Effect of gamma irradiation on the physicochemical and rheological properties of enzyme-catalyzed tragacanth-based injectable hydrogels
Abstract
In the present study, gamma irradiation was applied to promote the mechanical properties of enzyme- mediated in situ forming hydrogels prepared with tyramine-functionalized gum tragacanth (TA-GT). For this purpose, after gamma irradiation of powder or hydrocolloid solution of gum tragacanth (GT), the physiochemical and rheological properties of GT solution, and resultant hydrogel was investigated. In situ forming hydrogels were prepared via horseradish peroxidase catalyzed coupling reaction of TA-GT in the presence of hydrogen peroxide. Gamma irradiation led to a decrease in GT molecular weight and solution viscosity. Also, the solubility of GT improved and the separation of water soluble/swellable part of gum samples became easier, using gamma irradiation. In addition, by gamma irradiation of GT powder at doses of 5–15 kGy, a polymeric solution with higher concentration could be prepared that resulted in the promotion of hydrogels storage modulus. Further increase of irradiation dose did not improve storage modulus due to the extra decrease of gum molecular weight.
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Articles in the same Issue
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Articles in the same Issue
- Frontmatter
- Material properties
- Effect of temperature on the impact behavior of PVC/ASA binary blends with various ASA terpolymer contents
- The infrared spectroscopy of chitosan films doped with silver and gold nanoparticles
- The effect of the addition of a slip agent on the rheological properties of polyethylene: off-line and in-line measurements
- Analysis of the mechanical properties of polymer materials considering lateral confinement effects
- Effect of gamma irradiation on the physicochemical and rheological properties of enzyme-catalyzed tragacanth-based injectable hydrogels
- Effects of MAH/St grafted nanocellulose on the properties of carbon reinforced styrene butadiene rubber
- Preparation and assembly
- Preparation, characterization and kinetics study of chitosan/PVA electrospun nanofiber membranes for the adsorption of dye from water
- Engineering and processing
- Polymer-induced metal diffusion during plastic processing: a reason for deposit formation
- Optimization of process parameters in plastic injection molding for minimizing the volumetric shrinkage and warpage using radial basis function (RBF) coupled with the k-fold cross validation technique
- Effects of process conditions on the heat transfer coefficient at the polymer-mold interface and tensile strength of thin-wall injection molding parts