The infrared spectroscopy of chitosan films doped with silver and gold nanoparticles
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Evgeniya S. Zemlyakova
,
Vasilyi A. Slezhkin
Abstract
This work presents the dependences of the absorption intensity of the acid-soluble chitosan biopolymer films in the infrared (IR) region of the spectrum on the concentrations of silver and gold nanoparticles (NPs) of different morphologies. The interaction mechanisms in the vibrational spectra overlapping area of the silver NPs and chitosan molecules (2500–3500 cm−1) were observed. The influence of the metal NPs on the dipole moments of the OH-, NH3+- and CH-chitosan molecule group oscillations was established. This interaction leads to a linear increase of the IR absorption intensity with an increase of the silver nanoparticle concentration, synthesized by the citrate and borohydride methods. The presence of silver and gold ablative NPs in the chitosan films demonstrates the IR absorption intensity exponential decrease with the metal NPs’ concentrations.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material properties
- Effect of temperature on the impact behavior of PVC/ASA binary blends with various ASA terpolymer contents
- The infrared spectroscopy of chitosan films doped with silver and gold nanoparticles
- The effect of the addition of a slip agent on the rheological properties of polyethylene: off-line and in-line measurements
- Analysis of the mechanical properties of polymer materials considering lateral confinement effects
- Effect of gamma irradiation on the physicochemical and rheological properties of enzyme-catalyzed tragacanth-based injectable hydrogels
- Effects of MAH/St grafted nanocellulose on the properties of carbon reinforced styrene butadiene rubber
- Preparation and assembly
- Preparation, characterization and kinetics study of chitosan/PVA electrospun nanofiber membranes for the adsorption of dye from water
- Engineering and processing
- Polymer-induced metal diffusion during plastic processing: a reason for deposit formation
- Optimization of process parameters in plastic injection molding for minimizing the volumetric shrinkage and warpage using radial basis function (RBF) coupled with the k-fold cross validation technique
- Effects of process conditions on the heat transfer coefficient at the polymer-mold interface and tensile strength of thin-wall injection molding parts
Artikel in diesem Heft
- Frontmatter
- Material properties
- Effect of temperature on the impact behavior of PVC/ASA binary blends with various ASA terpolymer contents
- The infrared spectroscopy of chitosan films doped with silver and gold nanoparticles
- The effect of the addition of a slip agent on the rheological properties of polyethylene: off-line and in-line measurements
- Analysis of the mechanical properties of polymer materials considering lateral confinement effects
- Effect of gamma irradiation on the physicochemical and rheological properties of enzyme-catalyzed tragacanth-based injectable hydrogels
- Effects of MAH/St grafted nanocellulose on the properties of carbon reinforced styrene butadiene rubber
- Preparation and assembly
- Preparation, characterization and kinetics study of chitosan/PVA electrospun nanofiber membranes for the adsorption of dye from water
- Engineering and processing
- Polymer-induced metal diffusion during plastic processing: a reason for deposit formation
- Optimization of process parameters in plastic injection molding for minimizing the volumetric shrinkage and warpage using radial basis function (RBF) coupled with the k-fold cross validation technique
- Effects of process conditions on the heat transfer coefficient at the polymer-mold interface and tensile strength of thin-wall injection molding parts
