google Scholar
13. Pascal, P., Kandara, M., Paredes, G., Moulin, L., Weiss-Hortala, E., Kundu, A., Ratel, N., Plewa, P-M., Pellenq, R., Monthloux, M. Analyzing the Raman spectra of graphenic xarbon materials from kerogens to nanotubes: what type of information can be extracted from defect bands? J. Carbon Res. 2019, 5, 69.10.3390/c5040069Suche in Google Scholar
14. Wojtoniszak, M., Chen, X., Kalenczuk, R. J., Wajda, A., Łapczuk, J. Synthesis, dispersion, and cytocompatibility of graphene oxide and reduced graphene oxide. Colloids Surf. B Biointerfaces 2012, 89, 79–85; https://doi.org/10.1016/j.colsurfb.2011.08.026.Suche in Google Scholar PubMed
15. Sahoo, M., Antony, R. P., Mathews, T., Dash, S., Tyag, A. K. Raman studies of chemically and thermally reduced graphene oxide. AIP Conf. Proc. 2013, 1512, 1262–1264.10.1063/1.4791511Suche in Google Scholar
16. Wang, F., Zhang, K. Reduced graphene oxide–TiO2 nanocomposite with high photocatalystic activity for the degradation of rhodamine B. J. Mol. Catal. A Chem. 2011, 345, 101–107; https://doi.org/10.1016/j.molcata.2011.05.026.Suche in Google Scholar
17. Mazzoli, A., Favoni, O. Particle size, size distribution and morphological evaluation of airborne dust particles of diverse woods by scanning electron microscopy and image processing program. Powder Technol. 2012, 225, 65–71; https://doi.org/10.1016/j.powtec.2012.03.033.Suche in Google Scholar
18. Dittrich, B., Wartig, K. A., Hofmann, D., Mülhaupt, R., Schartel, B. Carbon black, multiwall carbon nanotubes, expanded graphite and functionalized graphene flame retarded polypropylene nanocomposites. Polym. Adv. Technol. 2013, 24, 916–926; https://doi.org/10.1002/pat.3165.Suche in Google Scholar
19. Wang, K., Hu, N. X., Xu, G., Qi, Y. Stable superhydrophobic composite coatings made from an aqueous dispersion of carbon nanotubes and a fluoropolymer. Carbon 2011, 49, 1769–1774; https://doi.org/10.1016/j.carbon.2010.12.063.Suche in Google Scholar
20. Zhang, W., Zuo, H., Zhang, X., Wang, J., Guo, L., Peng, X. Preparation of graphene-perfluoroalkoxy composite and thermal and mechanical properties. Polymers 2018, 10, 1–15; https://doi.org/10.3390/polym10070700.Suche in Google Scholar PubMed PubMed Central
21. Becerril, H. A., Mao, J., Liu, Z., Stoltenberg, R. M., Bao, Z., Chen, Y. Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2008, 2, 463–470; https://doi.org/10.1021/nn700375n.Suche in Google Scholar PubMed
22. D`Urso, L., Acocella, M. R., Guerra, G., Lozzino, V., De Santis, F., Pantani, R. PLA melt stabilization by high-surface-area graphite and carbon black. Polymers 2018, 10, 1–13; https://doi.org/10.3390/polym10020139.Suche in Google Scholar PubMed PubMed Central
23. Kim, I.-H., Jeong, Y. Polylactide/exfoliated graphite nanocomposites with enhanced thermal stability, mechanical modulus, and electrical conductivity. J. Polym. Sci. B Polym. Phys. 2010, 48, 850–858; https://doi.org/10.1002/polb.21956.Suche in Google Scholar
24. Sangurima, E. X., Maldonado, F. M. Degree Thesis; Universidad Politécnica Salesiana De Ecuador, 2016.Suche in Google Scholar
25. Mensah, B., Kang, S. I., Wang, W., Nah, C. Effect of graphene on polar and nonpolar rubber matrices. Mech. Adv. Mater. Modern Process. 2018, 4, 1–12; https://doi.org/10.1186/s40759-017-0034-0.Suche in Google Scholar
26. Domínguez-Robles, J., Larrañeta, E., Fong, M. L., Martin, N. K., Irwin, N. J., Mutjé, P., Tarrés, Q., Delgado-Aguilar, M. Lignin/poly(butylene succinate) composites with antioxidant and antibacterial properties for potential biomedical applications. Int. J. Biol. Macromol. 2020, 145, 92–99; https://doi.org/10.1016/j.ijbiomac.2019.12.146.Suche in Google Scholar PubMed PubMed Central
27. Gerardo, M., Salavagione, H. Nanocompuestos poliméricos a partir de grafeno. Rev. Plast. Mod. 2010, 646, 336–346.Suche in Google Scholar
28. Shahbazi, M., Jäger, H. Current status in the utilization of biobased polymers for 3D printing process: a systematic review of the materials, processes, and challenges. ACS Appl. Bio Mater. 2021, 4, 325–369; https://doi.org/10.1021/acsabm.0c01379.Suche in Google Scholar PubMed
29. Goutham, R., Veena, T. R., Babagowda, Srinivasa Prasad, K. R. Study on mechanical properties of recycled acrylonitrile butadiene styrene (ABS) blended with virgin acrylonitrile butadiene styrene (ABS) using Taguchi method. Mater. Today Proc. 2018, 5, 24836–24845; https://doi.org/10.1016/j.matpr.2018.10.282.Suche in Google Scholar
30. Amza, C. G., Zapciu, A., Eyþórsdóttir, A., Björnsdóttir, A., Borg, J. Mechanical properties of 3D printed composites with ABS/ASA substrate and glass fiber inserts. MATEC Web Conf. 2019, 290, 1–6; https://doi.org/10.1051/matecconf/201929004002.Suche in Google Scholar
31. Franciszczak, P., Piesowicz, E., Kalniņš, K. Manufacturing and properties of r-PETG/PET fibre composite – novel approach for recycling of PETG plastic scrap into engineering compound for injection moulding. Compos. B Eng. 2018, 154, 430–438; https://doi.org/10.1016/j.compositesb.2018.09.023.Suche in Google Scholar
32. Zhang, W., Xu, Y. Mechanical Properties of Polycarbonate; ISTE Press Ltd, Elsevier Ltd: London, 2019. 1st Chapter.10.1016/B978-1-78548-313-4.50001-7Suche in Google Scholar
© 2022 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material properties
- Research progress of low dielectric constant polymer materials
- Natural rubber reinforced with super-hydrophobic multiwalled carbon nanotubes: obvious improved abrasive resistance and enhanced thermal conductivity
- Epoxy resin/graphene nanoplatelets composites applied to galvanized steel with outstanding microwave absorber performance
- Enhancement of thermal conductivity in polymer composites by maximizing surface-contact area of polymer-filler interface
- Dynamic characterization of the magnetomechanical properties of off axis anisotropic magnetorheological elastomer
- Investigation of optical and biocompatible properties of polyethylene glycol-aspirin loaded commercial pure titanium for cardiovascular device applications
- Polylactic acid effectively reinforced with reduced graphitic oxide
- Preparation and assembly
- Assembled hybrid films based on sepiolite, phytic acid, polyaspartic acid and Fe3+ for flame-retardant cotton fabric
- Fabrication, characterization, and performance of poly (aryl ether nitrile) flat sheet ultrafiltration membranes with polyvinyl pyrrolidone as additives
- Synthesis of composite membranes from polyacrylonitrile/carbon resorcinol/formaldehyde xerogels: gamma effect study, characterization and ultrafiltration of salted oily wastewater
- Chitosan nanoparticles encapsulated into PLA/gelatin fibers for bFGF delivery
- Engineering and Processing
- Stable photoluminescent electrospun CdSe/CdS quantum dots-doped polyacrylonitrile composite nanofibers
Artikel in diesem Heft
- Frontmatter
- Material properties
- Research progress of low dielectric constant polymer materials
- Natural rubber reinforced with super-hydrophobic multiwalled carbon nanotubes: obvious improved abrasive resistance and enhanced thermal conductivity
- Epoxy resin/graphene nanoplatelets composites applied to galvanized steel with outstanding microwave absorber performance
- Enhancement of thermal conductivity in polymer composites by maximizing surface-contact area of polymer-filler interface
- Dynamic characterization of the magnetomechanical properties of off axis anisotropic magnetorheological elastomer
- Investigation of optical and biocompatible properties of polyethylene glycol-aspirin loaded commercial pure titanium for cardiovascular device applications
- Polylactic acid effectively reinforced with reduced graphitic oxide
- Preparation and assembly
- Assembled hybrid films based on sepiolite, phytic acid, polyaspartic acid and Fe3+ for flame-retardant cotton fabric
- Fabrication, characterization, and performance of poly (aryl ether nitrile) flat sheet ultrafiltration membranes with polyvinyl pyrrolidone as additives
- Synthesis of composite membranes from polyacrylonitrile/carbon resorcinol/formaldehyde xerogels: gamma effect study, characterization and ultrafiltration of salted oily wastewater
- Chitosan nanoparticles encapsulated into PLA/gelatin fibers for bFGF delivery
- Engineering and Processing
- Stable photoluminescent electrospun CdSe/CdS quantum dots-doped polyacrylonitrile composite nanofibers